全文获取类型
收费全文 | 13877篇 |
免费 | 2330篇 |
国内免费 | 1596篇 |
专业分类
化学 | 9804篇 |
晶体学 | 133篇 |
力学 | 596篇 |
综合类 | 171篇 |
数学 | 1461篇 |
物理学 | 5638篇 |
出版年
2024年 | 28篇 |
2023年 | 295篇 |
2022年 | 372篇 |
2021年 | 454篇 |
2020年 | 541篇 |
2019年 | 547篇 |
2018年 | 468篇 |
2017年 | 426篇 |
2016年 | 652篇 |
2015年 | 654篇 |
2014年 | 753篇 |
2013年 | 946篇 |
2012年 | 1287篇 |
2011年 | 1325篇 |
2010年 | 850篇 |
2009年 | 798篇 |
2008年 | 950篇 |
2007年 | 870篇 |
2006年 | 734篇 |
2005年 | 640篇 |
2004年 | 474篇 |
2003年 | 366篇 |
2002年 | 378篇 |
2001年 | 319篇 |
2000年 | 337篇 |
1999年 | 292篇 |
1998年 | 265篇 |
1997年 | 251篇 |
1996年 | 245篇 |
1995年 | 220篇 |
1994年 | 171篇 |
1993年 | 170篇 |
1992年 | 121篇 |
1991年 | 124篇 |
1990年 | 104篇 |
1989年 | 75篇 |
1988年 | 51篇 |
1987年 | 45篇 |
1986年 | 43篇 |
1985年 | 49篇 |
1984年 | 26篇 |
1983年 | 25篇 |
1982年 | 22篇 |
1981年 | 8篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1962年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
Kai Cheng Xiao-Shuai Zhang Jie An Cheng Li Ruo-Yun Zhang Run Ye Prof. Dr. Bang-Jiao Ye Prof. Dr. Bo Liu Prof. Dr. Yuan-Di Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(31):7553-7560
Given their superior penetration depths, photosensitizers with longer absorption wavelengths present broader application prospects in photodynamic therapy (PDT). Herein, Ag2S quantum dots were discovered, for the first time, to be capable of killing tumor cells through the photodynamic route by near-infrared light irradiation, which means relatively less excitation of the probe compared with traditional photosensitizers absorbing short wavelengths. On modification with polydopamine (PDA), PDA-Ag2S was obtained, which showed outstanding capacity for inducing reactive oxygen species (increased by 1.69 times). With the addition of PDA, Ag2S had more opportunities to react with surrounding O2, which was demonstrated by typical triplet electron spin resonance (ESR) analysis. Furthermore, the PDT effects of Ag2S and PDA-Ag2S achieved at longer wavelengths were almost identical to the effects produced at 660 nm, which was proved by studies in vitro. PDA-Ag2S showed distinctly better therapeutic effects than Ag2S in experiments in vivo, which further validated the enhanced regulatory effect of PDA. Altogether, a new photosensitizer with longer absorption wavelength was developed by using the hitherto-unexplored photodynamic function of Ag2S quantum dots, which extended and enhanced the regulatory effect originating from PDA. 相似文献
3.
Yao Yuan Chen Ying Chen Jianyong Gong Yulie 《Journal of Thermal Analysis and Calorimetry》2021,144(6):2357-2367
Journal of Thermal Analysis and Calorimetry - Based on innovative design, a liquid–vapor separation plate condenser with excellent heat transfer performance is invented. It takes less time to... 相似文献
4.
