Poly(vinyl alcohol)/heteropolyacid nanocomposites as new materials for radiochromic dosimetry in radiation processing

Radiochromic films composed of polymer matrices and organic dyes are widely used for routine dosimetry purposes in operation of various radiation facilities—gamma and X-ray-irradiation, electron accelerators, and so on. However, the sensitivity of these films rapidly decreases at doses exceeding 30–50 kGy due to a saturation of their optical response, making them unsuitable for accurate dosimetry in radiation processing of polymers and composites where doses up to 200 kGy are typically employed. To overcome this limitation, the use of inorganic substances as the coloring agents of polymer-based radiochromic films was proposed in this paper, specifically, heteropolyacidacid H₃PW₁₂O₄₀ (tungstophosphoric acid) in the matrix of poly(vinyl alcohol) (PVA). Nanocomposite PVA/H₃PW₁₂O₄₀ films were prepared by solution casting and their optical responses toward ⁶⁰Co gamma radiation and beams of 6 MeV electrons for a dose range of 10–200 kGy were investigated. It was established that upon exposure to gamma rays and electron beams, the films turn blue and a broad absorption band at 750 nm appears in their spectra. Importantly, the radiation-induced optical absorption increases in a linear fashion up to the dose of 150 kGy and only slightly deviates from linearity at 200 kGy. Moreover, it was found that the PVA/H₃PW₁₂O₄₀ films have a long shelf life, are dose-rate independent within a wide range, and color-stable after irradiation. All these features make the nanocomposite PVA/H₃PW₁₂O₄₀ films promising for use as routine dosimeters and dose labels in a much wider range of high doses as compared to radiochromic films based on organic dyes.     

Planck's constant and the theory of the red shift

This paper deals with problems on the threshold between General Relativity Theory and Quantum Theory. It contains some simple reasoning from which it follows that the so-called constanth cannot, in fact, be regarded as constant in General Relativity Theory.     

Fully three dimensional breather solitons can be created using feshbach resonances

We investigate the stability properties of breather solitons in a three-dimensional Bose-Einstein condensate with Feshbach resonance management of the scattering length and confined only by a one-dimensional optical lattice. We compare regions of stability in parameter space obtained from a fully 3D analysis with those from a quasi-two-dimensional treatment. For moderate confinement we discover a new island of stability in the 3D case, not present in the quasi-2D treatment. Stable solutions from this region have non-trivial dynamics in the lattice direction; hence, they describe fully 3D breather solitons. We demonstrate these solutions in direct numerical simulations and outline a possible way of creating robust 3D solitons in experiments in a Bose-Einstein condensate in a one-dimensional lattice. We point out other possible applications.     

On the stability of plane wave and soliton solutions to the Zakharov equations

Plane wave and soliton solutions of the two types of Zakharov equation (two dimensional and simplified one directional) are considered. Stability properties in one dimensional space are seen to be similar. This is interesting, as the first type of equation is not solvable whereas the second is. The soliton solutions of both are one dimensionally stable but those of the full Zakharov equations are unstable with respect to perpendicular perturbations. Regions of stability of nonlinear wave and shock wave solutions in parameter space as well as growth rates of instabilities are given.     

Order parameter of side groups of a polysiloxane in liquid crystalline uniaxial phases

The orientational order of a liquid crystalline side chain polysiloxane has been investigated by means of polarized light spectroscopy and dielectric relaxation measurements. The order parameters (P₂) and (P₄) have been determined as a function of the temperature for the smectic and nematic phases. The orienting properties of the polysiloxane investigated have been compared with those of a polysiloxane with the same mesogenic groups, but a shorter spacer.     

Study of orientational order in a nematic polysiloxane by utilizing the “guest–host” effect

A nematogenic side-chain polysiloxane is investigated by means of absorption and fluo-rescence spectroscopy.4-Dimethylamino-4′-nitrostilbene (DANS) is dissolved in the poly-meric matrix as a guest probe. The orientational order and the molecular distribution function have been determined from measurements of polarized absorption and fluorescence spectra. It has been found that fluorescence spectroscopy affords a method for determination of the phase transition temperatures of liquid–crystalline polymers. © 1993 John Wiley & Sons, Inc.     

Analysis of nanopore arrangement and structural features of anodic alumina layers formed by two-step anodizing in oxalic acid using the dedicated executable software

Anodic porous alumina layers were fabricated by a two-step self-organized anodization in 0.3 M oxalic acid under various anodizing potentials ranging from 30 to 60 V at two different temperatures (10 and 17 ^°C). The effect of anodizing conditions on structural features and pore arrangement of AAO was investigated in detail by using the dedicated executable publication combined with ImageJ software. With increasing anodizing potential, a linear increase of the average pore diameter, interpore distance, wall thickness and barrier layer thickness, as well as a decrease of the pore density, were observed. In addition, the higher pore diameter and porosity values were obtained for samples anodized at the elevated temperature, independently of the anodizing potential. A degree of pore order was investigated on the basis of Delaunay triangulations (defect maps) and calculation of pair distribution or angle distribution functions (PDF or ADF), respectively. All methods confirmed that in order to obtain nanoporous alumina with the best, hexagonal pore arrangement, the potential of 40 V should be applied during anodization. It was confirmed that the dedicated executable publication can be used to a fast and complex analysis of nanopore arrangement and structural features of nanoporous oxide layers.