Ternary chalcogenide systems X: The quasiternary system Ag2S-Cu2S-P4S10

The quasiternary system Ag₂S-Cu₂S-P₄S₁₀ was investigated by DTA- and X-ray measurements. No quasiternary compound was found. The phase diagram of the constituent binary Cu₂S-P₄S₁₀ is given for the first time. It contains the compounds Cu₇PS₆, Cu₃PS₄ and (CuPS₃)n. The previously reported Cu₄P₂S₇ was not observed. Thermal and X-ray data of these compounds are given. The compounds Cu₇PS₆ + Ag₇PS₆ and Cu₃PS₄ + Ag₃PS₄ are completely miscible in the solid state.

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Zusammenfassung Mittels DTA und Röntgendiffraktion wurde das quasiternäre System Ag₂S-Cu₂S-P₄O₁₀ untersucht. Es konnte keine quasiternäre Verbindung gefunden werden. Erstmalig wurde das Phasendiagramm für das binäre Teilsystem Cu₂S-P₄O₁₀ gegeben. Es enthält die Verbindungen Cu₇PS₆, Cu₃PS₄ und (CuPS₃)_n. Das unlängst beschriebene Cu₄P₂S₇ wurde nicht beobachtet. Thermoanalytische und röntgenografische Daten dieser Verbindungen werden gegeben. Die Verbindungen Cu₇PS₆ + Ag₇PS₆ und Cu₃PS₄ + Ag₃PS₄ sind im festen Aggregatzustand unbegrenzt mischbar.

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IX: B. Legendre, B. Gather and R. Blachnik, Z. Metallic., 71 (1980) 588.

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Dedicated to Professor Dr. H. J. Seifert on the occasion of his 60^th birthday

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We wish to thank the DFG (SFB 225) and the Fonds der Chemischen Industrie for support.     

K0 production in e+e− annihilations at 30 GeV center of mass energy

Inclusive K⁰-production has been measured in e⁺e^- annihilation at a center of mass energy of about W = 30 GeV. The ratio of K⁰ + K⁰ production to μ⁺μ^- production is R_K0 = 5.6 ± 1.1 (statist. error) ± 0.8 (system.error) This value is about a factor of three higher than R_K0 at W = 7 GeV. The cross sections (s/β) dσ/dx is consistent with a scaling behaviour.     

Λ, Λ production in e+e− annihilation at 33 GeV centre of mass energy

Performing a PWA of the π^?π^?π⁺ system over the ^?tp/p range 0.2 to 0.4 GeV² we find evidence for a J^P = 0^? ,J^G=1^? meson of mass 1342 ± 20 MeV and width 220 ±70 MeV decaying into ?π. This state is produced by natural parity exchange with a slope similar to that of elastic scattering. It can be interpreted as a radial excitation of the π meson (π′).     

A measurement of σtot(e+e− → hadrons) for cm energies between 12.0 and 36.7 GeV

The ration R = σ(e⁺e^? → hadrons)σ_μμ was measured between 12.0 and 36.7 GeV c.m. energy W with a precision of typically ± 5.2%. R is found to be constant with an average R = 4.01 ± 0.03 (stat) ± (syst.) for W ? 14 GeV. Quarks are found to be point-like, the mass parameter describing a possible quark form-factor being larger than 186 GeV. Fits including QCD corrections and a weak neutral-current contribution are presented.     

Cover Picture: Photoprogrammable Organic Light‐Emitting Diodes (Angew. Chem. Int. Ed. 22/2009)

Programmable organic light‐emitting diodes: UV irradiation converts an oxetane‐functionalized dithienylethene derivative from its colorless open form into a dark blue closed form, while visible light reverses the reaction. In the Communication on page 4038 ff., K. Meerholz and co‐workers describe a reversibly switchable organic light‐emitting diode based on this principle.

     

Photoprogrammable Organic Light‐Emitting Diodes

Enlightening the memory : The integration of a crosslinkable photochromic dithienylperfluorocyclopentene (DTE) into organic light‐emitting diodes (OLED) allows for the individualization of the emissive area of the OLED device, for example, for signage applications. The operation principle is based on switching the injection barrier for holes (positive charge carriers). Very large ON/OFF ratios of up to 3000 for current as well as electroluminescence have been achieved.

     

Comparison of e+e− annihilation with QCD and determination of the strong coupling constant

We have analyzed 1113 events of the reaction e⁺e^? → hadrons at CM energies of 12 and 30 GeV in order to make a detailed comparison with QCD. Perturbative effects can be well separated from effects depending on the quark and gluon fragmentation parameters to yield a reliable measurement of the coupling constant α_S. At 30 GeV, the result is α_S = 0.17 ± 0.02 (statistical) ± 0.03 (systematic). QCD model predictions, using the fragmentation parameters determined along with α_S, agree with both gross properties of the final states and with detailed features of the three-jet states.     

Asymptotic expansions for central limit theorems for general linear stochastic processes. I: General theorems on rates of convergence

This paper deals with so-called general linear stochastic processes (GLSP), defined by T. Kawata in 1972 in generalization of work of R. Lugannani and J. B. Thomas of 1967/71. These second order processes (which are not necessarily stationary nor have independent increments) are described by rather weak requirements, so that several processes such as some random noise and pulse train processes are specific models of these GLSP. Part I is concerned with two general theorems giving asymptotic expansions (including those for the density function) in the central limit theorem for such GLSP, together with error rates. The assumptions for the corresponding θ– and o–error estimates seem rather natural: in the former, apart from assumptions on the inherent structure of such GLSP, the existence of certain moments of higher order as well as a Cramer-type condition are assumed, in the latter in addition a Lindeberg-type condition of higher order. Fourier analytic machinery is used for the proofs.     

Lasing from Escherichia coli bacteria genetically programmed to express green fluorescent protein

We report on lasing action from colonies of Escherichia coli bacteria that are genetically programmed to synthesize the green fluorescent protein (GFP). When embedded in a Fabry-Perot type cavity and excited by ns-pulses of blue light (465 nm), the bacteria generate green laser emission (～520 nm). Broad illumination of pump light yields simultaneous lasing over a large area in bacterial colonies.     

Mesogenic Groups Control the Emitter Orientation in Multi-Resonance TADF Emitter Films**

The use of thermally activated delayed fluorescence (TADF) emitters and emitters that show preferential horizontal orientation of their transition dipole moment (TDM) are two emerging strategies to enhance the efficiency of OLEDs. We present the first example of a liquid crystalline multi-resonance TADF (MR-TADF) emitter, DiKTa-LC . The compound possesses a nematic liquid crystalline phase between 80 °C and 110 °C. Importantly, the TDM of the spin-coated film shows preferential horizontal orientation, with an anisotropy factor, a, of 0.28, which is preserved in doped poly(vinylcarbazole) films. Green-emitting (λ_EL=492 nm) solution-processed OLEDs based on DiKTa-LC showed an EQE_max of 13.6 %. We thus demonstrate for the first time how self-assembly of a liquid crystalline TADF emitter can lead to the so-far elusive control of the orientation of the transition dipole in solution-processed films, which will be of relevance for high-performance solution-processed OLEDs.