Tianyu Gong Longhai Guo Jun Ye Lifan He Teng Qiu Xiaoyu Li 《Journal of polymer science. Part A, Polymer chemistry》2021,59(16):1807-1820
The implementation of covalent adaptable networks (CANs) in general resin system is becoming attractive. In this work, we propose a simple post-curing strategy based on the core-shell structured acrylate latex for the achievement on both the improved general performance and the CANs characteristics in latex films. The building to the CANs was relied on the introduction of 4,4′-diaminophenyl disulfide as the curing agent, which cured the acetoacetoxy decorated shell polymer through the ketoamine reaction. The metathesis reaction of aromatic disulfides in the crosslinking segments enabled the thermally induced dynamic behavior of the network as revealed in the stress relaxation tests by comparison with other diamine crosslinking agents without the incorporation of disulfide. The synergism of the dynamic crosslinking of the shell polymer and static crosslinking in the core polymer contributed to the improved mechanical strength (15 MPa, strain% = 250%) and the suppressed water adsorption (~1% in 24 h of soaking) of the latex film, which exhibited above 90% of recovery in both strength and strain from a cut-off film damage within 1 h at 80°C. Moreover, the cured latex film could be recycled, and 75% of the mechanical performance was regained after three fragmentation-hot-pressing cycles. These, in addition with the feasible and environmental friendly characteristics, suggest a sustainable paradigm toward the smart thermosetting latex polymers. 相似文献
5.
6.
Yu Wang Xin-jing Zhao Rong-Jing Wei Gui-jie Liang Kang Wang Yuan-zhi Tan Ye Yang 《化学物理学报(中文版)》2021,34(5):591-597
The intermolecular interaction determines the photophysical properties of the organic aggregates, which are critical to the performance of organic photovoltaics. Here, excitonic coupling, an important intermolecular interaction in organic aggregates, between the π-stacking graphene quantum dots is studied by using transient absorption spectroscopy. We find that the spectral evolution of the ground state bleach arises from the dynamic variation of the excitonic coupling in the excited π-stacks. According to the spectral simulations, we demonstrate that the kinetics of the vibronic peak can be exploited as a probe to measure the dynamics of excitonic coupling in the excited π-stacks. 相似文献
7.
Hejia Hu Linlin Wu Mei Li Cun Xue Guangcheng Wang Siying Chen Yong Huang Lin Zheng Aimin Wang Yueting Li Zipeng Gong 《Biomedical chromatography : BMC》2020,34(1):e4714
Eucommia ulmoides Oliv. (E. ulmoides) is a valuable and nourishing medicinal herb in China that has been used in the treatment of hypertension. Given the fact that most traditional Chinese medicine is mainly used to treat disease, investigating the pharmacokinetics of traditional Chinese medicines in the pathological state is more useful than that in the normal state. However, the differences in the absorption kinetics of active ingredients of E. ulmoides extract between pathological and physiological conditions have not been reported. Therefore, in this study, the rat intestinal in situ circulatory perfusion model was used to investigate the differences in absorption kinetics of seven active ingredients of E. ulmoides extract in normal and spontaneously hypertensive rats, namely, genipinic acid, protocatechuic acid, neochlorogenic acid, chlorogenic acid, cryptochlorogenic acid, (+)-pinoresinol di-O-β-D -glucopyranoside and (+)-pinoresinol 4′-O-β-D -glucopyranoside. Our results indicate that the pathological state of spontaneous hypertension may change the absorption of active components of E. ulmoides extracts, and these findings may provide a reference for improving the rational use of E. ulmoides in the clinic. 相似文献
8.
9.
A 1.5-μm eye-safe, 3-D scanning, and compact Mie LIght Detection and Ranging (LIDAR) is presented. The transmitter of the LIDAR is based on a KTA optical parameter oscillator (OPO) resonator. For detecting return signals, an InGaAs APD is used. The all solid-state OPO laser transmitter has the feature of small volume and lightweight, which allows a 165-lb compact eye-safe scanning LIDAR to be constructed. A system simulation using our own model was conducted to direct the system development. A method to solve the problem with small active area APD detectors was developed and described. The preliminary field-test measurement results indicated that the LIDAR has the capability to detect aerosols and clouds in lower atmospheres up to three dimensions. 相似文献
10.