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排序方式: 共有72条查询结果,搜索用时 15 毫秒
1.
Eggenhffner R. Masini R. Bellingeri E. Cimberle M. R. Ferdeghini C. Costa G. A. Kaiser E. Signorelli E. 《Il Nuovo Cimento D》1994,16(10):1659-1664
Il Nuovo Cimento D - The formation of Hg-based HTSC materials was investigated through the development of non-conventional techniques. The former was based on a singlestep synthesis at temperatures... 相似文献
2.
J. C. Masini Oswaldo E. S. Godinho Luiz M. Aleixo 《Fresenius' Journal of Analytical Chemistry》1998,360(1):104-111
A linearization method based on modified Gran functions, and a general nonlinear regression program were used to study potentiometric
titration curves of denatured ovalbumin and lysozyme in 6 mol L–1 guanidine hydrochloride medium with the aim of determining the ionizable species. With both numerical techniques it was possible
to determine the sum of the carboxylic groups, the imidazol, the α-amine, and the sum of ɛ-amine, phenolic and sulfhydryl
groups, if the protein is completely denatured, and assumes a randomly coiled conformation. A total of 87.8 ± 2.5 and 20.7
± 0.6 groups per mol were determined in the ovalbumin and lysozyme, respectively. These values are very close to the 88 and
21 groups expected by aminoacid composition of both proteins, indicating that all ionizable groups were exposed to the solvent.
For ovalbumin the distribution of groups was very similar to that expected by the aminoacid composition, but for lysozyme
some anomalies were observed, suggesting the existence of interactions between ionizable groups, altering the dissociation
constants.
Received: 9 December 1996 / Revised: 27 February 1997 / Accepted: 4 March 1997 相似文献
3.
Gianlorenzo Marino 《Journal of heterocyclic chemistry》1972,9(4):817-819
The report that the dipole moment in the five-membered heterocyclic rings, furan, thiophene, and pyrrole has the positive pole on the heteroatom is contradicted with arguments based on reactivity data, theoretical calculations and moment values of substituted derivatives. In actuality, the dipole moment in furan and thiophene is directed from the ring (positive pole) to the heteroatom (negative pole). 相似文献
4.
C. Artini M. M. Carnasciali G. A. Costa R. Masini E. Franceschi F. Locardi 《Journal of Thermal Analysis and Calorimetry》2013,112(1):499-503
Hexagonal as well as tetragonal rare earth oxycarbonates can act as hosts for optically active ions; hence, the knowledge of the structural modifications occurring when foreign hosts are inserted into the parent compound is of fundamental importance for the design of new phosphors. In this article, a phase stability study of the pseudobinary system Gd2O2CO3–Nd2O2CO3 at P = 1 atm. CO2 between 420 and 850 °C is presented, to study the amplitude of the existence fields of the different structures typical of rare earth oxycarbonates. The samples were prepared by thermal decomposition of the corresponding oxalates in CO2 atmosphere. According to composition and temperature, all the three structural forms reported for oxycarbonates (hexagonal, tetragonal, and monoclinic) have been observed. Above a certain temperature, that depends on composition and increases with Nd amount, all the samples decompose into the corresponding Gd–Nd-mixed oxides and crystallize into one of the three possible structural forms typical of rare earth sesquioxides. Structural refinements performed on the hexagonal oxycarbonates demonstrate that the insertion of Nd3+ in Gd2O2CO3 results in a linear increase of the lattice parameters (Vegard’s law) and in a reorganization of the distances between and in the CO 3 2? groups and the (Nd/Gd2O2)2+ layers. 相似文献
5.
Prof. Gianlorenzo Bussetti Claudia Filoni Prof. Andrea Li Bassi Dr. Alberto Bossi Prof. Marcello Campione Prof. Alessio Orbelli Biroli Prof. Chiara Castiglioni Dr. Silvia Trabattoni Dr. Stefania De Rosa Prof. Luca Tortora Prof. Franco Ciccacci Prof. Lamberto Duò 《ChemistryOpen》2021,10(8):748-755
We have recently discussed how organic nanocrystal dissolution appears in different morphologies and the role of the solution pH in the crystal detriment process. We also highlighted the role of the local molecular chemistry in porphyrin nanocrystals having comparable structures: in water-based acid solutions, protonation of free-base porphyrin molecules is the driving force for crystal dissolution, whereas metal (ZnII) porphyrin nanocrystals remain unperturbed. However, all porphyrin types, having an electron rich π-structure, can be electrochemically oxidized. In this scenario, a key question is: does electrochemistry represent a viable strategy to drive the dissolution of both free-base and metal porphyrin nanocrystals? In this work, by exploiting electrochemical atomic force microscopy (EC-AFM), we monitor in situ and in real time the dissolution of both free-base and metal porphyrin nanocrystals, as soon as molecules reach the oxidation potential, showing different regimes according to the applied EC potential. 相似文献
6.
