Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti(III)/Ti(IV)

The first 3-D open-framework TiGaPO complex, constructed from Ti(III)O(6), Ti(IV)O(6), GaO(4), and PO(4) polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure.     

The mass spectra of substituted 2-methylbenzophenones

The mass spectra of some methoxy and methyl derivatives of 2-methylbenzophenone have been examined. Loss of a substituents from 3′-and 4′-positions as well as the previously known loss from 2′-positions are important fragmentation processes. Thus, these fragmentations are of little use in locating substituents on benzophenones of unknown structure. Deuterium labelling shows the [M - 1]⁺ ion from 3′,4,4′,5,5′-pentamethoxy-2-methyl benzophenone to be due largely to loss of hydrogen from 2′- and 6′-positions.     

Two-soliton interaction as an elementary act of soliton turbulence in integrable systems

Two-soliton interactions play a definitive role in the formation of the structure of soliton turbulence in integrable systems. To quantify the contribution of these interactions to the dynamical and statistical characteristics of the nonlinear wave field of soliton turbulence we study properties of the spatial moments of the two-soliton solution of the Korteweg–de Vries (KdV) equation. While the first two moments are integrals of the KdV evolution, the 3rd and 4th moments undergo significant variations in the dominant interaction region, which could have strong effect on the values of the skewness and kurtosis in soliton turbulence.     

Emergence of Envelope Solitary Waves from Initial Localized Pulses within the Ostrovsky Equation

Radiophysics and Quantum Electronics - We study the emergence of steady wave packets in the form of envelope solitary waves (envelope solitons) which evolve from localized pulse-type initial...     

Rogue internal waves in the ocean: Long wave model

Rogue waves can be categorized as unexpectedly large waves, which are temporally and spatially localized. They have recently received much attention in the water wave context, and also been found in nonlinear optical fibers. In this paper, we examine the issue of whether rogue internal waves can be found in the ocean. Because large-amplitude internal waves are commonly observed in the coastal ocean, and are often modeled by weakly nonlinear long wave equations of the Korteweg-de Vries type, we focus our attention on this shallow-water context. Specifically, we examine the occurrence of rogue waves in the Gardner equation, which is an extended version of the Korteweg-de Vries equation with quadratic and cubic nonlinearity, and is commonly used for the modelling of internal solitary waves in the ocean. Importantly, we choose that version of the Gardner equation for which the coefficient of the cubic nonlinear term and the coefficient of the linear dispersive term have the same sign, as this allows for modulational instability. From numerical simulations of the evolution of a modulated narrow-band initial wave field, we identify several scenarios where rogue waves occur.     

Dispersion management for solitons in a Korteweg-de Vries system

The existence of "dispersion-managed solitons," i.e., stable pulsating solitary-wave solutions to the nonlinear Schrodinger equation with periodically modulated and sign-variable dispersion is now well known in nonlinear optics. Our purpose here is to investigate whether similar structures exist for other well-known nonlinear wave models. Hence, here we consider as a basic model the variable-coefficient Korteweg-de Vries equation; this has the form of a Korteweg-de Vries equation with a periodically varying third-order dispersion coefficient, that can take both positive and negative values. More generally, this model may be extended to include fifth-order dispersion. Such models may describe, for instance, periodically modulated waveguides for long gravity-capillary waves. We develop an analytical approximation for solitary waves in the weakly nonlinear case, from which it is possible to obtain a reduction to a relatively simple integral equation, which is readily solved numerically. Then, we describe some systematic direct simulations of the full equation, which use the soliton shape produced by the integral equation as an initial condition. These simulations reveal regions of stable and unstable pulsating solitary waves in the corresponding parametric space. Finally, we consider the effects of fifth-order dispersion. (c) 2002 American Institute of Physics.     

Water Wave Packets Over Variable Depth

In this paper, we develop higher‐order nonlinear Schrödinger equations with variable coefficients to describe how a water wave packet will deform and eventually be destroyed as it propagates shoreward from deep to shallow water. It is well‐known that in the framework of the usual nonlinear Schrödinger equations, a wave packet can only exist in deep water, more precisely when kh > 1.363 , where k is the wavenumber and h is the depth. Using a combination of asymptotic analysis and numerical simulations we find that in the framework of the higher‐order nonlinear Schrödinger equations, the wave packet can penetrate into shallow water kh < 1.363 or not even reach kh > 1.363 , depending on the sign of the initial value in deep water of a certain parameter of the wave packet that measures its speed.     

Asymptotic description of solitary wave trains in fully nonlinear shallow-water theory

We derive an asymptotic formula for the amplitude distribution in a fully nonlinear shallow-water solitary wave train which is formed as the long-time outcome of the initial-value problem for the Su–Gardner (or one-dimensional Green–Naghdi) system. Our analysis is based on the properties of the characteristics of the associated Whitham modulation system which describes an intermediate “undular bore” stage of the evolution. The resulting formula represents a “non-integrable” analogue of the well-known semi-classical distribution for the Korteweg–de Vries equation, which is usually obtained through the inverse scattering transform. Our analytical results are shown to agree with the results of direct numerical simulations of the Su–Gardner system. Our analysis can be generalised to other weakly dispersive, fully nonlinear systems which are not necessarily completely integrable.