全光纤反射式马赫曾德尔干涉型多波长滤波器的研究

对反射式的马赫－曾德尔干涉型多波长滤波器的性能作了较详细的研究，得出了两个耦合器的分光比和两臂的臂长差对其输出谱线的影响，结论对设计制作不同性能指标的该型多波长滤波器具有重要的参考价值。实验上用光纤熔融拉锥法制作了该种器件，实验结果与理论相符合。     

Study on Dual Bragg Wavelength Fiber Grating and Its Tuning Scheme

Because of package, a single FBG has dual Bragg wavelength. One is sensitive to stress and the other is sensitive to temperature. By using the special mechanism, the wavelengths can be tuned by stress and temperature respectively.     

Studies of the reaction of dimethyltin dichloride with mercaptoacetic acid in the presence of amines and crystal structure of [(n-Pr)3NH][Me2Sn(μ-SCH2COO)Cl]

A series of new five-coordinated ionic organotin(IV) complexes with general formula [Q][Me₂Sn(μ²-SCH₂COO)Cl](Q = diethylammonium, triethylammonium, di-i-propylammonium, tripropylammonium, tri-n-butylammonium, pyrimidium, 3-picolinium, methylphenylammonium, dimethylphenylammonium) were synthesized by the reaction of mercaptoacetic acid with dimethyltin dichloride in the presence of an organic base. These complexes have been characterized by elemental analyses, IR and ¹H NMR spectroscopies. The crystal structure of [(n-Pr)₃NH][Me₂Sn(μ²-SCH₂COO)Cl] was determined by X-ray crystallography. The structure consists of an anion part, and a tri-n-propylammonium cation part as a counterion. The tin atom has a distorted cis-tbp geometry with two carbon and one sulfur atoms occupying the equatorial positions and the O atom and Cl atom occupying the axial positions. The organotin anion and its counterion are connected through a hydrogen bond between the N atom in the ammonium and the O atom of the carbonyl group with a N-O length of 2.766 Å.     

部分还原二氧化钛的NMR和EPR研究

Partially reduced TiO₂ nanomaterials have attracted significant interest because of their visible-light activity for catalysis and photodegradation. Herein, we prepared a partially reduced anatase TiO₂ (Re-A-TiO₂) nanoparticle material using a fast combustion method, demonstrating good activity toward decomposing methyl orange under visible light irradiation. The surface structure of the prepared material, after being surface-selectively ¹⁷O-labeled with H₂¹⁷O (¹⁷O-enriched water), was studied via ¹⁷O and ¹H solid-state magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy and electron paramagnetic resonance (EPR) spectroscopy, and the obtained results were compared to those of non-reduced anatase TiO₂ (A-TiO₂). The EPR results showed that the concentrations of paramagnetic species (i.e., oxygen vacancies (OV) and Ti³⁺) in Re-A-TiO₂ were much higher than that in A-TiO₂, while the former was associated with a higher OV/Ti³⁺ ratio. The intensities of the EPR signals were significantly affected by the adsorbed water, and this phenomenon was explored in combination with ¹H NMR spectroscopy. The ¹H species on Re-A-TiO₂ appeared at larger chemical shifts, denoting the increased acidity of the sample, and these ¹H species on Re-A-TiO₂ were more difficult to remove than those on A-TiO₂. On the other hand, different features were observed for the signals arising from the two-coordinated oxygen atoms (μ₂-O) in ¹⁷O NMR, suggesting a typical anatase TiO₂(101) surface on A-TiO₂, but a more complex surface environment for Re-A-TiO₂. Furthermore, a larger amount of hydroxyl groups (OH) were observed on Re-A-TiO₂ compared to that on A-TiO₂, indicating a larger proportion of exposed (001) facets on Re-A-TiO₂. However, the μ₂-O signals broadened and became similar when the drying temperature was increased to 100 ℃, indicating a non-faceted anatase TiO₂ surface in such conditions. Based on the EPR and NMR results, a significant fraction of the OH species is believed to be formed from the reaction of the paramagnetic centers and adsorbed water molecules. The ¹H→¹⁷O cross polarization (CP) MAS and two-dimensional heteronuclear correlation (2D HETCOR) NMR spectra were used to verify the spatial proximity of the hydrogen and oxygen species, confirming the spectral assignments of a strongly adsorbed water and one type of surface OH species. In particular, the ¹H NMR signals at approximately 11 ppm were ascribed to the hydrogen species in the intramolecular hydrogen bond. In summary, this study investigated the paramagnetic species and surface structure of anatase TiO₂ materials by combining EPR along with ¹H and ¹⁷O solid-state NMR spectroscopy. The differences in the surface structures of Re-A-TiO₂ and A-TiO₂ should be closely related to their different properties toward the photodegradation of methyl orange.     

Enhanced nonlinearity in photonic crystal fiber by germanium doping in the core region

Germanium doping in silica can be used as a method for nonlinearity enhancement.Properties of the enhanced nonlinearity in photonic crystal fiber(PCF)with a GeO2-doped core are investigated theoretically by using all-vector finite element method.Numerical result shows that the nonlinear coefficient of PCF is greatly enhanced with increasing doping concentration,furthermore,optimal radius of the doped region should be considered for the desired operating wavelength.     

窄带光纤光栅的写入

改进相位掩模法写入光栅的装置,提高其机械稳定性和温度稳定性,不仅提高了光纤光栅的反射率,而且降低了带宽,特别是能在国产的光敏光纤上写出了大于99%反射率和小于02nm带宽的高质量的光纤光栅.这种光栅特别适用于光纤光栅传感方面的应用。     

Coupling and decoupling of dual-core photonic bandgap fibers

Coupling characteristics of dual-core photonic bandgap fibers with triangular photonic crystal cladding are investigated by use of a vector plane-wave expansion method and a vector finite-element method. We demonstrate the eigenmodes and the coupling length for two orthogonal polarizations. A decoupling phenomenon is found at a certain wavelength in this fiber configuration. The decoupling effect is attributed to the effect of surface modes on the eigenmodes. The decoupling wavelength decreases as the ratio of core radius to cladding air-hole pitch increases from 1.05 to 1.15.     

带宽调制型单光纤光栅温变无补偿位移传感

报道了利用反射谱带宽调制和光强差分探测技术实现单一光纤光栅温变无补偿位移精确测量的新方法。设计了一种结构新颖的曲臂梁位移传感装置,结合光波导理论与材料力学原理分析了光纤光栅在高斯应变作用下光栅反射谱侧向梯度展宽的成因,理论推导了特殊结构梁在外力作用下光栅反射谱带宽/反射光强与压力之间的响应关系。光栅反射谱侧向梯度展宽的同时反射光强线性增加,利用光强差分检测方法消除光源出光抖动的影响,提高了位移测量精度。基于带宽调制的光纤光栅位移传感方法免受温度变化的影响,在-10℃~80℃的温度变化范围内,测量误差小于1.2%,实现了单光纤光栅温变无补偿位移测量。     

一类特殊的无限非正则p-群

利用有限正则p-群和局部幂零群的理论,得到:如果G是可解的非正则p-群,且G的每一个无限真子群是正则的,那么群G是秩为p-1的可除阿贝尔群被循环群的扩张.     

Studies on the electrochemical and dopamine sensing properties of AgNP-modified carboxylated cellulose nanocrystal-doped poly(3,4-ethylenedioxythiophene)

Ionics - Carboxylated cellulose nanocrystals (CNCC) were synthesized by treating microcrystalline cellulose with ammonium persulfate. Silver nanoparticles (AgNPs) were prepared on the surface of...