Semistar ascending chain conditions over polynomial rings

Ricerche di Matematica - Let D be an integral domain. G. Picozza associated to a stable semistar operation $$\star $$ on D,  a semistar operation $$\star _1$$ on the polynomial ring D[X]....     

Schwingungsspektren und Kraftkonstanten der Übergangsreihen OP(OCH3)3?OPCl3 und SP(OCH3)3?SPCl3

The IR- and RAMAN -spectra are reported from OP(OCH₃)₂Cl, OP(OCH₃)Cl₂, SP(OCH₃)Cl, SP(OCH₃)Cl₂. The assignement to the fundamental vibration is given and all Valence-force-constants are calculated. With increasing number of chlorine atoms decrease f P? OCH₃ and f P? Cl. In the contrary, f O? P and f S? P increase. Here the influence of decreasing electro negativity is compensated by the change from an element of the first period of eight elements to an element of the second period.     

Supply chain optimization of petroleum organization under uncertainty in market demands and prices

A multi-period stochastic planning model has been developed and implemented for a supply chain network of a petroleum organization operating in an oil producing country under uncertain market conditions. The proposed supply chain network consists of all activities related to crude oil production, processing and distribution. Uncertainties were introduced in market demands and prices. A deterministic optimization model was first developed and tested. The impact of uncertainty on the supply chain was studied by performing a sensitivity analysis in which ±20% deviations were introduced in market demands and prices of different commodities. A stochastic formulation was then proposed, which is based on the two-stage problem with finite number of realizations. The proposed stochastic programming approach proved to be quite effective in developing resilient production plans in light of high degree of uncertainty in market conditions. The anticipated production plans have a considerably lower expected value of perfect information (EVPI). The main conclusion of this study is that for an oil producing country with oil processing capabilities, the impact of economic uncertainties may be tolerated by an appropriate balance between crude exports and processing capacities.     

Identification of the Physical Parameters Used in the Thermo-Hygro-Mechanical Model

This paper describes different methods used to identify a large number of physical parameters of the thermo-hygro-mechanical coupling model. This model is developed on the basis of mechanics of porous media and deals with the prediction of response of a structure submitted to thermal, hygrometric and mechanical loading. The aim of this work is mainly to propose some experimental methods for the determination of physical parameters used previously in the model such as hygrometric parameters (liquid Biot's coefficient b _l , vapour and liquid permeability _v, _l and tangent capillary modulus N _ll). Thermal parameters such as thermal conductivity (), specific heat (C) and the thermo-hydrous expansion coefficient ( _i ^p ) have been identified using some works published previously. The different physical parameters were identified in the case of cement mortar without taking into account the influence of hysteresis.     

An uncertainty principle for the basic Bessel transform

The aim of this paper is to prove an uncertainty principle for the basic Bessel transform of order . In order to obtain a sharp uncertainty principle, we introduce and study a generalized q-Bessel-Dunkl transform which is based on the q-eigenfunctions of the q-Dunkl operator newly given by:

Synthesis and applications of copillar[5]arene dithiols

Abstract

A novel copillar[4+1]arene incorporating alkylthiol substituents was synthesised in three steps and structurally characterised as the first example of a pillar[n]arene to incorporate two terminal thiols on the same aromatic ring. The macrocycle was attached to gold electrodes through a standard dipping technique. Cyclic voltammetry demonstrated selectivity for Li⁺ over other alkali metal cations. The copillar[4+1]arene was also used as a capping agent in the preparation of 3 nm gold nanoparticles.     

Modification of mechanical and thermal property of chitosan–starch blend films

Chitosan–starch blend films (thickness 0.2 mm) of different composition were prepared by casting and their mechanical properties were studied. To improve the properties of chitosan–starch films, glycerol and mustard oil of different composition were used. Chitosan–starch films, incorporated with glycerol and mustard oil, were further modified with monomer 2-hydroxyethyl methacrylate (HEMA) using gamma radiation. The modified films showed improvement in both tensile strength and elongation at break than the pure chitosan–starch films. Water uptake of the films reduced significantly than the pure chitosan–starch film. Thermo gravimetric analysis (TGA) and dynamic mechanical analysis (DMA) showed that the modified films experience less thermal degradation than the pure films. Scanning electron microscopy (SEM) and FTIR were used to investigate the morphology and molecular interaction of the blend film, respectively.