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1.
Annija Lace Aideen Byrne Simon Bluett Laurent Malaquin Vincent Raimbault Remi Courson Zain Hayat Breda Moore Eoin Murray 《Journal of separation science》2022,45(5):1042-1050
An ion chromatography system employing a low-cost three-dimensional printed absorbance detector for indirect ultraviolet detection towards portable phosphate analysis of environmental and industrial waters has been developed. The optical detection cell was fabricated using stereolithography three-dimensional printing of nanocomposite material. Chromatographic analysis and detection of phosphate were carried out using a CS5A 4 × 250 mm analytical column with indirect ultraviolet detection using a 255 nm light-emitting diode. Isocratic elution using a 0.6 mM potassium phthalate eluent combined with 1.44 mM sodium bicarbonate was employed at a flow rate of 0.75 mL/min. A linear calibration range of 0.5 to 30 mg/L PO43− applicable to environmental and wastewater analysis was achieved. For retention time and peak area repeatability, relative standard deviation values were 0.68 and 4.09%, respectively. Environmental and wastewater samples were analyzed with the optimized ion chromatography platform and the results were compared to values obtained by an accredited ion chromatograph. For the analysis of environmental samples, relative errors of <14 % were achieved. Recovery analysis was also carried out on both freshwater and wastewater samples and recovery results were within the acceptable range for water analysis using standard ion chromatography methods. 相似文献
2.
A range of pyrazolidin-3-ones have been prepared and their activity as catalysts for iminium-ion promoted Diels-Alder reactions evaluated. Systematic variation of the C(5)- and N(2)-substituents indicates that the incorporation of an electron withdrawing substitutent at N(2) and either a Ph or CF3 substitution at C(5) results in optimal catalytic activity. The diastereoisomeric resolution of a model C(5)-Ph substituted pyrazolidinone and its ability to impart modest levels of asymmetric induction in the organocatalytic Diels-Alder reaction is also demonstrated. 相似文献
3.
Eoin Moriarty 《Tetrahedron letters》2009,50(37):5251-2730
The preparation of alicyclic ring-fused tetracyclic and pentacyclic benzimidazoles containing one and two fused aryl rings, respectively, is achieved conveniently in three steps, including Bu3SnH-mediated 6-exo-trig cyclization of σ-aryl radicals generated from 1-allyl-2-(ω-bromoaryl)benzimidazoles. Inclusion of 4,7-dimethoxy substituents on the radical precursors allows access to aryl ring-fused benzimidazolequinones, a unique family of potential bioreductive anti-cancer agents. 相似文献
4.
A technique to optimize the stability of a general mechanical system is outlined. The method relies on decomposing the damping matrix into several component matrices, which may have some special structure or physical relevance. An optimization problem can then be formulated where the ratio of these are varied to either stabilize or make more stable the equilibrium state subject to sensible constraints. For the purpose of this study, we define a system to be more stable if its eigenvalue with largest real part is as negative as possible. The technique is demonstrated by applying it to an introduced non-dimensionalized variant of a known minimal wobbling disc brake model. In this case, it is shown to be beneficial to shift some damping from the disc to the pins for a system optimized for stability. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
5.
Schulzendorf M Cavelius C Born P Murray E Kraus T 《Langmuir : the ACS journal of surfaces and colloids》2011,27(2):727-732
We report the synthesis of well-dispersed core-shell Au@SiO(2) nanoparticles with minimal extraneous silica particle growth. Agglomeration was suppressed through consecutive exchange of the stabilizing ligands on the gold cores from citrate to L-arginine and finally (3-mercaptopropyl)triethoxysilane. The result was a vitreophilic, stable gold suspension that could be coated with silica in a biphasic mixture through controlled hydrolysis of tetraethoxysilane under L-arginine catalysis. Unwanted condensation of silica particles without gold cores was limited by slowing the transfer across the liquid-liquid interface and reducing the concentration of the L-arginine catalyst. In-situ dynamic light scattering and optical transmission spectroscopy revealed the growth and dispersion states during synthesis. The resulting core-shell particles were characterized via dynamic light scattering, optical spectroscopy, and electron microscopy. Their cores were typically 19 nm in diameter, with a narrow size distribution, and could be coated with a silica shell in multiple steps to yield core-shell particles with diameters up to 40 nm. The approach was sufficiently controllable to allow us to target a shell thickness by choosing appropriate precursor concentrations. 相似文献
6.
Eoin F. Clarke Helge Müller-Bunz Declan G. Gilheany 《Journal of organometallic chemistry》2011,696(23):3608-819
The synthesis is reported of novel P-stereogenic binaphthyl substituted monophosphines via a short five-step synthesis using a nickel coupling reaction with separation of the borane-protected diastereomeric products. Extensive coordination studies of these ligands with a number of well-known metal precursors were performed to more effectively understand their behaviour during catalysis.These ligands and some previously reported P-stereogenic ligands were tested in the rhodium catalysed asymmetric addition of phenyl boronic acid to napthaldehyde. These studies in asymmetric catalysis were used to compare the chiral induction of ligands that combine both axial and central chirality with ligands lacking P-stereogenicity. 相似文献
7.
Eoin O''Ciardha Jason Lynch Brendan Lyons Sean Cremin Sverre Lidholm 《International Journal of Infrared and Millimeter Waves》2002,23(6):841-854
Details on a broadband MMIC frequency doubler targeting the MVDS market are presented. The design evolution from an individual pHEMT device to the complete practical doubler realisation is discussed. The doubler MMIC, which has been fabricated using the GMMT H40 GaAs process, has been evaluated in a customised package. An output power of +10 dBm at 40 GHz has been achieved with an associated conversion gain of 1.5 dB. The measured and predicted performance responses are compared. This chip is ideally suited to use in a number of emerging mm-wave applications. 相似文献
8.
Eoin Long 《Combinatorica》2013,33(4):395-428
Let Q n denote the graph of the n-dimensional cube with vertex set {0, 1} n in which two vertices are adjacent if they differ in exactly one coordinate. Suppose G is a subgraph of Q n with average degree at least d. How long a path can we guarantee to find in G? Our aim in this paper is to show that G must contain an exponentially long path. In fact, we show that if G has minimum degree at least d then G must contain a path of length 2 d ? 1. Note that this bound is tight, as shown by a d-dimensional subcube of Q n . We also obtain the slightly stronger result that G must contain a cycle of length at least 2 d . 相似文献
9.
The multileaf collimator sequencing problem is an important component in effective cancer treatment delivery. The problem can be formulated as finding a decomposition of an integer matrix into a weighted sequence of binary matrices whose rows satisfy a consecutive ones property. Minimising the cardinality of the decomposition is an important objective and has been shown to be strongly NP-hard, even for a matrix restricted to a single column or row. We show that in this latter case it can be solved efficiently as a shortest path problem, giving a simple proof that the one-row problem is fixed-parameter tractable in the maximum intensity. We develop new linear and constraint programming models exploiting this result. Our approaches significantly improve the best known for the problem, bringing real-world sized problem instances within reach of exact algorithms. 相似文献
10.
The synthesis of amidourea-based colorimetric anion sensors 1 and 2 and the evaluation of these sensors using anions such as acetate , fluoride (F−), hydrogen phosphate and hydrogenpyrophosphate (pyr) in DMSO is described. While 1 has a single amidourea moiety, 2 has two such receptors incorporated into a lower-rim 1,3-disubstituted calix[4]arene scaffold. Whilst both sensors gave rise to red shifts in their absorption spectra upon anion recognition, the sensing of F− and pyr gave rise to large changes with concomitant colour changes from yellow to purple, which were visible to the naked eye. 相似文献