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排序方式: 共有434条查询结果,搜索用时 390 毫秒
1.
Girard V Farrenq R Sorokin E Sorokina IT Guelachvili G Picqué N 《Chemical physics letters》2006,419(4-6):584-588
The spectral dynamics of a mid-infrared multimode Cr(2+):ZnSe laser located in a vacuum sealed chamber containing acetylene at low pressure is analyzed by a stepping-mode high-resolution time-resolved Fourier transform interferometer. Doppler-limited absorption spectra of C(2)H(2) in natural isotopic abundance are recorded around 4000 cm(-1) with kilometric absorption path lengths and sensitivities better than 3 10(-8) cm(-1). Two cold bands are newly identified and assigned to the ν(1)+ν(4) (1) and ν(3)+ν(5) (1) transitions of (12)C(13)CH(2). The ν(1)+ν(5) (1) band of (12)C(2)HD and fourteen (12)C(2)H(2) bands are observed, among which for the first time ν(2)+2ν(4) (2)+ν(5) (-1). 相似文献
2.
Denis Prat Françoise Benedetti Lahlou Nait Bouda Gilles Franc Girard 《Tetrahedron letters》2004,45(4):765-768
An industrial synthesis of 11β-aryl-estrone derivatives is described, based on the 1,4-addition of the aryl side-chain, as a cuprate, on to a mixture of allylic 5(10) alpha and beta epoxides, followed by hydrolysis and subsequent aromatization. 相似文献
3.
Transverse displacement at total reflection near the grazing angle: a way to discriminate between theories 总被引:1,自引:0,他引:1
F. Pillon H. Gilles S. Girard M. Laroche O. Emile 《Applied physics. B, Lasers and optics》2005,80(3):355-357
The transverse shift is observed and precisely measured at total internal reflection on a dielectric interface for a circularly polarized light beam when the incident angle is scanned from the critical angle up to the grazing angle close to 90°. The experimental results show with no doubt that the transverse displacement exists far away from the critical angle and only vanishes at grazing angle. A comparison with theories also allows a discrimination between the most different theoretical models traditionally used to interpret physically this effect. 相似文献
4.
A. Girard 《Numerische Mathematik》1989,56(1):1-23
Summary We propose a fast Monte-Carlo algorithm for calculating reliable estimates of the trace of the influence matrixA
involved in regularization of linear equations or data smoothing problems, where is the regularization or smoothing parameter. This general algorithm is simply as follows: i) generaten pseudo-random valuesw
1, ...,w
n
, from the standard normal distribution (wheren is the number of data points) and letw=(w
1, ...,w
n
)
T
, ii) compute the residual vectorw–A
w, iii) take the normalized inner-product (w
T
(w–A
w))/(w
T
w) as an approximation to (1/n)tr(I–A
). We show, both by theoretical bounds and by numerical simulations on some typical problems, that the expected relative precision of these estimates is very good whenn is large enough, and that they can be used in practice for the minimization with respect to of the well known Generalized Cross-Validation (GCV) function. This permits the use of the GCV method for choosing in any particular large-scale application, with only a similar amount of work as the standard residual method. Numerical applications of this procedure to optimal spline smoothing in one or two dimensions show its efficiency. 相似文献
5.
Dupieux P Alard JP Augerat J Babinet R Bastid N Brochard F Charmensat P De Marco N Fanet H Fodor Z Fraysse L Girard J Gorodetzky P Gosset J Laspalles C Lemaire MC L'Hôte D Lucas B Marroncle J Montarou G Parizet MJ Poitou J Qassoud D Racca C Schimmerling W 《Physics letters. [Part B]》1988,200(1-2):17-21
Proton-proton small angle correlations have been measured in neon-nucleus collisions, using the 4 pi detector Diogene, at 400 and 800 MeV per nucleon incident energies. Values of the size of the emitting region are obtained by comparison with the Koonin formula, taking into account the biases of the apparatus. The dependence of the density on target mass and incident energy is also analysed. 相似文献
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Methylenecyclohexanes, prepared in excellent yield by Corey and Chaykovsky then Cornforth reactions, give on oxymercuration followed by reductive demercuration tertiary alcohols resulting from axial attack by solvent. The attack takes place trans to the substiuent when the latter is at the 2 position. α-Hydroxy or methoxy compounds behave similarly to each other. For acetoxy compounds, the cis alcohols are obtained preferentially, by intramolecular attack of acetoxy group on the mercurinium ion intermediate. The results can be explained satisfactorily on the assumption that the factors inducing stereochemistry are short distance interactions. 相似文献