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Using a direct position-space renormalization-group approach we study percolation clusters in the limits , wheres is the number of occupied elements in a cluster. We do this by assigning a fugacityK per cluster element; asK approaches a critical valueK
c
, the conjugate variables . All exponents along the path (K–K
c
) 0 are then related to a corresponding exponent along the paths . We calculate the exponent , which describes how the radius of ans-site cluster grows withs at the percolation threshold, in dimensionsd=2, 3. Ind=2 our numerical estimate of =0.52±0.02, obtained from extrapolation and from cell-to-cell transformation procedures, is in agreement with the best known estimates. We combine this result with previous PSRG calculations for the connectedness-length exponent , to make an indirect test of cluster-radius scaling by calculating the scaling function exponent using the relation =/. Our result for is in agreement with direct Monte-Carlo calculations of , and thus supports the cluster-radius scaling assumption. We also calculate ind=3 for both site and bond percolation, using a cell of linear sizeb=2 on the simple-cubic lattice. Although the result of such small-cell calculations are at best only approximate, they nevertheless are consistent with the most recent numerical estimates.Supported in part by grants from ARO and ONR 相似文献
5.
Fereydoon Gobal Masoud Faraji 《Applied Physics A: Materials Science & Processing》2014,117(4):2087-2094
Nanoporous/cracked structures of cobalt oxide (Co3O4) electrodes were successfully fabricated by electroplating of zinc–cobalt onto previously formed TiO2 nanotubes by anodizing of titanium, leaching of zinc in a concentrated alkaline solution and followed by drying and annealing at 400 °C. The structure and morphology of the obtained Co3O4 electrodes were characterized by X-ray diffraction, EDX analysis and scanning electron microscopy. The results showed that the obtained Co3O4 electrodes were composed of the nanoporous/cracked structures with an average pore size of about 100 nm. The electrochemical capacitive behaviors of the nanoporous Co3O4 electrodes were investigated by cyclic voltammetry, galvanostatic charge–discharge studies and electrochemical impedance spectroscopy in 1 M NaOH solution. The electrochemical data demonstrated that the electrodes display good capacitive behavior with a specific capacitance of 430 F g?1 at a current density of 1.0 A g?1 and specific capacitance retention of ca. 80 % after 10 days of being used in electrochemical experiments, indicating to be promising electroactive materials for supercapacitors. Furthermore, in comparison with electrodes prepared by simple cathodic deposition of cobalt onto TiO2 nanotubes(without dealloying procedure), the impedance studies showed improved performances likely due to nanoporous/cracked structures of electrodes fabricated by dealloying of zinc, which provide fast ion and electron transfer routes and large reaction surface area with the ensued fast reaction kinetics. 相似文献
6.
The factors influencing the electrochemical behaviour of a supercapacitor have been partly examined in this work. The effects
of so-called intrinsic parameters, i.e. exchange current density, unit cell length and double layer (DL) capacitance; as well
as the so-called application parameters, i.e. cell current, on the cell potential discharge time have been considered. The
contributions of each type of capacitors, DL capacitor and faradaic supercapacitor under various states of operation and material
have been analyzed, and the competing (compensating) effects of the two types of capacitors as regards to the discharge and
power characteristics manifested by current–potential and energy–power (Ragone plots) are elucidated. 相似文献
7.
Majid JAFARIAN Mehdi RASHVAND AVEI Iman DANAEE Fereydoon GOBAL Mohammad G.MAHJANI 《催化学报》2010,31(11):1351-1357
A stable copper (hydr)oxide-modified electrode was prepared in 0.5 mol/L NaOH solution by cyclic voltammetry in the range of -250 to 1 000 mV. It can be used for electrochemical studies in the range of -250 to 1 000 mV without interfering peaks because there is no oxidation of copper. During an anodic potential sweep, the electro-oxidation of saccharose on Cu occurred by the formation of CuIII and this reaction also occurred in the early stages of the reversed cycle until it is stopped by the negative potentials. A mechanism based on the electro-chemical generation of CuIII active sites and their subsequent consumption by saccharose was proposed, and the rate law and kinetic parameters were obtained. The charge transfer resistance from theoretical and impedance studies was used to verify the mechanism. Under chronoamperometry regimes, the reaction followed Cottrellian behavior. The transfer of up to 21 electrons was observed in further investigations of the electro-oxidation of saccharose on a (hydr)oxide Cu rotating disk electrode. 相似文献
8.
In this paper a genetic algorithm for solving a class of project scheduling problems, called Resource Investment Problem, is presented. Tardiness of project is permitted with defined penalty. Elements of algorithm such as chromosome structure, unfitness function, crossover, mutation, immigration and local search operations are explained. 相似文献
9.
A hybrid scatter search for the discrete time/resource trade-off problem in project scheduling 总被引:1,自引:0,他引:1
We develop a heuristic procedure for solving the discrete time/resource trade-off problem in the field of project scheduling. In this problem, a project contains activities interrelated by finish-start-type precedence constraints with a time lag of zero, which require one or more constrained renewable resources. Each activity has a specified work content and can be performed in different modes, i.e. with different durations and resource requirements, as long as the required work content is met. The objective is to schedule each activity in one of its modes in order to minimize the project makespan. We use a scatter search algorithm to tackle this problem, using path relinking methodology as a solution combination method. Computational results on randomly generated problem sets are compared with the best available results indicating the efficiency of the proposed algorithm. 相似文献
10.
Sadif A. Shirvan Fereydoon Khazali Sara Haydari Dezfuli Ali Borsalani 《Molecular Crystals and Liquid Crystals》2017,656(1):105-112
The new complex of [Hg(2-AMPy)2Cl]2.HgCl4 (1) was synthesized from the reaction of HgCl2 with 2-(aminomethyl)pyridine (2-AMPy) in methanolic solution. Suitable crystal of compound 1 for diffraction experiment was obtained by slow evaporation from dimethyl sulfoxide. Resulted complex was characterized by infrared, elemental analysis, thermal analysis, and single crystal X-ray diffraction. In the cationic part of this compound, two five-coordinated mercury centers have two different geometries, including distorted square-based pyramidal geometry by the trigonality index, τ5, of 0.23 and trigonal bipyramidal geometries by the trigonality index, τ5, of 0.57. 相似文献