全文获取类型
收费全文 | 85篇 |
免费 | 4篇 |
国内免费 | 3篇 |
专业分类
化学 | 55篇 |
力学 | 6篇 |
数学 | 13篇 |
物理学 | 18篇 |
出版年
2022年 | 3篇 |
2021年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2015年 | 3篇 |
2014年 | 3篇 |
2013年 | 7篇 |
2012年 | 6篇 |
2011年 | 9篇 |
2010年 | 4篇 |
2009年 | 2篇 |
2008年 | 1篇 |
2007年 | 5篇 |
2006年 | 2篇 |
2005年 | 5篇 |
2004年 | 1篇 |
2003年 | 3篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1960年 | 1篇 |
排序方式: 共有92条查询结果,搜索用时 15 毫秒
1.
We consider a shock-type wave solution of the modified quintic complex Ginzburg-Landau equation and make a numerical study
of its spatiotemporal stability. Discussions related to the behavior of this front wave are introduced and it is shown how
the velocities of the wave can be used to collect information concerning the pattern formation in the system.
Published in Neliniini Kolyvannya, Vol. 10, No. 2, pp. 270–276, April–June, 2007. 相似文献
2.
Ion chromatography was used to determine trace anionic contamination on the surface of hard disk drive components. These contaminants can have a detrimental effect on device reliability and yield. Disk drive components were soaked in deionized water and these extracts were analyzed for anions. The anions fluoride, acetate, formate, acrylate, methacrylate, chloride, nitrite, bromide, nitrate, benzoate, sulfate, oxalate, phthalate and phosphate were separated on a high-performance anion-exchange column and determined at concentrations less than 1 microg/l with suppressed conductivity detection. The extract solutions were analyzed either by injecting 1 ml or by preconcentrating 5 ml. We evaluated the performance of both methods. 相似文献
3.
The tin-collection scheme of fire-assaying has been simplified to permit the rapid and accurate determination of platinum, palladium and gold in ores and related materials. The presence of tellurium in the charge ensures that the precious metals remain insoluble during the parting of the tin button with hydrochloric acid. The residue is easily collected and dissolved and the resultant solution analysed for the precious metals by AAS. The accuracy of the method has been established by application to five diverse certified reference materials. 相似文献
4.
We have evaluated the efficiency of a fast, simple and efficient method, fluorophore-assisted carbohydrate electrophoresis (FACE), for the characterization of plant N-linked glycans. After their enzymatic release from plant glycoproteins, N-glycans were reductively aminated to the charged fluorophore 8-aminonaphthalene-1, 3, 6-trisulfonic acid (ANTS) and separated using high resolution polyacrylamide gel electrophoresis. In addition, an affinity purification procedure using concanavalin A was developed for separation of ANTS-labeled high-mannose-type N-glycans from other plant oligosaccharides. 相似文献
5.
We prove the existence of fast traveling pulse solutions in excitable media with non-local coupling. Existence results had been known, until now, in the case of local, diffusive coupling and in the case of a discrete medium, with finite-range, non-local coupling. Our approach replaces methods from geometric singular perturbation theory, that had been crucial in previous existence proofs, by a PDE oriented approach, relying on exponential weights, Fredholm theory, and commutator estimates. 相似文献
6.
The infrared absorption of the ν3 band region of SF6, at temperatures spanning the 130 to 297 K range, has been reexamined using improved instrumentation with one goal: to estimate the broadening of parameters by nitrogen gas. These parameters are compared to previous literature predictions and an extended set of IR cross-sections is proposed and compared to other existing datasets. 相似文献
7.
Adams B Lowpetch K Thorndycroft F Whyte SM Young DW 《Organic & biomolecular chemistry》2005,3(18):3357-3364
Two members of the alpha-family of PLP-dependent enzymes, L-aspartate aminotransferase and D-amino acid aminotransferase, have been shown to catalyse beta-substitution of L- and D-beta-chloroalanine respectively with beta-mercaptoethanol, reactions typical of the beta-family of PLP-dependent enzymes. The reaction catalysed by L-aspartate aminotransferase has been shown to occur with retention of stereochemistry, a typical outcome for reactions catalysed by beta-family enzymes. There are also indications that the reaction catalysed by D-amino acid aminotransferase may involve retention of stereochemistry. Both enzymes have been shown to catalyse exchange at C-3 when the appropriate enantiomer of beta-chloroalanine is the substrate. 相似文献
8.
Bulk superconducting samples of type Tl0.5Pb0.5Sr1.6Ba0.4CaCu2−x
Ru
x
O7−δ, (Tl, Pb)/Sr-1212, with 0.0 ≤ x ≤ 0.525 were prepared by the conventional one-step solid-state reaction technique. The prepared samples were investigated
using X-ray powder diffraction, electrical resistivity and electron paramagnetic resonance (EPR) measurements. Enhancement
of the phase formation, superconducting transition temperature T
c and hole carriers concentration P was observed up to x = 0.075. For x > 0.075, a reverse trend was observed. EPR spectra were measured at different temperatures (120–290 K) for all prepared samples.
The number of spins N participating in the resonance and the paramagnetic susceptibility χ were calculated as a function of both Ru-content and
temperature. N and χ increased as the Ru-content increased. A linear relationship between logN and 1/T was established, from which the activation energy E
a was calculated as a function of the Ru-content. The temperature dependence of χ was fitted according to Curie–Weiss type
of magnetic behavior. Curie constant C, Curie temperature θ, the effective magnetic moment μ and the electronic specific heat γ were estimated as a function of the Ru-content. 相似文献
9.
We give a complete characterization of constant quadratic functions over an affine variety. This result is used to convexify
the objective function of a general quadratic programming problem (Pb) which contains linear equality constraints. Thanks
to this convexification, we show that one can express as a semidefinite program the dual of the partial Lagrangian relaxation
of (Pb) where the linear constraints are not relaxed. We apply these results by comparing two semidefinite relaxations made
from two sets of null quadratic functions over an affine variety.
相似文献
10.
Zofia M. Wosinska Faye L. Stump Rajeev Ranjan Edward D. Lorance GeNita N. Finley Priya P. Patel Muzamil A. Khawaja Katie L. Odom Wolfgang H. Kramer Ian R. Gould 《Photochemistry and photobiology》2014,90(2):313-328
Irreversible photooxidation based on N–O bond fragmentation is demonstrated for N‐methoxyheterocycles in both the singlet and triplet excited state manifolds. The energetic requirements for bond fragmentation are studied in detail. Bond fragmentation in the excited singlet manifold is possible for ππ* singlet states with energies significantly larger than the N–O bond dissociation energy of ca 55 kcal mol?1. For the nπ* triplet states, N–O bond fragmentation does not occur in the excited state for orbital overlap and energetic reasons. Irreversible photooxidation occurs in the singlet states by bond fragmentation followed by electron transfer. Irreversible photooxidation occurs in the triplet states via bimolecular electron transfer to the donor followed by bond fragmentation. Using these two sensitization schemes, donors can be irreversibly oxidized with oxidation potentials ranging from ca 1.6–2.2 V vs SCE. The corresponding N‐ethylheterocycles are characterized as conventional reversible photooxidants in their triplet states. The utility of these sensitizers is demonstrated by irreversibly generating the guanosine radical cation in buffered aqueous solution. 相似文献