Simultaneous separation of flavanone glycosides and polymethoxylated flavones in citrus juices using liquid chromatography

We present a simultaneous liquid chromatographic method for the separation of two flavonoid compound families, flavanone glycosides (FGs) and polymethoxylated flavones (PMFs), which are usually found in citrus fruit species and varieties. This technique permits the quantitation of six FGs (narirutin, naringin, hesperidin, neohesperidin, didymin, poncirin) and six PMFs (sinensetin, hexamethoxyflavone, nobiletin, scutellarein, heptamethoxyflavone and tangeretin). This technique, to be used to characterize a citrus juice by its polyphenolic profile, has been applied to the determination of flavonoid compounds in grapefruit- and orange juice. Differentiation of orange juice varieties and mixtures containing tangor juice using polyphenolic profiles and flavonoid content has been achieved.     

Timing performance of ZnO:Ga nanopowder composite scintillators

The implementation of nanocrystal‐based composite scintillators as a new generation of ultrafast particle detectors is explored using ZnO:Ga nanopowder. Samples are characterized with a spectral‐time resolved photon counting system and pulsed X‐rays, followed by coincidence time resolution (CTR) measurements under 511 keV gamma excitation. Results are comparable to CTR values obtained using bulk inorganic scintillators. Bringing the ZnO:Ga nanocrystal's timing performance to radiation detectors could pave the research path towards sub‐20 ps time resolution as shown in this contribution. However, an efficiency boost when placing nanopowders in a transparent host constitutes the main challenge in order to benefit from sub‐nanosecond recombination times. (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

Bridgman growth and site occupation in LuAG:Ce scintillator crystals

LuAG:Ce single crystals with various activator concentrations were grown by the vertical Bridgman technique. Characterization of crystals was done in terms of actual doping level, macroscopic defects and degree of non-equivalent substitutions by Lu for Al in octahedral lattice sites. Scintillation measurements were performed using 2×2×8 mm³ shaped samples with Ce concentration in the range 0.05–0.55 at%. Essential improvement of performance was demonstrated in samples containing ≥0.2 at% of Ce; the light yield measured in LuAG:Ce (0.55 at%) was about 26000 ph/MeV, or close to that of LSO.     

Derivation of anisotropic matrix for bi-dimensional strain-gradient elasticity behavior

The different forms of second order elasticity operators, in Mindlin’s strain-gradient elasticity, are given for a bi-dimensional physical space. These different forms are obtained according to the different symmetry classes of a material media. Dimensional aspects are discussed together with observations made on the physical behavior of such a media.     

On Anisotropic Polynomial Relations for the Elasticity Tensor

In this paper, we explore new conditions for an elasticity tensor to belong to a given symmetry class. Our goal is to propose an alternative approach to the identification problem of the symmetry class, based on polynomial invariants and covariants of the elasticity tensor C, rather than on spectral properties of the Kelvin representation. We compute a set of algebraic relations which describe precisely the orthotropic ( $[\mathbb {D}_{2}]$ ), trigonal ( $[\mathbb {D}_{3}]$ ), tetragonal ( $[\mathbb {D}_{4}]$ ), transverse isotropic ([SO(2)]) and cubic ( $[\mathbb {O}]$ ) symmetry classes in $\mathbb {H}^{4}$ , the highest-order irreducible component in the decomposition of $\mathbb {E}\mathrm {la}$ . We provide a bifurcation diagram which describes how one “travels” in $\mathbb {H}^{4}$ from a given isotropy class to another. Finally, we study the link between these polynomial invariants and those obtained as the coefficients of the characteristic or the Betten polynomials. We show, in particular, that the Betten invariants do not separate the orbits of the elasticity tensors.     

Discretisation of diffusive fluxes on hybrid grids

The main approaches of discretising the viscous operator of fluid flow on hybrid meshes are analysed for accuracy, consistence, monotonicity and sensitivity to mesh quality. As none of these approaches is fully satisfactory, a novel method using an approximated finite-element approach is presented and analysed. The methods are compared for the linear heat equation and the Navier–Stokes equations. While the novel approximated finite-element method performs significantly better for the linear heat equation, a stabilised edge-based method performs equally well for the considered test-cases for the Navier–Stokes equations.     

Analytical expressions for odd-order anisotropic tensor dimension

According to the symmetries of the matter, the number of coefficients needed to define a tensorial relation varies. It is well known that in linear elasticity the number of generic coefficients varies from 21, for a complete anisotropic material, to 2, in case of isotropy. In a previous contribution, we provided analytical expressions that give the number of generic anisotropic coefficients in any anisotropic system for an even-order tensor. In the present note, we aim at extending the previous results to the case of odd-order tensors. As an illustration, the dimension of any anisotropic system for third-order piezoelectricity tensors and of the fifth-order coupling tensors of Mindlin's strain-gradient elasticity are determined.