全文获取类型
收费全文 | 262篇 |
免费 | 10篇 |
专业分类
化学 | 184篇 |
晶体学 | 6篇 |
力学 | 6篇 |
数学 | 41篇 |
物理学 | 35篇 |
出版年
2023年 | 3篇 |
2022年 | 12篇 |
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 14篇 |
2018年 | 10篇 |
2017年 | 2篇 |
2016年 | 10篇 |
2015年 | 7篇 |
2014年 | 12篇 |
2013年 | 20篇 |
2012年 | 15篇 |
2011年 | 17篇 |
2010年 | 13篇 |
2009年 | 6篇 |
2008年 | 17篇 |
2007年 | 15篇 |
2006年 | 9篇 |
2005年 | 12篇 |
2004年 | 11篇 |
2003年 | 3篇 |
2002年 | 12篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 4篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1985年 | 3篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1966年 | 1篇 |
1957年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有272条查询结果,搜索用时 15 毫秒
1.
Bending of optical fiber leads to an induced-anisotropy in the index profile that influences many important guiding fiber parameters. An analytical method is described for the measurement of refractive-index-wavelength dispersion in bent optical fibers. Multiple-beam Fizeau fringes technique at transmission is used to analyze the opto-mechanical properties and induced-index anisotropy in a standard single-mode fiber undergoes pure mechanical macrobending. The shift in Fizeau fringes is employed to evaluate the dispersion of the cladding material of the bent fiber. The radial variations in Cauchy’s coefficients and the associated variations of some fiber parameters due to macrobending are carried out. The radial profiles of some material parameters such as oscillation energy, dispersion energy, lattice energy and material dispersion are measured as well. The presented method is capable to achieve quantitative and qualitative measurements, which is not available with other methods. The method has a good index resolution in the order of 10−4 and spatial resolution of 1.3 μm. 相似文献
2.
A review of the optimal stopping problem with more than a single decision maker (DM) is presented in this paper. We classify
the existing literature according to the arrival of the offers, the utility of the DMs, the length of the sequence of offers,
the nature of the game and the number of offers to be selected. We enumerate various definitions for this problem and describe
some dynamic approaches.
Fouad Ben Abdelaziz is on leave from the Institut Superieur de Gestion, University of Tunis, Tunisia e-mail: foued.benabdelaz@isg.run.tn. 相似文献
3.
Abdelhak Moumen Youghourta Belhocine Najoua Sbei Seyfeddine Rahali Fatima Adam Mohamed Ali Fedia Mechati Fouad Hamdaoui Mahamadou Seydou 《Molecules (Basel, Switzerland)》2022,27(21)
In this study, natural Algerian kaolin was used as a support and impregnated with nickel at different loading amounts (2 wt.%, 5 wt.%, and 7 wt.%) in order to prepare a supported catalyst. The wet impregnation technique was used in this preparation; nickel oxide (NiO) was the active phase precursor of the catalyst, and the catalysts were designated as follows: 2%, 5%, and 7% Ni/kaolin. These catalysts were put to the test in catalytic wet peroxide oxidation (CWPO) for degrading the organic contaminant malachite green dye (MG). Analytical techniques such as FTIR spectroscopy, X-ray diffraction, BET, and X-fluorescence were used to examine the structure, morphology, and chemical composition of the support and the produced catalysts. Several parameters, including temperature, catalytic dose, metal loading, hydrogen peroxide volume, and kinetic model were systematically investigated. The combination of improved parameters resulted in a significant increase in the catalytic activity, achieving a high removal rate of MG dye of 98.87%. 相似文献
4.
Santosh Kumari Suvarcha Chauhan Kuldeep Singh Ahmad Umar Hassan Fouad Mohammad Shaheer Akhtar 《Molecules (Basel, Switzerland)》2022,27(24)
This study aims to understand how glycyl dipeptide affected the compressibility, volumetric behavior and viscometric behavior of the cationic surfactants CTAB (Cetyltrimethylammonium bromide) and DTAB (dodecyltrimethylammonium bromide). Information on solute–solute, solute–solvent, and solvent–solvent interactions has been inferred using the quantification of density (ρ), speed of sound (u) and viscosity in aqueous media containing glycyl dipeptide in the temperature range 293.15–313.15 K at an interval of 5 K. The data from the aforementioned research have been used to enumerate numerous volumetric and compressibility metrics that aid in the collection of information about the interactional behavior of the system under consideration. The study suggests that CTAB interacts strongly compared to DTAB with dipeptide, and it also significantly dehydrates glycyl dipeptide. The difference in water–water interactions caused by the loss of hydrophobic hydration of the surfactant molecules upon the addition of cationic surfactants may be the cause of the variation in determined parameters with surfactant concentration. Consideration of the structural rearrangement of molecules that may occur in the system has been used to explain the results of viscosity and computed factors related to viscosity. The patterns of competitive intermolecular interactions in the ternary (dipeptide + water + surfactant) system have been used to analyze the trends of all the parameters. The study may be helpful to understand the stability and structural changes in protein–surfactant systems mediated through various interactions that may be present in the system. 相似文献
5.
