排序方式: 共有11条查询结果,搜索用时 15 毫秒
1.
Self-association system of(R)-1,3-butanediol in dilute carbon tetrachloride(CCl4)solution is studied as a model of molecular association mixture.Analysis methods including FSMWEFA(fixed-size moving window evolving factor analysis)combined with PCA(principal component analysis),SIMPLISMA (simple-to-use interactive self-modeling mixture analysis),and ITTFA(iterative target transformation factor analysis)are adopted to resolve infrared spectra of(R)-1,3-butanediol solution.Association number and equilibrium constant are computed.(R)-1,3-butanediol in dilute inert solution is determined as a monomer-trimer equilibrium system.Theoretical investigation of trimer structures is carried out with DFT(density functional theory),and structural factors are analyzed. 相似文献
2.
The microstructure of CosoNi22Ga28 ribbon with the L10 structure is examined. The band-like morphology is observed. These bands with the width in a range of 40-200 nm appear along the transverse direction of the ribbon. The giant magnetoimpedance (GMI) effect in this alloy is measured. The results show that Co5oNi22Ga28 exhibits a sharp peak of the GAI effect. The maximum GAH ratio up to 360% is detected. The GMI effect measured versus temperature shows large jumps of the magnetoimpedance amplitude at the reversal martensitic transformation temperature 240℃ and Curie temperature 375℃C respectively. The jump ratios of the magnetoimpedance amplitude examined at these temperatures are about 5 and 10, respectively. 相似文献
3.
The hydrothermal reaction of CuBr2 and CuBr with phen·H2O (phen= 1,10-phenanthroline) in a molar ratio of 1:1:1.5 gave birth to the first copper-halo cationic cluster [Cu2^Ⅱ Cu2^Br4 (phen)4 ] ^2+(1) with tetranuclear anionic cluster [Cu4Br6]^2-. Changing the precursors or their molar ratios, two mononuclear complexes [Cu(phen)2Br]Br·H2O (2) and [Ni(phen)3][CuCl2]2 (3) as well as two unusual copper-halo chains found in polymers [Cu2Br2(phen)]∞ (4) and [Cu^ⅡCu3^ⅠBr2Ⅰ3 (phen)2 ]∞ (5) were obtained. The (Cu2Br2)∞ chain of 4 looks like a linearar ray of hexagons based on fused Cu3Br3 units, and the linear (Cu3Ⅰ3Br^-)∞ chain of 5 is an alternate combination of the rhombic Cu2I2 cores and the Cu4I4Br2^2- units. In addition, the hydrothermal reaction of CuBr2 with NA(NA=nicotinic acid) or INA (INA =isonicotinic acid) resulted in the syntheses of two compounds [CuBr(NA)] (6) and [CuBr(INA)]∞(7) containing staircase chain. Among them the third-order non-linear optical properties of 2, 5, 6 and 7 were investigated and all exhibit the reverse saturable absorption (α2〉0) and self-defocusing performance (n2〈0). 相似文献
4.
XiGuang Cao Xun Chen YunHua Chen XiangYi Cui DeQing Fang ChangBo Fu Karl L. Giboni HaoWei Gong GuoDong Guo Ming He Jie Hu XingTao Huang XiangDong Ji YongLin Ju ShaoLi Li Qing Lin HuaXuan Liu JiangLai Liu Xiang Liu Wolfgang Lorenzon YuGang Ma YaJun Mao KaiXuan Ni Kirill Pushkin XiangXiang Ren Michael Schubnell ManBing Shen YuJie Shi Scott Stephenson AnDi Tan Greg Tarlé HongWei Wang JiMing Wang Meng Wang XuMing Wang Zhou Wang YueHuan Wei ShiYong Wu MengJiao Xiao Xiang Xiao PengWei Xie Tao Ye YingHui You XiongHui Zen Hua Zhang Tao Zhang HaiYing Zhao Li Zhao XiaoPeng Zhou ZhongHua Zhu 《中国科学:物理学 力学 天文学(英文版)》2014,57(8):1476-1494
5.
