排序方式: 共有36条查询结果,搜索用时 15 毫秒
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Abe K Ahrens LA Amako K Aronson SH Beier EW Callas JL Cutts D Diwan M Durkin LS Gibbard BG Heagy SM Hedin D Hoftun JS Hurley M Kabe S Kurihara Y Lanou RE Mann AK Marx MD Murtagh MJ Nagashima Y Newcomer FM Shinkawa T Stern E Suzuki Y Terada S White DH Williams HH Yamaguchi Y 《Physical review letters》1987,58(7):636-639
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Substituent effects on monoboronic acid sensors for saccharides based on N-phenyl-1,8-naphthalenedicarboximides 总被引:4,自引:0,他引:4
In the course of our investigations on new monoboronic acid saccharide sensors with C(0) spacers, a series of probes 1-6 based on 1,8-naphthalenedicarboximide were synthesized. Sensor 1 displays features typical of PET monoboronic acid sensors and shows high selectivity to fructose. Sensor 2 exhibits a novel dual emission and remarkable sensitivity for glucose relative to fructose and galactose through subtle changes in pH. Sensor 3 displays significantly enhanced fluorescence in the presence of galactose at low pH. Although probes 4-6 exhibit unique properties such as high quantum yield (Phi(F) = 0.407) and excellent solubility in water, they did not show significant change in fluorescence intensity in the presence of monosaccharides. The effects of substituent on all six probes lend support to the proposed photoelectrochemical model. 相似文献
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Summary We investigate the transition from two-frequency quasiperiodicity to chaotic behavior in a model for a quasiperiodically driven
magnetoelastic ribbon. The model system is a two-frequency parametrically driven Duffing oscillator. As a driving parameter
is increased, the route to chaos takes place in four distinct stages. The first stage is a torus-doubling bifurcation. The
second stage is a transition from the doubled torus to a strange nonchaotic attractor. The third stage is a transition from
the strange nonchaotic attractor to a geometrically similar chaotic attractor. The final stage is a hard transition to a much
larger chaotic attractor. This latter transition arises as the result of acrisis, the characterization of which is one of our primary concerns. Numerical evidence is given to indicate that the crisis arises
from the collision of the chaotic attractor with the stable manifold of a saddle torus. Intermittent bursting behavior is
present after the crisis with the mean time between bursts scaling as a power law in the distance from the critical control
parameter; τ ∼ (A-Ac)-α. The critical exponent is computed numerically, yielding the value α=1.03±0.01. Theoretical justification is given for the
computed critical exponent. Finally, a Melnikov analysis is performed, yielding an expression for transverse crossings of
the stable and unstable manifolds of the crisis-initiating saddle torus. 相似文献
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A 3 x 14 matrix of substituted N-aryl-1,8-naphthalimides was synthesized for the evaluation and discovery of dual fluorescence. Because of their unique photophysical properties, these dual fluorescent systems represent an exception to the widely studied TICT (Twisted Internal Charge Transfer) fluorescent dyes or tautomeric benzofluorescein class of two-color dyes. The matrix library was designed to investigate the effects of heterocycles, particularly pi-excessive and pi-deficient systems. Of the 42 compounds surveyed, five displayed well-resolved two-color emission in solvents as nonpolar as hexane. Based on the observed trends in fluorescence lambda(max) and quantum yield, a new model is proposed that predicts LW and SW emission for these systems. In addition, this model provides potential design features for the synthesis of new dual fluorescent species. 相似文献
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The field of chaotic synchronization has grown considerably since its advent in 1990. Several subdisciplines and "cottage industries" have emerged that have taken on bona fide lives of their own. Our purpose in this paper is to collect results from these various areas in a review article format with a tutorial emphasis. Fundamentals of chaotic synchronization are reviewed first with emphases on the geometry of synchronization and stability criteria. Several widely used coupling configurations are examined and, when available, experimental demonstrations of their success (generally with chaotic circuit systems) are described. Particular focus is given to the recent notion of synchronous substitution-a method to synchronize chaotic systems using a larger class of scalar chaotic coupling signals than previously thought possible. Connections between this technique and well-known control theory results are also outlined. Extensions of the technique are presented that allow so-called hyperchaotic systems (systems with more than one positive Lyapunov exponent) to be synchronized. Several proposals for "secure" communication schemes have been advanced; major ones are reviewed and their strengths and weaknesses are touched upon. Arrays of coupled chaotic systems have received a great deal of attention lately and have spawned a host of interesting and, in some cases, counterintuitive phenomena including bursting above synchronization thresholds, destabilizing transitions as coupling increases (short-wavelength bifurcations), and riddled basins. In addition, a general mathematical framework for analyzing the stability of arrays with arbitrary coupling configurations is outlined. Finally, the topic of generalized synchronization is discussed, along with data analysis techniques that can be used to decide whether two systems satisfy the mathematical requirements of generalized synchronization. (c) 1997 American Institute of Physics. 相似文献
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[reaction: see text]. A monoboronic acid fluorescent sensor was conveniently synthesized from 3-nitronaphthalic anhydride and 3-aminophenylboronic acid. This novel saccharide probe exhibits dual emission suitable for ratiometric sensing and displays a remarkable sensitivity for glucose relative to fructose and galactose. 相似文献
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Simple Zeros of the Riemann Zeta-Function 总被引:1,自引:0,他引:1
Assuming the Riemann Hypothesis, Montgomery showed by meansof his pair correlation method that at least two-thirds of thezeros of Riemann's zeta-function are simple. Later he and Taylorimproved this to 67.25 percent and, more recently, Cheer andGoldston increased the percentage to 67.2753. Here we proveby a new method that if the Riemann and Generalized LindelöofHypotheses hold, then at least 70.3704 percent of the zerosare simple and at least 84.5679 percent are distinct. Our methoduses mean value estimates for various functions defined by Dirichletseries sampled at the zeros of the Riemann zeta-function. 1991Mathematics Subject Classification: 11M26. 相似文献