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Nesrine Mechi Ismahen Ben Khemis Houcine Dhaou Slim Zghal Abdelmottaleb Ben Lamine 《Chinese Journal of Physics (Taipei)》2018,56(2):449-467
The Mg50Ni45Cr5 alloy for hydrogen storage is prepared by mechanical alloying. First, using the X-ray diffraction (XRD) and the scanning electron microscopy (SEM) we examine the morphology and the structure of the substrate. The obtained results highlight the effectiveness of this alloy in loading hydrogen as it is a nanocrystalline and a ductile one. Second, we attempt to justify these expectations using the statistical physic, precisely the model monolayer with two levels of energy, in modeling a hydrogen absorption and desorption isotherms on Mg50Ni45Cr5 alloy at four temperatures T?=?275?K, T?=?300?K, T?=?325?K and T?=?350?K. The model has six physicochemical parameters deduced from the fitting of the isotherms, they are divided by two categories of steric and energetic parameters. Thanks to these parameters we compare the absorption and desorption processes, in order to highlight the hysteresis phenomenon encountered during the hydrogen sorption. 相似文献
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The synthesis of novel substituted 3-p-nitro-phenyliminocoumarins and corresponding N-ureaiminocoumarins is described. The condensation of these materials with oxalyl chloride leads to the corresponding N-parabanic iminocoumarins, which have not previously been described, in moderate or good yields and high selectivity. The structures were characterized by Fourier transform infrared, 1H and 13C NMR, and elemental analysis.
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Jouini Houda Mejri Imène Rhimi Baker Mhamdi Mourad Blasco Teresa Delahay Gérard 《Research on Chemical Intermediates》2021,47(7):2901-2915
Research on Chemical Intermediates - Fe–Cu–ZSM-5 and Ce–Fe–Cu–ZSM-5 solids prepared using solid-state ion exchange method (SSIE) were tested in the NH3–SCR of NO... 相似文献
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The space of distribution vectors of a holomorphic discrete series representation of scalar type can be identified to a space of holomorphic functions with moderate growth. This is the main result of the paper. We give an application of it to the Hankel transform and to multivariate Laguerre series expansions.
Mathematics Subject Classification (2000): 32M15, 22E46in final form: 19 January 2004 相似文献
Resume. Lespace des vecteurs distributions dune représentation de la série discrète holomorphe scalaire dun domaine borné symétrique sidentifie à lespace des fonctions holomorphes à croissance modérée. Cest le principal résultat de cet article. Nous en donnons une application à la transformation de Hankel et aux développements en série de fonctions de Laguerre de plusieurs variables.
Mathematics Subject Classification (2000): 32M15, 22E46in final form: 19 January 2004 相似文献
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An optical correlation setup is used to image transparent objects through scattering media, and 10-mum longitudinal and 2.5-mum transverse resolution are achieved. Spectral-bandwidth sampling of the light source is made possible by a tunable dye laser and leads to signal enhancement as a result of sampling interferogram filtering. An optical system allows observation of sample slices without the need for a translation stage. 相似文献
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We give the system of Laguerre–Freud equations associated with the D ω -semi-classical functionals of class one, where D ω is the divided difference operator. This system is solved in the symmetric case. There are essentially two canonical cases. The corresponding integral representations are given. 相似文献
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This work describes an approach for the development of two bacteria biosensors based on surface plasmon resonance (SPR) technique. The first biosensor was based on functionalized gold substrate and the second one on immobilized gold nanoparticles. For the first biosensor, the gold substrate was functionalized with acid-thiol using the self-assembled monolayer technique, while the second one was functionalized with gold nanoparticles immobilized on modified gold substrate. A polyclonal anti-Escherichia coli antibody was immobilized for specific (E. coli) and non-specific (Lactobacillus) bacteria detection. Detection limit with a good reproducibility of 104 and 103 cfu mL−1 of E. coli bacteria has been obtained for the first biosensor and for the second one respectively. A refractive index variation below 5 × 10−3 due to bacteria adsorption is able to be detected. The refractive index of the multilayer structure and of the E. coli bacteria layer was estimated with a modeling software. 相似文献
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Ahmed SB Sghaier RM Guesmi F Kaabi B Mejri M Attia H Laouini D Smaali I 《Natural product research》2011,25(12):1195-1201
In this study, we tested 10 essential oils (EOs) extracted from 10 plants issued from Sned region (Tunisia) to evaluate both their leishmanicidal effects against Leishmania major and L. infantum, and their cytotoxicity against murine macrophage cell line RAW 264.7 (ATCC, TIB-71). The antioxidant activity was also monitored by the DDPH method, while the chemical composition of active EO was assessed by GC-MS analysis. The results showed that the EOs obtained from Thymus hirtus sp. algeriensis (rich on monoterpenoids, especially linalool at 17.62% and camphor at 13.82%) is significantly active against both L. major and L. infantum, whereas Ruta chalepensis EO (rich on 2-undecanone at 84.28%) is only active against L. infantum. Both oil extracts showed low cytotoxicity towards murine macrophages. The characteristic ratios (IC?? Raw264.7 cells/IC?? L. infantum and IC?? Raw264.7 cells/IC?? L. major) were, respectively, 2.7 and 1.57 for T. hirtus sp. algeriensis, and 1.34 and 0.19 for R. chalepensis. However, when measuring the antioxidant effects (DDPH method), the two latter EOs presented a moderate 2,2-diphenyl-2-picrylhydrazyl hydrate scavenging effects compared to EOs from Eucaliptus globulus, Pinus halepensis, Pituranthos tortuosus, Rosmarinus officinalis, Tetraclinis articulata or to BHT. 相似文献