Fouad FS Wright JM Plourde G Purohit AD Wyatt JK El-Shafey A Hynd G Crasto CF Lin Y Jones GB 《The Journal of organic chemistry》2005,70(24):9789-9797
[structure: see text] The viability of proteins as targets of thermally and photoactivated enediynes has been confirmed at the molecular level. Model studies using a labeled substrate confirmed the efficacy of atom transfer from diyl radicals produced from enediynes to form captodatively stabilized carbon centered aminoacyl radicals, which then undergo either fragmentation or dimerization. To exploit this finding, a family of enediynes was developed using an intramolecular coupling strategy. Derivatives were prepared and used to target specific proteins, showing good correlation between affinity and photoinduced protein degrading activity. The findings have potential applications in the design of artificial chemical proteases and add to our understanding of the mechanism of action of the clinically important enediyne antitumor antibiotics. 相似文献
6.
Ayman M. Atta Ahmed A. Fadda Adel A.-H. Abdel-Rahman Husein S. Ismail Rasha R. Fouad 《Journal of Dispersion Science and Technology》2013,34(6):775-785
Water soluble nonionic amphiphilic block copolymers based on hydrophilic poly(ethylene glycol) (PEG) and hydrophobic poly(propylene glycol) (PPG) were prepared. Poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) copolymers, PEG-PPG-PEG, were prepared in the normal condition. The chemical composition and molecular weights of the prepared copolymers were determined from 1H NMR and GPC techniques. The surface properties of the prepared surfactants were determined by measuring the surface tension at different temperatures. The prepared nonionic surfactants were evaluated as demulsifiers for water in crude-oil emulsions that were pronounced at different ratios of crude oil: water at 318 K and 333 K. The experimental results showed that the dehydration rate of the prepared demulsifiers reached 100% based on demulsifier chemical compositions and concentrations. 相似文献
7.
Bruno Ameduri Bernard Boutevin Fouad Malek 《Journal of polymer science. Part A, Polymer chemistry》1994,32(16):3161-3169
The synthesis of maleimides that have pyrazolic or bipyrazolic pendant groups is described. Their homopolymerization and their copolymerization with 2-chloroethyl vinyl ether (CEVE) is reported. The homopolymerizations of such maleimides were performed under various conditions and led to low molecular-weight polymers. However, alternating copolymers were obtained from CEVE as comonomers whatever the monomers feed compositions. A similar behavior was also observed for maleimides that do not exhibit any spacer, whereas for bulky vinyl ethers, random copolymers were produced. A comparison of the thermal behavior between these copolymers (glass transition temperatures, Tg, and decomposition temperatures) and other copolymers having different spacers between the nitrogenated cycles and the chain are related. Thus, an important decrease of Tg, was observed when C3H6CO2CH2 groups were used as the spacer instead of methylene groups. Moreover, the thermal weakness of these copolymers may come from the substituents of the vinyl ether and is discussed. © 1994 John Wiley & Sons, Inc. 相似文献
8.
Macrocyclic chemistry has been extensively developed over the past several decades. In fact, the architecture of new macrocyclic models has undergone exponential growth to offer molecules with specific properties. In this context, an attempt is made in this study to provide an overview of some synthetic methods allowing the elaboration of N-heterocycles containing macrocycles (imidazole, triazole, tetrazole, and pyrazole), as well as their applications in the complexation of metal cations or as pharmacological agents. 相似文献
9.
10.
N. E. Fouad 《Journal of Thermal Analysis and Calorimetry》2000,60(2):541-547
The thermal behaviour of CrO3 on heating up to 600°C in dynamic atmospheres of air, N2 and H2 was examined by thermogravimetry (TG), differential thermal analysis (DTA), IR spectroscopy and diffuse reflectance spectroscopy
(DRS). The results revealed three major thermal events, depending to different extents on the surrounding atmosphere: (i)
melting of CrO3 near 215°C (independent of the atmosphere), (ii) decomposition into Cr2(CrO4)3 at 340–360°C (insignificantly dependent), and (iii) decomposition of the chromate into Cr2O3 at 415–490°C (significantly dependent). The decomposition CrO3 → Cr2(CrO4)3 is largely thermal and involves exothermic deoxygenation and polymerization reactions, whereas the decomposition Cr2(CrO4)3 → Cr2O3 involves endothermic reductive deoxygenation reactions in air (or N2) which are greatly accelerated and rendered exothermic in the presence of H2. TG measurements as a function of heating rate (2–50°C min−1) demonstrated the acceleratory role of H2, which extended to the formation of Cr(II) species. This could sustain a mechanism whereby H2 molecules are considered to chemisorb dissociatively, and then spillover to induce the reduction. DTA measurements as a function
of the heating rate (2–50°C min−1) helped in the derivation of non-isothermal kinetic parameters strongly supportive of the mechanism envisaged.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献