排序方式: 共有14条查询结果,搜索用时 31 毫秒
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Gorce JP Bovey D McDonald PJ Palasz P Taylor D Keddie JL 《The European physical journal. E, Soft matter》2002,8(4):421-429
We present a systematic study of the vertical uniformity of water distribution during the drying of waterborne colloidal films,
testing the predictions of a Peclet number Pe defined for this system. Pe indicates the relative contributions of water evaporation and Brownian diffusion in determining the concentration profile
in the vertical direction (i.e. normal to the substrate). When Pe < 1, the water concentration in films cast from an alkyd emulsion is found via magnetic-resonance profiling to be uniform with depth, which is consistent with expectations. When Pe > 1, a gradient in the water concentration develops, with less water near the interface with air. The water profiles reveal
that the alkyd particles do not coalesce immediately upon contact in close-packing. At later times, a concentrated surface
layer develops, but particles are not coalesced in this layer to form a continuous “skin”, but rather the structure is likely
to be that of a biliquid foam.
Received 20 March 2002 and Received in final form 12 June 2002 相似文献
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Fontaine-Gautrelet C Krafft JM Gorce O Villain F Djéga-Mariadassou G Thomas C 《Physical chemistry chemical physics : PCCP》2006,8(32):3732-3740
The identification of a Rh-oxidised species of a Rh(0.29)/Ce0.68Zr0.32O2 catalyst that exhibits peculiar CO-O2 kinetics [I. Manuel, J. Chaubet, C. Thomas, H. Colas, N. Matthess and G. Djéga-Mariadassou, J. Catal. 2004, 224, 269] is addressed. For this purpose, various catalysts are studied by XANES, CO- and N2-FTIR, and benzene hydrogenation. The results obtained, particularly from N2-FTIR, which is, to our knowledge, reported for the first time on this kind of catalyst, suggest that Rh is mainly stabilised as electron-deficient clusters (Rhndelta+) on a Rh(0.29)/Ce0.68Zr0.32O2 catalyst after reduction at 500 degrees C under H2. The existence of these species, which may be caused by either electron perturbation induced on the metal by the reduced support or electron withdrawal from the metal clusters by an inductive effect of the neighbouring Cl anions, is also revealed through CO-FTIR experiments. In the presence of CO, however, evidence of RhI(CO)2 species is also provided. 相似文献
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The structural and electronic transport properties of La1−x
Ce
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MnO3 (x=0.0–1.0) have been studied. All the samples exhibit orthorhombic crystal symmetry and the unit cell volume decreases with
Ce doping. They also make a metal-insulator transition (MIT) and transition temperature increases with increase in Ce concentration
up to 50% doping. The system La0.5Ce0.5MnO3 also exhibits MIT instead of charge-ordered state as observed in the hole doped systems of the same composition. 相似文献
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Homa Nikbakht Michle Wigger Malcolm Egan Shlomo Shamai Jean-Marie Gorce H. Vincent Poor 《Entropy (Basel, Switzerland)》2022,24(5)
Fifth generation mobile communication systems (5G) have to accommodate both Ultra-Reliable Low-Latency Communication (URLLC) and enhanced Mobile Broadband (eMBB) services. While eMBB applications support high data rates, URLLC services aim at guaranteeing low-latencies and high-reliabilities. eMBB and URLLC services are scheduled on the same frequency band, where the different latency requirements of the communications render their coexistence challenging. In this survey, we review, from an information theoretic perspective, coding schemes that simultaneously accommodate URLLC and eMBB transmissions and show that they outperform traditional scheduling approaches. Various communication scenarios are considered, including point-to-point channels, broadcast channels, interference networks, cellular models, and cloud radio access networks (C-RANs). The main focus is on the set of rate pairs that can simultaneously be achieved for URLLC and eMBB messages, which captures well the tension between the two types of communications. We also discuss finite-blocklength results where the measure of interest is the set of error probability pairs that can simultaneously be achieved in the two communication regimes. 相似文献
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J D'hooge B Bijnens J Nuyts J M Gorce D Friboulet J Thoen F Van de Werf P Suetens 《The Journal of the Acoustical Society of America》1999,106(2):1126-1133
A study is presented in which the influence of the pressure amplitude of the incident pulse on the estimated frequency dependency of the attenuation coefficient is shown. First, the effect is demonstrated with a simple theoretical model for both transmission and reflection measurements. Simulations show that for both measurement techniques a high-amplitude incident pulse results in a biased estimate of the attenuation coefficient due to nonlinear interaction of the different frequency components of the incident pulse. It is shown that in transmission and reflection measurements the biases have opposite signs. The effect of bandwidth, central frequency, and phase of the incident pulse on this bias is investigated. Second, the effect is demonstrated both in vitro, using a broadband through-transmission substitution technique on a tissue mimicking gelatine phantom, and in vivo, using reflection measurements with standard clinical equipment. The experimental results agree well with the theoretical model. The relevance of this study for ultrasonic tissue characterization is shown. 相似文献
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Jérôme JP. Leon 《Letters in Mathematical Physics》1981,5(1):75-80
We establish a transformation which connects the potentials of the one-dimensional Dirac and Klein-Gordon operators. This transformation links the solutions of the nonlinear evolution equations solvable by means of the two inverse spectral transforms which use the Dirac and Klein-Gordon direct and inverse spectral problems. 相似文献