全文获取类型
收费全文 | 692篇 |
免费 | 11篇 |
国内免费 | 7篇 |
专业分类
化学 | 421篇 |
晶体学 | 1篇 |
力学 | 7篇 |
数学 | 159篇 |
物理学 | 122篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 3篇 |
2018年 | 11篇 |
2017年 | 4篇 |
2016年 | 4篇 |
2015年 | 9篇 |
2014年 | 10篇 |
2013年 | 26篇 |
2012年 | 41篇 |
2011年 | 43篇 |
2010年 | 27篇 |
2009年 | 29篇 |
2008年 | 49篇 |
2007年 | 36篇 |
2006年 | 40篇 |
2005年 | 36篇 |
2004年 | 36篇 |
2003年 | 33篇 |
2002年 | 37篇 |
2001年 | 7篇 |
2000年 | 16篇 |
1999年 | 15篇 |
1998年 | 19篇 |
1997年 | 12篇 |
1996年 | 16篇 |
1995年 | 14篇 |
1994年 | 7篇 |
1993年 | 12篇 |
1992年 | 4篇 |
1991年 | 11篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1979年 | 10篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1976年 | 3篇 |
1975年 | 3篇 |
排序方式: 共有710条查询结果,搜索用时 15 毫秒
1.
2.
Bram van Asch Henk Hollmann Henk van Tilborg 《Journal of Combinatorial Theory, Series A》2006,113(8):1594-1613
When Jack van Lint was appointed as full professor at the Eindhoven University of Technology at the age of 26 he combined a PhD in number theory with a very open scientific mind. It took a sabbatical visit to Bell Laboratories in 1966 to make him understand that a new and fascinating field of applied mathematics was emerging: discrete mathematics. It fascinated and inspired him for the rest of his life. When he passed away on September 28, 2004, he left behind a legacy of 18 books and 177 articles, covering many aspects of coding theory, combinatorics, and finite geometry.van Lint was also a strong international advocate of the role that discrete mathematics ought to play in modern applied mathematics curricula. Quite a few departments sought his advice. Years later, four different universities showed their appreciation by awarding him an honorary degree.This overview is an homage to van Lint's academic achievements and can serve as an introduction to his work for younger generations. 相似文献
3.
4.
Nynke A. M. Verhaegh Jeroen S. van Duijneveldt Jan K. G. Dhont Henk N. W. Lekkerkerker 《Physica A》1996,230(3-4):409-436
Mixtures of colloidal silica spheres and polydimethylsiloxane in cyclohexane with a colloid-polymer size ratio of about one were found to phase separate into two fluid phases, one which is colloid-rich and one which is colloid-poor. In this work the phase separation kinetics of this fluid-fluid phase separation is studied for different compositions of the colloid-polymer mixtures, and at several degrees of supersaturation, with small angle light scattering and with light microscopy. The small angle light scattering curve exhibits a peak that grows in intensity and that shifts to smaller wave vector with time. The characteristic length scale that is obtained from the scattering peak is of the order of a few μm, in agreement with observations by light microscopy. The domain size increases with time as
, which might be an indication of coarsening by diffusion and coalescence, like in the case of binary liquid mixtures and polymer blends. For sufficiently low degrees of supersaturation the angular scattering intensity curves satisfy dynamical scaling behavior. 相似文献
5.
Seppo Hassi Manfred Mö ller Henk de Snoo 《Proceedings of the American Mathematical Society》2006,134(10):2885-2893
The class of Nevanlinna functions consists of functions which are holomorphic off the real axis, which are symmetric with respect to the real axis, and whose imaginary part is nonnegative in the upper halfplane. The Kac subclass of Nevanlinna functions is defined by an integrability condition on the imaginary part. In this note a further subclass of these Kac functions is introduced. It involves an integrability condition on the modulus of the Nevanlinna functions (instead of the imaginary part). The characteristic properties of this class are investigated. The definition of the new class is motivated by the fact that the Titchmarsh-Weyl coefficients of various classes of Sturm-Liouville problems (under mild conditions on the coefficients) actually belong to this class.
6.