设计了一种塑料靶表面涂铋(Bi)的靶丸替代常规内爆靶,利用分幅相机获取辐射驱动内爆替代靶丸Bi等离子体再发射X射线的2维图像。实验时,从主激光中分出一束光信号,经光电转换后作为分幅相机的触发信号,以激光直接驱动金球靶建立相机的时标。根据分幅相机的时标可确定每幅X射线图像相对于主激光的时间延迟。分析Bi球靶的X射线分幅图像,得到夹持内爆靶丸的CH膜的烧蚀时间及Bi球靶半径的变化关系。通过X射线图像还可反推出诊断孔的大小和CH膜支撑靶丸的对称性。 相似文献
6.
HaiYing Li YunXiang Lu Xiang Zhu ChangJun Peng Jun Hu HongLai Liu Ying Hu 《中国科学:化学(英文版)》2012,55(8):1566-1572
Halogen bonding interactions between several halogenated ion pairs and CO2 molecules have been investigated by means of density functional theory calculations. To account for the influence of solvent environment, the implicit polarized continuum model was also employed. The bromide and iodide cations of ionic liquids (ILs) under study can interact with CO2 molecules via X O interactions, which become much stronger in strength than those in the complexes of iodo-perfluorobenzenes, very effective halogen bond donors, with CO2 molecules. Such interactions, albeit somewhat weaker in strength, are also observed between halogenated ion pairs and CO2 molecules. Thus, the solubility of CO2 may be improved when using halogenated ILs, as a result of the formation of X O halogen bonds. Under solvent effects, the strength of the interactions tends to be weakened to some degree, with a concomitant elongation of intermolecular distances. The results presented here would be very useful in the design and synthesis of novel and potent ILs for CO2 physical absorption. 相似文献
7.
酞菁的大π共轭体系使其具有良好的电子给予能力和对可见光的强烈吸收性质,可作为人工光合作用体系中的光捕捉单元.富勒烯具有独特的三维笼状结构,几乎所有反应中都具有低的重组能,是良好的电子或能量受体.将富勒烯与酞菁结合起来,集两个光活性实体于一身,由于酞菁和富勒烯给受体之间的电子相互作用,又赋予其新的性质,具有良好的应用前景,是富勒烯和酞菁领域中的研究热点.本文将酞菁.富勒烯给受体体系分为共价和非共价两种连接方式,介绍其结构与性质以及两者的相互关系,总结了其在有机太阳能电池、非线性光学和液晶性等方面的应用进展,展望了该体系的未来发展趋势. 相似文献
8.
A new fluorescent probe RY was synthesized for the detection of Au3+ ions based on a rhodamine B derivative. The fluorescent probe showed good selectivity and sensitivity to Au3+ ions. Obvious color and fluorescence changes could be observed with the naked eye while the fluorescent probe reacted with the Au3+ ions. The detection limit of the probe was determined to be 36 ppb by the fluorescence titration; the excellent linear relationship suggests that the probe is potentially useful for quantitative detection of Au3+ in vitro. We also demonstrated its bioimaging application in both living cells and mice; this was the first time that a fluorescent probe was successfully applied to imaging Au3+ in living animals. 相似文献
9.
Gao Jie Zhai JiYuan Pan WeiMin Li ShaoPeng Sun Yi Dai JianPing Chi YunLong Li ZhongQuan Zhao TongXian Huang TongMing Ma Qiang Ge Rui Li ChunHua Guo HaiSheng Wang GuangWei Qiu Feng Lin HaiYing Hou Mi Wang QunYao 《中国科学:物理学 力学 天文学(英文版)》2011,54(2):154-159
The 1.3 GHz superconducting radio-frequency (SRF) technology is one of the key technologies for the ILC and future XFEL and ERL projects in China. With the aim to develop 1.3 GHz SRF technology, IHEP has started a program to build an SRF Accelerating Unit. This unit contains a 9-cell 1.3 GHz superconducting cavity, a short cryomodule, a high power input coupler, a tuner and a low level RF system. This program also includes the SRF laboratory upgrade, which will permit the unit to be built and tested at IHEP. The unit will be used for the 1.3 GHz SRF system integration study, high power horizontal test and possible beam test in the future. In this paper, we report the recent R&D status of this program. The first large grain low-loss shape 9-cell superconducting RF cavity made by IHEP reached 20 MV/m in the first vertical test in July, 2010. The prototype tuner and low level RF (LLRF) system are under test. The high power input coupler and cryomodule are under fabrication. Several key SRF facilities for 9-cell cavity surface treatment and pre-tuning were successfully commissioned and are in operation. 相似文献
10.