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1.
A.J.?Lpez-Moreno 《Acta Mathematica Hungarica》2005,106(4):343-354
Summary We obtain preservation inequalities for Lipschitz constants of higher order in simultaneous approximation processes by Bernstein type operators. From such inequalities we derive the preservation of the corresponding Lipschitz spaces. 相似文献
2.
György Gát 《Analysis Mathematica》2006,32(1):25-48
Summary It is known that the Fejér means - with respect to the character system of the Walsh, and bounded Vilenkin groups - of an
integrable function converge to the function a.e. In this work we discuss analogous problems on the complete product of finite,
not necessarily Abelian groups with respect to the character system for functions that are constant on the conjugacy classes.
We find that the nonabelian case differs from the commutative case. We prove the a.e. convergence of the (C,1) means of the Fourier series of square integrable functions. We also prove the existence of a function f∊Lq for some q >1 such that sup |σn f | = + ∞ a.e. This is a sharp contrast between the Abelian and the nonabelian cases. 相似文献
3.
4.
Results from Super-Kamiokande-I’s entire 1496 live days of solar neutrino data are presented, including the absolute flux,
energy spectrum, zenith angle (day/night) and seasonal variation. The possibility of MSW and vacuum oscillations is discussed
in light of these results. Results from the first 1289 days of Super-K-I’s atmospheric neutrino analysis are also presented,
including the evidence for νμ →ν
τ oscillations, against νμ → νsterile oscillations, and the current limits on proton decay. Finally, results based on 56 × 1019 protons on target are given for the K2K long-baseline neutrino oscillation experiment. 相似文献
5.
K. Migléczi Gy. Somorjai M. Pátfalusi G. Tóth Gy. Horváth I. Hazai 《Chromatographia》2004,60(1):S67-S74
GYKI-16084 – (+)-(R)-2-{3-(benzo[1,4]dioxan-2-yl-methylamino)-1-propyl}-3(2H)-pyridazinone hydrochloride – is a new drug candidate for the treatment of benign prostatic hyperplasia. In our study the major metabolites formed in the rat and dog were isolated from dog and rat urine, then their structures were elucidated by means of MS and NMR. A two stage solid phase extraction (SPE) procedure and a semi-preparative HPLC method were developed utilizing various mechanisms of separation. The major metabolites proved to be isomeric glucuronides of the benzodioxane moiety hydroxylated at positions 6 or 7 and {2-(2-carboxyethyl)-3(2H)-pyridazinone}. 相似文献
6.
Application of stir bar sorptive extraction for wine analysis 总被引:4,自引:0,他引:4
Yoji?Hayasaka Kevin?MacNamara Gayle?A.?Baldock Randell?L.?Taylor Alan?P.?PollnitzEmail author 《Analytical and bioanalytical chemistry》2003,375(7):948-955
Stir bar sorptive extraction (SBSE) coupled with gas chromatography/mass spectrometry (GC/MS) was used to analyse wine samples for three applications: flavour and compositional analysis; 2,4,6-trichloroanisole (TCA), a common off-aroma in wine; and agrochemicals. SBSE was found to be orders of magnitude more sensitive than modern conventional methodology, allowing for lower detection and quantitation levels, and improved confirmation of identity; SBSE often gave better signal to noise in scan mode than other methods in selective ion monitoring (SIM) mode. With the help of their characteristic mass spectra all agrochemicals could be identified unambiguously at concentrations of 10 microg L(-1) in wine and a further 100 constituents were detected in a Cabernet Sauvignon sample. Thus it is now possible to analyse complex samples such as wine by scan mode, with better confirmation of identity, and without sacrificing sensitivity, where previously SIM methodology had to be used. 相似文献
7.
O.?V.?OshurkovaEmail author V.?P.?Nesterov 《Russian Journal of Electrochemistry》2005,41(12):1325-1329
The separation of a mixture containing anions of nine organic acids is investigated on an instrument for capillary isotachophoresis with an optical detector for the registration of boundaries. The separation is conducted in concentrated solutions of sodium salts. A counterflow is used during the separation. 相似文献
8.
P.M.?Kosaka Y.?Kawano M.C.?Salvadori D.F.S.?PetriEmail author 《Cellulose (London, England)》2005,12(4):351-359
The adsorption of cellulose acetate (CA), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) from solutions
prepared in acetone onto silicon wafers led to ultrathin films, which were characterized by ellipsometry, atomic force microscopy
(AFM) and contact angle measurements. The polysaccharides films were characterized in the air just after their formation and
after annealing at temperatures higher than their glass transition temperature or melt temperature. The films thickness close
to 2 nm and surface roughness did not vary significantly upon annealing. AFM images revealed the presence of small clumps
dispersed on a homogeneous layer, which covered completely the Si wafers. Such topographic details were also observed after
annealing. However, upon annealing the films surfaces changed from hydrophilic to hydrophobic, evidencing molecular re-orientation
at the solid–air interface. The adhesion of bovine serum albumin (BSA) and lipase onto the cellulose esters films was quantified
in order to evaluate the possibility of applying such films as selective support for biomolecules. 相似文献
9.
Mycotoxins are secondary metabolites, formed by the action of fungi on agricultural crops in the field or during storage. These metabolites are highly toxic to animals and humans and high levels have been measured in agricultural crops. In order to evaluate human risks due to ingestion of mycotoxin-contaminated food different methods have been developed for analysis of mycotoxins in cereals and maize. In this project the focus was on mycotoxins in agricultural soil and the fate of these toxins in the soil-water-plant system. Two different mycotoxins were selected in the study: zearalenone (ZON) produced by species of Fusariumor Aspergillusand ochratoxin A (OTA) produced by species of Penicillium. We developed a method for analysis of these toxins in soil. Soil samples were extracted with methanol-water (9:1) and purified by solid-phase extraction (SPE, C8-columns). The final extract was analysed using high-pressure liquid chromatography (HPLC) with fluorescence detection. A Phenyl Hexyl column was used to separate the toxins. The detection limits obtained were 0.1 and 1.0 microg kg(-1) dry weight (dw) for OTA and ZON, respectively. The developed method has been used for analysis of different soils in connection with growth chamber experiments. The soil types used in the growth chamber experiments were a sandy soil, a sandy clay soil, and a soil with high content of organic matter. The recovery was determined as 85.8 and 93.4% and the repeatability to 5.1 and 12.8% for OTA and ZON, respectively. The reproducibility obtained was 8.5 and 15.0% for soil samples, representing concentration levels from 0.2-30 microg kg(-1) dw (OTA) and from 1.0-100 microg kg(-1) dw (ZON). 相似文献
10.
Irina Odinets Tamás Körtvélyesi Tamás Kégl László Kollár György Keglevich 《Transition Metal Chemistry》2007,32(3):299-303
In the series of 1-(2,4,6-trialkylphenyl-)3-methyl-1H-phospholes (1a–c) that are to a certain extent of aromaticity, only the isopropyl substituted one (1a) entered into reaction with dimeric (pentamethylcyclopentadienyl)rhodium dichloride to afford Rh(III) complex (2a) in a reversible manner. After a careful workup, (2a) could be prepared and characterized whose stereostructure was elucidated by B3LYP/3–21G*, B3LYP/6–31G* and LANL2DZ calculations.
Complex (2a) as a preformed catalyst, as well as the Rh(acac)(CO)2 + 2(1a) in situ catalytic system were useful in the hydroformylation of styrene and gave the branched aldehyde in regioselectivities of 65–96%. 相似文献