Pd (II)‐catalyzed vinyl addition polymerization of novel functionalized norbornene bearing dimethyl carboxylate groups

Three novel functionalized polynorbornenes (PNB) with pendant dimethyl carboxylate group (carboxylates—acetate, propionate, and butyrate) are synthesized as a vinyl‐type with a palladium (II) catalyst in high yield. The effects of size of substitutents, molar ratio of monomer to catalyst, solvent polarity, reaction time, and temperature on the polymerization of exo‐norbornene dimethyl propionate were systematically investigated. The low molar ratio and temperature, as well as high polarity of solvent, and long reaction time, are favorable for the enhancement of the monomer conversion, especially, the solvent have an obvious effect on the catalyst activity. The resulting poly(cis‐norbornene‐exo‐2,3‐dimethyl carboxylates) (PNB‐dimethyl carboxylates) show good solubility in common organic solvent and high thermal stability up to 360 °C. The glass transition temperature was detected by DMA at 331, 324, and 318 °C for acetate, propionate, and butyrate, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3391–3399, 2007     

MODELING HARVEST SCHEDULING IN MULTIFUNCTIONAL PLANNING OF FORESTS FOR LONGTERM WATER YIELD OPTIMIZATION

In this study, wood production and hydrologic functions of forests were accommodated within a planning procedure for separate working circles (areas dedicated to certain forest functions) that were delineated according to an Ecosystem‐Based Functional Planning approach. Mixed integer goal programming was used as the optimization technique. The timing and scheduling of a maintenance cutting (partial harvest) was the decision variable in the modeling effort, and an original formulation was developed as a multiobjective planning procedure. Four sample planning strategies were developed and model outputs were evaluated according to these strategies. Spatial characteristics of stands were considered, and used to prohibit the regeneration of adjacent stands during the same time period. Because of the positive relationship between qualified water production and standing timber volume in the forest, the model attempts to maximize qualified water production levels by increasing standing volume stocks in the forest through the delay of regeneration activities.     

Effect of chemical modification on oligomerization capacity of alumina support for Pd-Al<Subscript>2</Subscript>O<Subscript>3</Subscript> catalyst

Effect of modification with an alkali metal on the acid properties of alumina supports and on the oligomerization capacity and working stability of Pd-Al₂O₃ catalysts was studied.     

Demonstration of all-optical beam steering in modulated photonic lattices

We demonstrate experimentally all-optical beam steering in modulated photonic lattices induced optically by three-beam interference in a biased photorefractive crystal. We identify and characterize the key physical parameters governing the beam steering and show that the spatial resolution can be enhanced by the additional effect of nonlinear beam self-localization.     

Synthesis and cytotoxicity of 28-carboxymethoxy lupane triterpenoids.Preference of 28-O-acylation over 28-O-alkylation of betulm by ethyl bromoacetate

28-Carboxymethoxy lupane tritepenoids 3 and 4 were synthesized by alkylation of betulin with the THP protected 2- hydroxyethyl iodide followed by oxidation and reduction.Direct reaction of betulin(5) or betulone(10) with ethyl bromoacetate led to 28-O-acylation,instead of 28-O-alkylation.The targeted compounds 3 and 4 were not cytotoxic at the highest concentration tested(75μmol/L),suggesting that elongation of the chain length at the 28-position in both betulinic acid(1) and betulonic acid(2) was detrim...     

Theoretical study on the electronic,structural, properties and reactivity of a series of mono-, di-, tri- and tetrachlorothiophenes as well as corresponding radical cation forms as monomers for conducting polymers

In this paper, electrical and structural properties of mono-, di-, tri- and tetrachlorothiophenes and their radical cations have been studied using the density functional theory and B3LYP method with 6-311++G** basis set. The effects of the number and position of the substituent of chlorine atoms on the properties of the thiophene ring for all chlorothiophenes and their radical cations have been studied. Vibrational frequencies, nuclear chemical shielding constants, spin-density distribution, size and direction of dipole moment vector, ionization potential, electric polarizabilities and NICS values of these compounds have been calculated as well. The analysis of these data showed that double bonds in 3-chlorothiophene are more delocalized and it is the best possible candidate monomer among all chlorothiophenes for the synthesis of corresponding conducting polymers with modified characteristics.     

Nonlinear surface waves in arrays of curved waveguides

We study both theoretically and experimentally the nonlinear surface waves at the edge of curved waveguide arrays with a surface defect. We show that the nonlinear coupling between different linear modes supported by the array can lead to beam switching to different output waveguides with increasing of the nonlinearity strength. Our experimental observations are in good agreement with the numerical modelling.     

Defect-free surface states in modulated photonic lattices

We predict that interfaces of periodically curved waveguide arrays can support a novel type of surface states which exist in a certain region of modulation parameters associated with the band flattening. Such linear surface states appear in truncated but otherwise perfect (defect-free) lattices as a direct consequence of the periodic modulation of the lattice potential. We show that the existence of these modes in different band gaps can be flexibly controlled by selecting the modulation profile, with no restrictions on Bloch-wave symmetries characteristic of Shockley states.     

Shaping and switching of polychromatic light in arrays of periodically curved nonlinear waveguides

We overview our recent theoretical results on spatio-spectral control, diffraction management, and broadband all-optical switching of polychromatic light in periodically curved one and two dimensional arrays of coupled optical waveguides. In particular, we show that polychromatic light beams and patterns produced by white-light and supercontinuum sources can experience wavelength-independent normal, anomalous, or zero diffraction in specially designed structures. We also demonstrate that in the nonlinear regime, it is possible to achieve broadband all-optical switching of polychromatic light in a directional waveguide coupler with special bending of the waveguide axes. Our results suggest novel opportunities for creation of all-optical logical gates and switches which can operate in a very broad frequency region, e.g., covering the entire visible spectrum. Presented at 9-th International Workshop on Nonlinear Optics Applications, NOA 2007, May 17–20, 2007, Świnoujście, Poland     

Design and study of a high-current 5-cell superconducting rf cavity

The Advanced Photon Source （APS） at Argonne National Laboratory is considering the development of a superconducting linac-based fourth-generation hard X-ray source to meet future scientific needs of the hard X-ray user community. This work specifically focuses on the design of an optimized 5-cell superconducting radio-frequency structure well suited for a high-energy, high-beam-current energy recovery linac. The cavity design parameters are based on the APS storage ring nominal 7 GeV and 100 mA beam operation. A high-current 5-cell cw superconducting cavity operating at 1.4 GHz has been designed. In order to achieve a high current, the accelerating cavity shape has been optimized and large end-cell beam pipes have been adopted. The beam break-up threshold of the cavity has been estimated using the code TDBBU, which predicts a high threshold beam current for a 7 GeV energy recovery linac model. A copper prototype cavity has been fabricated that uses half-cell modules, initially assembled by clamping the cells together.