全文获取类型
收费全文 | 435篇 |
免费 | 5篇 |
国内免费 | 3篇 |
专业分类
化学 | 259篇 |
晶体学 | 2篇 |
力学 | 11篇 |
数学 | 56篇 |
物理学 | 115篇 |
出版年
2019年 | 5篇 |
2017年 | 2篇 |
2016年 | 8篇 |
2014年 | 8篇 |
2013年 | 17篇 |
2012年 | 21篇 |
2011年 | 22篇 |
2010年 | 10篇 |
2009年 | 17篇 |
2008年 | 22篇 |
2007年 | 22篇 |
2006年 | 15篇 |
2005年 | 11篇 |
2004年 | 12篇 |
2003年 | 15篇 |
2002年 | 14篇 |
2001年 | 16篇 |
2000年 | 11篇 |
1999年 | 6篇 |
1998年 | 3篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1994年 | 4篇 |
1993年 | 9篇 |
1992年 | 12篇 |
1991年 | 9篇 |
1990年 | 11篇 |
1989年 | 5篇 |
1988年 | 4篇 |
1987年 | 7篇 |
1986年 | 9篇 |
1985年 | 14篇 |
1984年 | 10篇 |
1983年 | 6篇 |
1982年 | 3篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1976年 | 3篇 |
1975年 | 7篇 |
1974年 | 2篇 |
1973年 | 6篇 |
1972年 | 5篇 |
1971年 | 4篇 |
1970年 | 3篇 |
1937年 | 2篇 |
1934年 | 2篇 |
1890年 | 2篇 |
排序方式: 共有443条查询结果,搜索用时 15 毫秒
1.
It is thought that the extensive industrial use of arsenic, gallium and indium, which have applications as the materials for III–V semiconductors, will increase human exposure to these compounds in the near future. We have undertaken the development of new biological indicators for assessing exposure to these elements. Element-specific alterations in protein synthesis patterns were expected to occur following exposure to arsenic compounds. We examined alterations in protein synthesis in primary cultures of rat kidney proximal tubule epithelial cells by sodium arsenite, gallium chloride and indium chloride, utilizing two-dimensional gel electrophoresis. After incubation with the chemicals for 20 h, newly synthesized proteins were labeled with [35S]methionine. A protein with a molecular weight (Mr) of 30 000 was markedly induced on exposure to 10 μM arsenite or 300 μM gallium chloride, and synthesis of proteins with Mr values of 85 000, 71 000, 65 000, 51 000, 38 000 and 28 000 were also increased by exposure to arsenite and gallium chloride. No significant changes were observed upon exposure to indium. Some of these increased proteins could be heat-shock proteins. 相似文献
2.
Christabel E. Fowler Catherine Buchber Joël Patarin Alain Walcarius 《Applied Surface Science》2007,253(12):5485-5493
Diatomaceous earth was functionalized by grafting organotrialkoxysilane precursors onto the surface of the porous silica cell walls of this biomineral. Vinyl- and mercapto-containing structures were prepared in aqueous media without disruption of the diatomic architecture. Successful grafting of the organic moieties was confirmed using solid state 29Si MAS NMR spectroscopy, and the presence of the intact diatom framework by scanning electron microscopy. The sorption properties of mercaptopropyl-functionalized diatoms towards heavy metals was studied by measuring the accessibility and diffusion rates of mercury(II) species to the binding sites (-SH) by the means of electrochemical methods. 相似文献
3.
4.
MM. J. Duflos D. Letouz G. Queguiner P. Pastour 《Journal of heterocyclic chemistry》1973,10(6):1083-1084
This communication describes the synthesis of l-methyl-2,3-diformylpyrrole. This new compound is used to prepare a new heterocycle, l-methylcyclohepta[b]pyrrol-6-one and thus allows a new synthesis of l-methylpyrrolo[2,3-d]pyridazine. 相似文献
5.
6.
7.
Armbruster P Agarwal YK Brüchle W Brügger M Dufour JP Gaggeler H Hessberger FP Hofmann S Lemmertz P Münzenberg G Poppensieker K Reisdorf W Schadel M Schmidt K Schneider JH Schneider WF Sümmerer K Vermeulen D Wirth aG Ghiorso A Gregorich KE Lee D Leino M Moody KJ Seaborg GT Welch RB Wilmarth P Yashita S Frink C Greulich N Herrmann G Hickmann U Hildebrand N Kratz JV Trautman N Fowler MM Hoffman DC Daniels WR von Gunten HR Dornhöfer H 《Physical review letters》1985,54(5):406-409
8.
9.
10.
In the simulation of a liquid drop it is expensive to calculate the excess pressure and obtain the surface tension by the Laplace formula. We use the Kelvin formula which only requires the vapour density, or at most the virial pressure. Some results are given for a Lennard-Jones 12-6 fluid. 相似文献