High-resolution FTIR spectra of CH2 = CClF in the 930-1050 cm−1 region

The gas-phase infrared spectra of natural CH₂ = CClF have been measured in the v ₆ and 2v ₁₂ band regions (930–1050 cm^?1) by high-resolution Fourier transform spectroscopy at room temperature. 1-Chloro-1-fluoroethylene is a planar asymmetric rotor (κ = ?0.54) belonging to the symmetry point group C_s and the vibrations investigated of symmetry species A′ give rise to a/b-hybrid bands with contributions of comparable intensity from both the components.

The rovibrational analysis of the fine structure led to the identification of 1894 (J ? 73, K_a ? 20) and 718 (J ? 53, K_a ? 8) transitions for the v ₆ and 2v ₁₂ bands of the ³⁵Cl isotopic species, respectively. Using the Watson's A-reduction Hamiltonian in the I^r representation a set of accurate spectroscopic parameters for both the excited states u ₆ = 1 and u12 = 2 of ³⁵Cl has been obtained for the first time. Transitions of ³⁷Cl isotopomer could also be assigned in the Q branch region of the 2v ₁₂ overtone; the determined band origin shift of 0.782 cm^?1 towards the lower wavenumbers led to describing the v ₁₂ fundamental as a vibration mainly involving the CFCl bending motion.     

Pathologies in the sticky limit of hard sphere Yukawa models for colloidal fluids: a possible correction

A known ‘sticky hard sphere’ model, starting from a hard sphere Yukawa potential and taking the limit of infinite amplitude and vanishing range with their product remaining constant, is shown to be ill-defined. This is because its Hamiltonian (which we call SHS2) leads to an exact second virial coefficient which diverges, unlike that of Baxter's original model (SHS1). This deficiency has never been observed so far, since the linearization implicit in the ‘mean spherical approximation’ (MSA), within which the model is analytically solvable, partly masks such a pathology. To overcome this drawback and retain some useful features of SHS2, we propose both a new model (SHS3) and a new closure (‘modified MSA’), whose combination yields an analytical solution formally identical with the SHS2-MSA solution. This mapping allows the recovery of many results derived from SHS2, after a re-interpretation within a correct framework. Possible developments are indicated.     

FTIR spectroscopy of the 2v3 overtone band for different BrCN isotopomers: an improved evaluation of the anharmonic force field of cyanogen bromide

The 2v₃ overtone band of six different isotopomers of cyanogen bromide has been recorded in the range from 4200 to 4400 cm^?1 with a resolution of 0.02 cm^?1 using a Fourier transform infrared (FTIR) spectrometer. This allowed us to achieve complete knowledge of the energies for all levels corresponding to double vibrational excitation. An improved evaluation of the quartic force field of cyanogen bromide has been performed using the new data obtained together with those already known from previous works. Theoretical values derived from a recent ab initio calculation have been used to constrain the potential terms which cannot be determined with sufficient precision by the least-squares analysis of the available experimental data.     

MULTISPECIES EXPLOITATION WITH EVOLUTIONARY SWITCHING OF HARVESTING STRATEGIES

In this paper, we propose a bioeconomic model which describes a fishery in which each of two noninteracting species is harvested by a given group of fishers during a defined time period. Then the Fishing Regulatory Authority allows each fisher to reconsider the harvesting decision at fixed (discrete) periods of time. The model derives from an Italian fisheries management experience in the Northern Adriatic Sea, where this kind of “self‐adjusting” fishing policy has been proposed to regulate harvesting of two shellfish species. The proposed dynamic model assumes the form of a hybrid system, as the natural growth functions of the two species (in continuous time) are coupled with a discrete time adaptive system that regulates how agents switch from one harvesting strategy to the other period by period according to an evolutionary mechanism based on profit comparison. In order to obtain some insights into the basic mechanisms of the system, some relevant benchmark cases are analyzed before tackling (mainly numerically) the complete hybrid model. Our results suggest that, for proper sets of parameters, this kind of myopic and adaptive self‐regulation may ensure a virtuous trade‐off between profit maximization and resource conservation, driven by cost externalities and market pressure.     

