Applications of SNMS in archaeometry

The recently developed High Frequency Mode HFM of electron gas SNMS allows investigations on insulating samples with the well known advantages of the SNMS Direct Bombardment Mode DBM for the analysis of conducting samples. HFM has been applied to analyses of different historic ceramic and glass samples in order to demonstrate the possibilities of SNMS in this field. It is shown that manufacturing places of ceramic samples could be distinguished by SNMS mass spectra ("fingerprints"). Furthermore questions of the constituents of colour remains on a painted ceramic ("Kaisermedaillon") could be answered by our SNMS analyses. SNMS investigations have been also applied to corrosion phenomena on different glass samples.     

The many faces of a character

We prove an identity between three infinite families of polynomials which are defined in terms of bosonic, fermionic, and one-dimensional configuration sums. In the limit where the polynomials become infinite series, they give different-looking expressions for the characters of the two integrable representations of the affine su(2) algebra at level one. We conjecture yet another fermionic sum representation for the polynomials which is constructed directly from the Bethe-ansatz solution of the Heisenberg spin chain.     

Beyond p-Hexaphenylenes: Synthesis of Unsubstituted p-Nonaphenylene by a Precursor Protocol

The synthesis of unsubstituted oligo-para-phenylenes ( OPP ) exceeding para-hexaphenylene—in the literature often referred to as p-sexiphenyl—has long remained elusive due to their insolubility. We report the first preparation of unsubstituted para-nonaphenylenes ( 9PP s) by extending our precursor route to poly-para-phenylenes ( PPP ) to a discrete oligomer. Two geometric isomers of methoxylated syn- and anti-cyclohexadienylenes were synthesized, from which 9PP was obtained via thermal aromatization in thin films. 9PP was characterized via optical, infrared and solid-state ¹³C NMR spectroscopy as well as atomic force microscopy and mass spectrometry, and compared to polymeric analogues. Due to the lack of substitution, para-nonaphenylene, irrespective of the precursor isomer employed, displays pronounced aggregation in the solid state. Intermolecular excitonic coupling leads to formation of H-type aggregates, red-shifting emission of the films to greenish. 9PP allows to study the structure–property relationship of para-phenylene oligomers and polymers, especially since the optical properties of PPP depend on the molecular shape of the precursor.     

Microwave oscillator based on Bloch oscillations of electrons in a semiconductor superlattice

We report on a microwave oscillator based on Bloch oscillations of electrons in a semiconductor superlattice. Our GaAs/AlAs superlattice, at room temperature, was coupled electromagnetically by an antenna to a rectangular cavity resonator, and was operated at a current-voltage state of negative differential conductance. We observed generation of microwave radiation at frequencies, depending on the resonator length, between 7 and 30 GHz. Electronic tuning by several percent was possible; the ratio of linewidth to frequency was of the order of 10^?4. A radiation power up to 1 μW (at 10 GHz) was obtained, corresponding to a generator efficiency of the order of 10^?3 for the conversion of electrical power to microwave radiation.     

Determination of the isotope distribution in partially deuterated compounds by NMR difference spectroscopy

The position and the isotope distribution within labelled compounds can be determined by NMR by analysing the difference spectrum, and its integral, of the labelled and the corresponding parent compound. The method is applied to m-terphenyl and it 4–4″-dideutero derivative.