In this work, (3,6-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-9-(4-vinylbenzyl)-9
H-carbazole) (EDOTVBCz) comonomer was chemically synthesized and characterized by Fourier transform infrared (FTIR), proton nuclear magnetic resonance, and carbon nuclear magnetic resonance spectroscopy. EDOTVBCz was electrocoated on glassy carbon electrode (GCE) in various initial molar concentrations ([EDOTVBCz]
0?=?1.0, 1.5, 2.0, and 3.0) in 0.1 M lithium perchlorate (LiClO
4)/acetonitrile (CH
3CN). P(EDOTVBCz)/GCE was characterized by cyclic voltammetry, FTIR reflectance-attenuated total reflection spectroscopy, scanning electron microscopy–energy dispersive X-ray analysis, atomic force microscopy, and electrochemical impedance spectroscopy (EIS). EIS was used to determine the capacitive behaviors of modified GCE via Nyquist, Bode magnitude, Bode phase, and admittance plots. The highest low-frequency capacitance value was obtained as
C LF?=?~2.35 mF cm
?2 for [EDOTVBCz]
0?=?3.0 mM. Double-layer capacitance of the polymer/electrolyte system was calculated as
C dl?=?~2.78 mF cm
?2 for [EDOTVBCz]
0?=?1.0 and 3.0 mM. The maximum phase angle was obtained as
θ?=?~76.7
o for [EDOTVBCz]
0?=?1.0, 1.5, 2.0, and 3.0 mM at the frequency of 20.6 Hz. AC impedance spectra of P(EDOTVBCz)/LiClO
4/CH
3CN was obtained by performing electrical equivalent circuit model of
R(
Q(
R(
CR))) with linear Kramers–Kronig test.
Figure SEM-EDX analysis of P(EDOTVBCz)/CFME EDX point analysis
inset: SEM point analysis, [EDOTVBCz]
0?=?3 mM. Chronoamperometric method of constant potential at 1.6 V, 300 s in 0.1 M LiClO
4/CH
3CN
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