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1.
2.
We have investigated the segregation of Pt atoms in the surfaces of Pt-Ni nanoparticles, using modified embedded atom method potentials and the Monte Carlo method. The nanoparticles are constructed with disordered fcc configurations at two fixed overall concentrations (50 at. % Pt and 75 at. % Pt). We use octahedral and cubo-octahedral nanoparticles terminated by {111} and {100} facets to examine the extent of the Pt segregation to the nanoparticle surfaces at T=600 K. The model particles contain between 586 and 4033 atoms (particle size ranging from 2.5 to 5 nm). Our results imply that a complete {100}-facet reconstruction could make the cubo-octahendral Pt-Ni nanoparticles most energetically favorable. We predict that at 600 K due to segregation the equilibrium cubo-octahedral Pt50Ni50 nanoparticles with fewer than 1289 atoms and Pt75Ni25 nanoparticles with fewer than 4033 atoms would achieve a surface-sandwich structure, in which the Pt atoms are enriched in the outermost and third atomic shells while the Ni atoms are enriched in the second atomic shell. We also find that, due to an order-disorder transition, the Pt50Ni50 cubo-octahedral nanoparticles containing more than 2406 atoms would form a core-shell structure with a Pt-enriched surface and a Pt-deficient homogenous core. 相似文献
3.
The elution order of the hop α- and β-acids has been studied under different modes of electrokinetic separation. A model is advanced to explain the shorter migration times of the more hydrophobic β-acids compared to the α-acids in micellar electrokinetic chromatography (MEKC). For quality control of the bitter principles in hops, the ruggedness of electrokinetic separation could be improved by replacing MEKC by microemulsion electrokinetic chromatography (MEEKC). 相似文献
4.
P. Knowles J. Deutsch J. Egger W. Fetscher F. Foroughi J. Govaerts M. Hadri K. Kirch S. Kistryn J. Lang X. Morelle O. Naviliat A. Ninane R. Prieels N. Severijns L. Simons J. Sromicki S. Vandormael P. Van Hove 《Hyperfine Interactions》1999,118(1-4):73-76
Unlike the majority of Michel parameters which are consistent with the Standard Model V-A interaction, the experimental value of ξ″(=0.65±0.36) [1] is poorly known. Our experiment will measure the longitudinal polarization,
P
L
, of positrons emitted from the decay of polarized muons. The value of P
L
, equal to unity in the Standard Model, will decrease for high energy positrons emitted antiparallel to the muon spin if the
combination of Michel parameters ξ″/ξξ′ − 1 deviates from the Standard Model value of zero.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
5.
M.A. Van Hove R.J. Koestner P.C. Stair J.P. Bibérian L.L. Kesmodel I. BartoŠ G.A. Somorjai 《Surface science》1981,103(1):189-217
The structures of the reconstructed Ir(100), Pt(100) and Au(100) surfaces have been investigated. Low energy electron diffraction (LEED) patterns are analyzed and LEED intensity versus energy data are measured. A variety of structures is observed by LEED: Ir(100) exhibits a relatively simple (1 × 5) pattern; Pt(100) shows a series of closely related patterns, a typical representative of which has a structure; Au(100) usually exhibits a c(26 × 68) pattern, often inaccurately described in the literature as a (20 × 5) pattern. The reconstruction of Au(111) is also considered for comparison. Various plausible structural models are discussed, while laser simulation is used to lessen the number of these models. The analysis is completed in a companion paper where LEED intensity calculations are reported to determine the atomic locations. 相似文献
6.
7.
C. Michel Y. El Masri R. Holzmann M. A. Van Hove J. Vervier 《Zeitschrift für Physik A Hadrons and Nuclei》1980,298(3):213-218
Lifetimes of the first 2+, 4+ and 6+ levels in170W have been measured by the recoil-distance method based on the Doppler effect, using the155Gd (20Ne, 5n)170W reaction. The following conclusions can be drawn from the results: if there are any deviations from the predictions of the rotational model for the lifetimes of the 4+ and 6+ states, they are smaller than 8.5 %; if this model accurately describes the nucleus170W, the intrinsic quadrupole moment of this nucleus is: Q0=5.93±0.06 barns, and its deformation is: β=0.240±0.003. The value of Q0 is compared with the predictions of various calculations for the tungsten isotopes. 相似文献
8.
In this study, methanol extracts (MEs) and essential oil (EO) of Angelica purpurascens (Avé-Lall.) Gill obtained from different parts (root, stem, leaf, and seed) were evaluated in terms of antioxidant activity, total phenolics, compositions of phenolic compound, and essential oil with the methods of 2,2-azino-bis(3ethylbenzo-thiazoline-6-sulfonic acid (ABTS•+), 2,2-diphenyl-1-picrylhydrazil (DPPH•) radical scavenging activities, and ferric reducing/antioxidant power (FRAP), the Folin–Ciocalteu, liquid chromatography−tandem mass spectrometry (LC−MS/MS), and gas chromatography-mass spectrometry (GC−MS), respectively. The root extract of A. purpurascens exhibited the highest ABTS•+, DPPH•, and FRAP activities (IC50: 0.05 ± 0.0001 mg/mL, IC50: 0.06 ± 0.002 mg/mL, 821.04 ± 15.96 µM TEAC (Trolox equivalent antioxidant capacity), respectively). Moreover, EO of A. purpurascens root displayed DPPH• scavenging activity (IC50: 2.95 ± 0.084 mg/mL). The root extract had the highest total phenolic content (438.75 ± 16.39 GAE (gallic acid equivalent), µg/mL)). Twenty compounds were identified by LC−MS/MS. The most abundant phenolics were ferulic acid (244.39 ± 15.64 μg/g extract), benzoic acid (138.18 ± 8.84 μg/g extract), oleuropein (78.04 ± 4.99 μg/g extract), and rutin (31.21 ± 2.00 μg/g extract) in seed, stem, root, and leaf extracts, respectively. According to the GC−MS analysis, the major components were determined as α-bisabolol (22.93%), cubebol (14.39%), α-pinene (11.63%), and α-limonene (9.41%) among 29 compounds. Consequently, the MEs and EO of A. purpurascens can be used as a natural antioxidant source. 相似文献
9.
10.