This paper presents a method for the determination of phenylephrine hydrochloride in pharmaceuticals by spectrophotometric flow injection analysis exploiting the reaction with potassium ferricyanide and 4-aminoantipyrine, which leads to the formation of a condensation product with strong absorptivity at 500 nm. The linear dynamic range was between 0.95 and 9 mg/L, with a limit of detection of 0.2 mg/L and a sampling throughput of 120 samples per hour. The method was applied to eyewashes and nasal decongestant liquid medicines. 相似文献
7.
Il Nuovo Cimento D - A new technique, specifically designed for the preparation of preferentially oriented HTSC (YBCO and BSCCO) films on metallic substrates has been developed. The method, named... 相似文献
8.
Knudsen MM Kalashnyk N Masini F Cramer JR Lægsgaard E Besenbacher F Linderoth TR Gothelf KV 《Journal of the American Chemical Society》2011,133(13):4896-4905
Chiral self-assembled structures formed from organic molecules adsorbed on surfaces have been the subject of intense investigation in the recent decade, owing both to relevance in applications such as enantiospecific heterogeneous catalysis or chiral separation as well as to fundamental interest, for example, in relation to the origin of biomolecular homochirality. A central target is rational design of molecular building blocks allowing transfer of chirality from the molecular to the supramolecular level. We previously studied the surface self-assembly of a class of linear compounds based on an oligo(phenylene ethynylene) backbone, which were shown to form a characteristic windmill adsorption pattern on the Au(111) surface. However, since these prochiral compounds were intrinsically achiral, domains with oppositely oriented windmill motifs and related conformational surface enantiomers were always realized in equal proportion. Here we report on the enantioselective, high yield chemical synthesis of a structurally related but intrinsically chiral compound in which two peripheral tert-butyl substituents are replaced by sec-butyl groups, each containing an (S) chiral center. Using scanning tunneling microscopy under ultrahigh vacuum conditions, we characterize the adsorption structures formed from this compound on the Au(111) surface. The perturbation introduced by the modified molecular design is found to be sufficiently small so structures form that are closely analogous to those observed for the original tert-butyl substituted compound. However, as demonstrated from careful statistical analysis of high-resolution STM images, the introduction of the two chiral (S)-sec-butyl substituents leads to a strong preference for windmill motifs with one orientation, demonstrating control of the chiral organization of the molecular backbones through rational molecular design. 相似文献
9.
Masini F Kalashnyk N Knudsen MM Cramer JR Laegsgaard E Besenbacher F Gothelf KV Linderoth TR 《Journal of the American Chemical Society》2011,133(35):13910-13913
It is demonstrated by scanning tunneling microscopy that coadsorption of a molecular chiral switch with a complementary, intrinsically chiral induction seed on the Au(111) surface leads to the formation of globally homochiral molecular assemblies. 相似文献
10.
Mixed LaREO3 (RE ≡ Dy, Ho, Er, Tm, Yb, Lu) and NdGdO3 oxides were prepared by thermal decomposition of the corresponding co-precipitated mixed oxalates. The decomposition of La/RE
and Nd/Gd oxalates was studied by means of differential thermal analysis and thermogravimetric (DTA-TG) measurements; in particular
the last step, consisting of the loss of a CO2 molecule from the corresponding oxycarbonate, has been thoroughly investigated, as it is particularly interesting for the
study of the formation temperature of mixed rare earth oxides. After the release of CO2, the oxides crystallize in a distorted perovskitic cell or one of the structures typical of rare earth sesquioxides, depending
on the cationic size difference and on the average cationic radius. The mixed rare earth oxycarbonate decomposition has been
studied in comparison to the decomposition of single rare earth oxycarbonates. A trend of the mixed oxides formation temperature
as a function both of the average cationic size and of the cationic sizes difference has been observed and compared to the
behaviour of single rare earth oxides. 相似文献