排序方式: 共有16条查询结果,搜索用时 15 毫秒
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Albrecht H Binder U Harder G Lembke-Koppitz I Philipp A Schmidt-Parzefall W Schröder H Schulz HD Wurth R Donker JP Drescher A Matthiesen U Scheck H Spaan B Spengler J Wegener aD Gabriel JC Schubert KR Stiewe J Waldi R Weseler S Brown NN Edwards KW Frisken WR Fukunaga C Gilkinson DJ Gingrich DM Goddard M Kapitza H Kim PC Kutschke R MacFarlane DB McKenna JA McLean KW Nilsson AW Orr RS Padley P Patel PM Prentice JD Seywerd HC Stacey BJ Yoon T Yun JC Ammar R Coppage D Davis R Kanekal S Kwak N 《Physical review letters》1986,56(6):549-552
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The elastic theory of nemtatic liquid crystals is used to determine whether it gives support for recent experimental observations of a novel periodic phase occurring in homeotropically aligned films when an electric field is applied in the plane of the film. The director remains in the plane defined by the film normal and the field, and the wavevector of the periodicity is parallel to the field. It is found that the theory is consistent with experiment. 相似文献
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Iodomethyl-, chloromethyl-, and fluoromethyldimethylsulfonium salts, 4b-d, have been synthesized and are observed to be highly reactive molecules that exhibit extraordinary diversity with respect to the nature of their reactivity, undergoing facile direct substitution (S(N)2) reactions, but also being highly susceptible to electron-transfer reactions. Cyclic voltametry experiments indicated that the iodomethyldimethylsulfonium compound, 4b, is a potent electron acceptor, even surpassing the reactivity of perfluoro-n-alkyl iodides in that capacity. The iodo- and chloromethyldimethylsulfonium salts, 4b,c, as well as the analogous iodomethyltrimethylammonium salt, 3a, are shown to be reactive SET acceptors. 相似文献
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Rheological measurements were performed on aqueous dispersions of two commercial crosslinked polymer microgels, Carbopol Ultrez
10 and Carbopol ETD 2050, prepared over a wide range of concentration and pH. For all concentrations studied, both the yield
stress and the elastic modulus initially increased dramatically with pH and displayed broad peaks at intermediate pH. This
is consistent with the onset of jamming of the Carbopol particles due to a rapid increase in particle size caused by osmotic
swelling in the presence of NaOH. Scaling of both yield stress and elasticity with concentration was observed only at higher
concentrations, which we believe indicates a change from a percolated structure at low volume fractions to a space filling
network of compressed particles at high volume fractions. This model is supported by confocal microscopy of fluorescently
dyed Carbopol dispersions. 相似文献
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