全文获取类型
收费全文 | 1440篇 |
免费 | 47篇 |
国内免费 | 8篇 |
专业分类
化学 | 967篇 |
晶体学 | 8篇 |
力学 | 26篇 |
数学 | 204篇 |
物理学 | 290篇 |
出版年
2022年 | 10篇 |
2021年 | 23篇 |
2020年 | 28篇 |
2019年 | 27篇 |
2018年 | 26篇 |
2017年 | 20篇 |
2016年 | 52篇 |
2015年 | 31篇 |
2014年 | 52篇 |
2013年 | 107篇 |
2012年 | 74篇 |
2011年 | 111篇 |
2010年 | 77篇 |
2009年 | 56篇 |
2008年 | 87篇 |
2007年 | 72篇 |
2006年 | 74篇 |
2005年 | 72篇 |
2004年 | 69篇 |
2003年 | 28篇 |
2002年 | 29篇 |
2001年 | 30篇 |
2000年 | 19篇 |
1999年 | 18篇 |
1998年 | 12篇 |
1997年 | 5篇 |
1996年 | 19篇 |
1995年 | 13篇 |
1994年 | 9篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 14篇 |
1990年 | 10篇 |
1989年 | 9篇 |
1988年 | 9篇 |
1987年 | 9篇 |
1986年 | 11篇 |
1985年 | 16篇 |
1984年 | 28篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 5篇 |
1980年 | 9篇 |
1979年 | 15篇 |
1978年 | 10篇 |
1977年 | 7篇 |
1976年 | 15篇 |
1975年 | 9篇 |
1974年 | 12篇 |
1973年 | 8篇 |
排序方式: 共有1495条查询结果,搜索用时 15 毫秒
1.
Hiroshi Noguchi Masanori Ueda Yoshinobu Baba Masako Takasu 《Journal of Polymer Science.Polymer Physics》2003,41(12):1316-1322
The electrophoresis of DNA chains in uncrosslinked polymer solutions with a Brownian dynamics simulation with an anisotropic friction tensor was analyzed. According to the degree of anisotropy, three types of migration behavior are obtained: fluctuation without or with periodicity between U‐shaped and compact conformations, or migration with linear conformation. We found good agreement between our simulation results and the direct observations of DNA by fluorescence microscopy. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1316–1322, 2003 相似文献
2.
The luminous intensity unit of candela was realized based on filter-radiometer, which is traceable to detector-based primary standard electrical substitution cryogenic radiometer (ESCR). In that realization the traditional Osram Wi41/G-type incandescent lamp and filter-radiometer consisting of an aperture, a V(λ) filter and a silicon photodiode based trap detector were used as light source and detection element, respectively. Measurement techniques of effective aperture area, spectral transmittance of V(λ) filter and absolute responsivity of trap detector are also presented. 相似文献
3.
We theoretically investigated the mass dependence of the sympathetic cooling rate of gas-phase ions trapped in a linear radio-frequency-quadrupole
ion trap. Using an a priori molecular dynamical calculation, tracing numerically with Newtonian equations of motion, we found
that ions with a mass greater than 0.54±0.04 times that of the laser-cooled ions are sympathetically cooled; otherwise, they
are heated. To understand the mass dependence obtained using the molecular-dynamical calculation, we made a heat-exchange
model of sympathetic cooling, which shows that the factor of 0.54±0.04 is a consequence of absence of micro-motion along the
axis of the linear ion trap.
Received: 10 December 2001 / Revised version: 28 January 2002 / Published online: 14 March 2002 相似文献
4.
5.
Tatsushi Baba 《Tetrahedron letters》2004,45(31):5973-5975
New water-soluble porphycenes having sulfonic acid groups at the β-pyrrolic positions were synthesized and characterized by UV-vis, NMR, IR, and mass spectroscopy as well as elemental analyses. The series of mono- to tri-sulfonato derivatives were simply separated by the extraction method. 相似文献
6.
Toshihide Baba Satoru Hikita Haruhisa Handa Yoshio Ono 《Research on Chemical Intermediates》1998,24(5):495-505
Europium supported on alumina (Eu/Al2O3) was prepared by impregnation from an ammoniacal solution of the metal. The catalytic activity of Eu/Al2O3 for the isomerization of 2,3-dimethylbut-1-ene to 2,3-dimethylbut-2-ene was examined. Eu/Al2O3 showed the highest catalytic activity for the isomerization when heated under a vacuum at 523 K, the yield of 2,3-dimethylbut-2-ene
in 20 min being 81.6% at 314 K. IR spectrum shows the presence of two kinds of Eu amides. The change of the IR spectra and
the catalytic activities with evacuation temperature suggest that only one of the two Eu amides is catalytically active for
this base-catalyzed isomerization. 相似文献
7.
8.
9.
Two Optically Active Luteochromes: Preparation, Spectra and Chiroptical and Chromatographic Properties Selective rearrangement of (5R,6S,5′ R,6′S)-5,6:5′, 6′ -diepoxy-5,6,5′, 6′ -tetrahydro- β,β -carotene with the aid ofan ethereal solution of malonic acid leads to the mixture of the C(8′)-epimeric luteochromes. HPLC separation gave the pure isomers. This is the first report on th preparation of optically active luteochromes. 相似文献
10.
Mauss F. Murat M. Missiaen J. M. Guilhot B. 《Journal of Thermal Analysis and Calorimetry》1996,47(3):799-813
Dehydration of hydrated ammonium alum is a function of physical gaseous pressure. During dehydration, two kinds of partially dehydrated amorphous alum appears. These solids differ in texture and residual water composition. 相似文献