Density dependence of the electric-field-gradient induced birefringence of the helium,neon and argon gases

An ab initio investigation of the density dependence of the electric-field-gradient induced birefringence (EFGB) for the noble gases helium, neon and argon is presented. To determine the second coefficient in the virial expansion of the molecular EFGB constant _mQ, the effect of two-body interactions has been studied by computing the internuclear dependence of the molecular quadrupole moment and of the dipole-dipole-quadrupole and dipole-magnetic dipole-dipole hyperpolarizabilities of the van der Waals dimers. A full-configuration-interaction approach as well as the coupled cluster singles and doubles and the coupled cluster singles and doubles plus perturbative triples approximations have been adopted, and extended basis sets including midbond functions have been employed. A semi-classical integration yields the virial coefficients. The effect of density for standard experimental conditions is found to be of the order of a few tens of parts per million for helium and neon, and of the order of a few parts per thousands for argon at low temperatures, and thus not detectable with present apparatus.     

On the compressibility equation of state for multi-component adhesive hard sphere fluids

The compressibility equation of state (EOS) for a multi-component sticky hard sphere model alternative to Baxter's one is investigated within the mean spherical approximation (MSA). For this model and this closure, as well as for a more general class of models and closures leading to Baxter functions q_ij(r) with density-independent stickiness coefficients, no compressibility EOS can exist for mixtures, unlike the one-component case (in view of this, an EOS recently reported in the literature turns out to be incorrect). The reason is the failure of the Euler reciprocity relation for the mixed second-order partial derivatives of the pressure with respect to the partial densities. This is in turn related to the inadequacy of the approximate closure (in particular, the MSA). A way out to overcome this drawback is presented in a particular example, leading to a consistent compressibility pressure, and a possible generalization of this result is discussed.     

High resolution FTIR spectroscopy of CH2DF: analysis of the v 3 and v 4 interacting bands

The high resolution (0.004cm^?1) Fourier transform infrared spectrum of the monodeuterated form of methyl fluoride, CH₂DF, has been recorded and analysed in the v ₃ and v ₄ band region around 1420cm^?1. Both bands, coming from A′ symmetry vibrations, have a/b hybrid character, although in v ₃ the b-type component prevails over the a-type. The rotational structure has been analysed using a dyad model including c-type Coriolis coupling and high order vibrational resonance between these states. Accurate upper state molecular parameters and interaction terms have been obtained by fitting about 3270 assigned transitions to Watson's A-reduced Hamiltonian in the I^r representation. In addition, from a simultaneous fit of ground state combination differences coming from this analysis and 42 literature microwave transitions, an improved and more complete set of ground state constants, including three new sextic centrifugal distortion terms (Φ_JK, Φ_KJ and Φ_K), has been derived.     

用触针下分布电阻的光电导相位法测量半导体中非平衡载流子寿命

本文提出一种测量半导体中非平衡载流子寿命的新方法。这方法是测量触针下分布电阻的光电导相位移,在不同的表面情况和不同的激发光光谱成分下,导得各种结果表达式,文中对通常所使用的测量条件即粗磨表面和长波激发条件给出数值计算的结果。同时,对这些结果进行较为详细的分析和讨论,这个方法具有一系列的优点。例如:1)可以在锭状晶体上测量;2)表面处理十分简单;3)在样品上不需制作固定电极;4)测量仪器简单,操作方便;5)有一定准确度。这个方法可以检验不均匀材料,可供科研机关作研究用,更适合于工厂检验单晶材料用。用这方法在锗和硅样品上进行测量,测得寿命值基本上与其它方法的结果一致。     

Evolutionary Selection of Socially Sensitive Preferences in Random Matching Environments

In this paper we study the evolutionary selection of socially sensitive preferences in the context of reference interaction settings such as coordination failure and cooperation. We refer to a specific class of socially sensitive preferences in which players weigh additively their own material payoff against the opponent with either a positive or negative coefficient (λ-players). Preference evolution is guided by replicator dynamics in a context of perfect observability of preferences types and stochastic pairwise matching. We take an indirect evolutionary approach, that is, the selection mechanism operates on the actual material payoffs earned by players, so that any instance of socially sensitive preference can be thought of as instrumentally maintained. We find that the evolutionary viability of socially sensitive preferences basically depends on whether or not they cause a substantial improvement in the achievement of socially efficient outcomes with respect to the case where only self-serving or unconditionally focused preference orientations are observed. Our results suggest that moderate pro-social preference orientations are likely to emerge from social selection even in the absence of an intrinsic motivational drive, whereas extremely pro-social orientations as well as competitive and anti-social ones may need a stronger motivational base.