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1.
Fereidoon Shahidi 《Journal of solution chemistry》1983,12(4):287-293
The partial molar volumesV° for a number of methoxybenzenes in carbon tetrachloride at 25°C have been determined. Results are in reasonable aggreement withV° values calculated by the addition of group increments to a covolume factor of 11.61 cm3-mol?1, and subtraction of fixed amounts for structural features known to involve intramolecular overcrowding. 相似文献
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Fereidoon Shahidi 《Journal of solution chemistry》1983,12(4):295-301
The partial molar volumes at infinite dilution for a number of hydrochlorides and sodium salts of N-methyl derivatives of , -aminocarboxylic acids in water at 25°C are measured and related to their van der Waals volumes. Results indicate that 4.96±0.48 water molecules hydrate a betaine hydrochloride. Volumes of proton ionization and interaction terms are evaluated. Group contributions to the partial molar volumes are also reported. 相似文献
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Extraction and analysis of phenolics in food 总被引:11,自引:0,他引:11
Phenolics are ubiquitous compounds found in all plants as their secondary metabolites. These include simple phenols, hydroxybenzoic acid and cinnamic acid derivatives, flavonoids, coumarines and tannins, among others. The extraction of phenolics from source materials is the first step involved in their analysis. While chemical methods are used for determination of total content of phenolics, chromatographic and spectrometric analyses are employed for identification and quantification of individual compounds present. This paper provides a summary of background information and methodologies used for the analysis of phenolics in foods and nutraceuticals. 相似文献
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Adriano Costa de Camargo Hernn Speisky Raquel Bridi Paula Núez Pizarro Arturo Larena Ana Clara da C. Pinaffi-Langley Fereidoon Shahidi Andrs R. Schwember 《Molecules (Basel, Switzerland)》2022,27(3)
The Valparaiso region in Chile was decreed a zone affected by catastrophe in 2019 as a consequence of one of the driest seasons of the last 50 years. In this study, three varieties (‘Alfa-INIA’, ‘California-INIA’, and one landrace, ‘Local Navidad’) of kabuli-type chickpea seeds produced in 2018 (control) and 2019 (climate-related catastrophe, hereafter named water stress) were evaluated for their grain yield. Furthermore, the flavonoid profile of both free and esterified phenolic extracts was determined using liquid chromatography-mass spectrometry, and the concentration of the main flavonoid, biochanin A, was determined using liquid chromatography with diode array detection. The grain yield was decreased by up to 25 times in 2019. The concentration of biochanin A was up to 3.2 times higher in samples from the second season (water stress). This study demonstrates that water stress induces biosynthesis of biochanin A. However, positive changes in the biochanin A concentration are overshadowed by negative changes in the grain yield. Therefore, water stress, which may be worsened by climate change in the upcoming years, may jeopardize both the production of chickpeas and the supply of biochanin A, a bioactive compound that can be used to produce dietary supplements and/or nutraceuticals. 相似文献
6.
Thaís Silva da Rocha Alessandro de Lima Jurandy do Nascimento Silva Geni Rodrigues Sampaio Rosana Aparecida Manlio Soares Freitas Renan Danielski Adriano Costa de Camargo Fereidoon Shahidi Elizabeth Aparecida Ferraz da Silva Torres 《Molecules (Basel, Switzerland)》2022,27(3)
Jua (juá in Portuguese) is an underexplored fruit from Brazil’s northeast. This fruit is rich in antioxidant substances. However, there is a dearth of information about jua’s bioactive potential. The present study evaluated two extraction methods (continuous agitation and ultrasound-assisted extraction—UAE) and employed three different solvents (water, ethanol, and acetone) to efficiently recover soluble phenolic compounds. Aqueous extracts obtained by UAE showed the highest total phenolic content (TPC) and antiradical activity. Besides being an eco-friendly procedure, extraction and/or solubility in an aqueous medium is also important for food application. Ellagic acids were the predominant phenolics (80%) found in aqueous jua pulp extract obtained by UAE, as determined by HPLC, while its TPC was 405.8 gallic acid equivalent per gram of fruit. This extract also exhibited a higher scavenging activity towards peroxyl radicals when compared to that of several other fruits from the literature, including grape, strawberry, cranberry, and walnuts, which are known references in terms of antioxidants. This is the first report that demonstrates jua pulp’s potential as an alternative source of ellagic acid and other phenolic acids and flavonoids. Therefore, the outcome of this study provides new information that can be useful for functional food and nutraceutical industries. 相似文献
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Measurements of the partial molar volumes in water at 25°C of the mono-and dihydrochlorides of the ,-diaminoalkanes, up to a chain length of 10 carbon atoms, are reported. Volumes of ionization have been determined and the electrostriction of the solvent calculated. Effects of the substituents are felt up to the -carbon atom, but thereafter are only very weak or nonexistent. 相似文献
8.
Bending analysis of thin functionally graded plates using generalized differential quadrature method
A. Fereidoon M. Asghardokht seyedmahalle A. Mohyeddin 《Archive of Applied Mechanics (Ingenieur Archiv)》2011,81(11):1523-1539
In this paper, the differential quadrature (DQ) method is presented for easy and effective analysis of isotropic functionally
graded (FG) and functionally graded coated (FGC) thin plates with constant Poisson’s ratio and varying Young’s modulus in
the thickness direction. The bending of FG and FGC plates under transverse loading has been studied using the polynomial differential
quadrature (PDQ) and the harmonic differential quadrature (HDQ) methods. A three-dimensional elasticity solution for a moderately
thick FG plate with exponential Young’s modulus is used as the benchmark. Two examples, including a thin FG rectangular plate
and a thin FGC rectangular plate with sigmoidal Young’s modulus, are investigated. The numerical results of PDQ and HDQ methods
reveal good agreement with other solutions. Also, it is shown that the formulations for thin FG plates and homogeneous plates
are similar, except that the plane strain components of the middle surface in FG plates are not zero. 相似文献
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Fereidoon Shahidi Patrick G. Farrell John T. Edward 《Journal of solution chemistry》1976,5(12):807-816
Partial molar volumes in water at 25°C have been determined for a number of carbohydrates, including mono-, di-, tri-, tetra-, penta-, hexa-, hepta-, and polysaccharides and their derivatives. The experimental values can be calculated from the van der Waals volumes of the molecules if account is taken of the shrinkage in volume caused by hydrogen-bonding of solvent molecules to the hydroxyl groups of the sugars. 相似文献