Kinetics of methanation of carbon dioxide on a nickel catalyst

The kinetics of hydrogenation of CO₂ to methane on an NKM-4A nickel-containing catalyst was studied in a wide range of change of partial pressures of hydrogen and carbon dioxide at 498–543 K. It was shown that when hydrogen is replaced by deuterium in the reaction, a reverse kinetic isotope effect is observed. The kinetic equation of the reaction was derived and a stepwise scheme is proposed which includes the involvement of oxygen-containing intermediates in the process without preliminary dissociation of CO₂.Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 26, No. 5, pp. 620–624, September–October, 1990.     

The Weinberg gluonic operator and the CP-odd nucleon coupling constant

The values of the CP-odd nucleon-nucleon coupling constants arising due to the induced three gluonic operator are estimated for different CP-violating models.This work was carried out under auspices of Monbusho as a foreign visiting scientist     

Possible parity-violating effects in ternary fission

Possible parity-violating effects are considered in ternary fission and estimated for different assumptions regarding the mechanism of the process. Here we shall consider differentP-violating effects in neutron-induced ternary fission. As shown in [1], all theP-violating effects in nuclear reactions proceeding via the compound-nucleus stage bear some features in common. All of them are characterized by the factors of dynamical enhancement (caused by the large density of compound-nucleus states), resonance enhancement defined by the ratio of the level spacing for the states of opposite of opposite parity to the width these states [1], and structural enhancement (or hindrance) factors in the exit or entrance channels. Since we believe that neutron-induced ternary fission proceeds via the compound-nucleus stage, one can apply here the basic methods and results [1] used for binary fission, with some modifications necessitated by the presence of 3 particles in the exit channel. Since, however, the analytic analysis of the 3-body problem is rather abstruse and difficult even in classical mechanics, we shall use some reasonable hypothesis about the mechanism of ternary fission in order to obtain the order of magnitude estimates forP-violating effects.     

Dispersion of doppleron-phonon modes in strong coupling regime

The dispersion equation for doppleron-phonon modes was constructed and solved analytically in the strong coupling regime. The Fermi surface model proposed previously for calculating the doppleron spectrum in an indium crystal was used. It was shown that in the vicinity of doppleron-phonon resonance, the dispersion curves of coupled modes form a gap qualitatively different from the one observed under helicon-phonon resonance: there is a frequency interval forbidden for existence of waves of definite circular polarization depending upon direction of the external DC magnetic field. The physical reason for it is interaction of the waves which have oppositely directed group velocities.     

Tunneling Relaxation Mechanisms of the Jahn–Teller Complexes in a CaF2:Cr2+ Crystal

JETP Letters - The temperature dependences of attenuation and the velocity of ultrasonic waves at frequencies of 26–158 MHz in a CaF2 fluorite crystal at the substitution of...     

Temperature Hysteresis in CO Oxidation on Copper Oxide Catalyst Applied to a Steel Gauze

The temperature hysteresis during the heterogeneous catalysis was studied by an example of model reaction of CO oxidation on copper oxide catalyst applied to a stainless steel gauze.     

Algebraic and Geometric Properties of Matrix Solutions of Nonlinear Wave Equations

We improve the construction of exact matrix solutions for nonlinear wave equations by using unitary anti-Hermitian and anticommuting matrices. We prove the theorem that constructs the matrix functions u _n satisfying the nonlinear wave equation for a set of special potentials. In this case, the graph of complex solution u ₁ has a soliton-like form with a finite number of coils. Exponential representation of matrix solutions u _n is associated with continuous rotations that can be used for describing intrinsic rotations and state changes of elementary particles. We also prove the theorem on the decomposition of continuous rotation (described by solution u ₂) onto three simultaneous rotations about coordinate vectors. Each of the three constructed matrix solutions u ₃ is also decomposed into the triplet of elementary matrix solutions.     

Parity non-conservation effects in neutron elastic scattering reactions

Energy dependence of parity non-conservation effects is derived for neutron elastic scattering on nuclei: emission asymmetry and the rotation of the polarization plane for the polarized neutron beam and longitudinal polarization for unpolarized neutrons. Both potential scattering and scattering through the compound-nucleus resonances (multi-level approximation) are taken into account. The expressions obtained are compared with experimental data on thermal neutron scattering.