Phillip L. Kempster Jacobus F. Staden Henk R. Vliet 《Fresenius' Journal of Analytical Chemistry》1988,332(2):153-156
Summary Using an 11 ml centrifugal type spray chamber, a rapid sample introduction rate of 320 injections per hour may be achieved when interfacing flow injection analysis and inductively coupled plasma emission spectrometric techniques. Calcium was determined in water samples with a relative standard deviation of better than 3.5% over the analytical range of 10 to 200 mg · l–1 Ca. Mean recovery was 97%.
Calciumbestimmung im Wasser mit dem Flow-injection-Prinzip kombiniert mit der Induktions-gekoppelten Plasma-Emissions-Spektrometrie (FIA-ICP)相似文献
7.
Johan Garssen Theresa L. Buckley Henk Van Loveren 《Photochemistry and photobiology》1998,68(2):205-210
The aim of this study was to investigate the possible role of sensory nerves in UV light-induced systemic immunomodulation. Contact hypersensitivity to the low molecular weight compound picrylchloride was used as a model for cellular immunity that can be suppressed by low (i.e. suberythemal) doses of UV light even after exposure at a distant locus (i.e. systemic immunosuppression). In sensory nerve-depleted mice, achieved by two subcutaneous injections with the neurotoxin capsaicin before the age of 4 weeks, UV light exposure failed to inhibit contact hypersensitivity responses to picrylchloride. This indicates that sensory nerves are at least partially involved in the induction of systemic immunosuppression by UV light. In order to analyze whether sensory neuropeptides, such as calcitonin gene-related peptide (CGRP) and tachykinins, are involved in UV light-induced systemic immunosuppression, mice were pretreated with selective antagonists prior to each UV light exposure. These experiments indicated that CGRP but not the tachykinins plays a crucial role in the UV light-induced systemic immunosuppression. 相似文献
8.
Jacquelynn L. Savoca Robert P. Lattimer Joseph M. Richards Willem Windig Henk L.C. Meuzelaar 《Journal of Analytical and Applied Pyrolysis》1985,9(1):19-28
A set of twelve natural rubber vulcanizates was analyzed by Curie-point pyrolysis-mass spectrometry (Py-MS). Multivariate analysis successfully correlated the Py-MS data with either total or polysulfidic crosslink density measurements. (Polysulfidic means two or more sulfurs.) The principal correlation observed was an increase in the ratio of monomer to dimer pyrolyzate yield with an increase in crosslink density. The feasibility of using Py-MS for total crosslink density determination has thus been demonstrated. The Py-MS data, however, did not allow us to distinguish different types of crosslinks. 相似文献
9.
Floris P. J. T. Rutjes Henk Hiemstra Hendrik H. Mooiweer W. Nico Speckamp 《Tetrahedron letters》1988,29(52):6975-6978
Acid catalyzed cyclization of methoxymethyl substituted acyclic hydrazides 4 provides cyclic hydrazides 5 in moderate to good yields through the intermediacy of N,N′-di(methoxycarbonyl)hydrazinium intermediates. 相似文献
10.
Henk Buck 《International journal of quantum chemistry》2005,101(1):73-83
With semi‐empirical MO and ab initio calculations at different levels, we investigated the π conjugation of alternating X? Y bonds with X? Y for N/B and N/C combinations in an open and cyclic arrangement. Although the intrinsic symmetry is lost for the acyclic even‐membered compounds, the alternation is still reflected in its geometry and electron‐density transfer. For the cyclic π compounds, we focused our attention on borazine N3B3H6 (D3h symmetry), which is isoelectronic with benzene (D6h symmetry). Specific attention is given to the electrophilic behavior of borazine with respect to CH and SiMe. The dynamics based on the results of FT‐ICR mass spectrometry was studied in more detail. In addition, the results of the cyclic systems with 4n and 4n+2 π electrons concerning their geometries are compared with the corresponding carbon compounds. Attention is also given to the dication of borazine, because of the corresponding triplet ground state of the benzene dication. © 2004 Wiley Periodicals, Inc. Int J Quantum Chem, 2005 相似文献