Investigating the interaction of crystal violet probe molecules on sodium dodecyl sulfate micelles with hyper-Rayleigh scattering

We report the use of the nonlinear optical technique of hyper-Rayleigh scattering to investigate the interaction of the cationic probe molecule crystal violet with micelles of sodium dodecyl sulfate. An absolute value of (847 +/- 80) x 10(-30) esu is measured at the fundamental wavelength of 870 nm for the molecular hyperpolarizability of crystal violet free in pure aqueous solutions. In aqueous solutions of sodium dodecyl sulfate, above and below the critical micelle concentration, the measured hyperpolarizability of crystal violet is weaker than in the solution free of sodium dodecyl sulfate. From the comparison with linear optical photoabsorption spectroscopy data, this difference is attributed to electrostatic interactions between the cationic crystal violet molecules and the negatively charged sodium dodecyl sulfate surfactant molecules present in excess. Polarization resolved hyper-Rayleigh scattering measurements are then performed to show that, below and above the critical micelle concentration, crystal violet molecules also undergo symmetry changes upon interaction with sodium dodecyl sulfate. Above the critical micelle concentration, the minimum fraction of micelles interacting with at least one CV molecule is estimated. For instance, for a crystal violet aqueous concentration of 150 microM, this fraction is larger than 7%.     

Protein-Polysaccharide Interactions for Stabilization of Food Emulsions

Proteins, polysaccharides and their blends, as examples of natural biopolymers, are surface active materials. Biopolymers may be considered as amphiphilic macromolecules that play an essential role in stabilizing food formulations (foams, emulsions and dispersions). Under specific conditions (such as protein-to-polysaccharide ratio, pH, ionic strength, temperature, mixing processing), it has been stated that proteins and polysaccharides form hybrids (complexes) with enhanced functional properties in comparison to the proteins and polysaccharides alone. Different protein-polysaccharide pairs are reviewed with particular attention to the emulsification capability of their mixtures. In the case of uncomplexed blends of biopolymers, competitive adsorption onto hydrophobic surfaces is generally reported. Conversely, electrostatic complexation between oppositely charged proteins and polysaccharides allows better anchoring of the new-formed macro-molecular amphiphile onto oil-water interfaces. Moreover, improved thermal stability and increased resistance to external treatment (high pressure) involved in food processing are obtained. This review presents basic and applied knowledge on protein-polysaccharide interactions in aqueous medium and at the oil-water interface in food emulsion systems. Electrostatic interactions and thermodynamic incompatibility in mixed biopolymer solutions are correlated to the functional properties (rheology, surface hydrophobiciry, emulsification power) of these interesting blends. Basic and industrial selected systems of different families of hydrocolloids (as gum Arabic, galactomannans, pectins) and protein (caseins, whey, soya, gelatin) mixtures are reviewed.     

Hyper Rayleigh scattering of protein-mediated gold nanoparticles aggregates

The second harmonic generation response from protein-mediated gold nanoparticles assemblies in solution has been studied by the technique of hyper Rayleigh scattering (HRS). It is found that the HRS intensity from biotinylated bovine serum albumin coated gold nanoparticles is enhanced when StreptAvidin is added into the solution. This increase in intensity is attributed to the aggregation of the gold nanoparticles through the binding of biotin and StreptAvidin. Comparison with photo-absorption spectroscopy indicates that the technique of HRS is a potential tool in detecting small levels of particle aggregation in liquid samples.     

Non perturbative approach for a polar and polarizable linear molecule in an inhomogeneous electric field: Application to molecular beam deviation experiments

A non perturbative approach is used to solve the problem of a rigid linear molecule with both a permanent dipole moment and a static dipole polarizability, in a static electric field. Eigenenergies are obtained and compared to perturbative low field and high field approximations. Analytical expressions for the orientation parameters and for the gradient of the energy are given. This non perturbative approach is applied to the simulation of beam deviation experiments in strong electric field. Results of simulations are given for inhomogeneous alkali dimers. For LiNa, the simulations are compared to experimental data. For LiK, deviation profiles have been simulated in order to prepare future experiments on this molecule. Received 21 July 1999 and Received in final form 22 September 1999     

Multiple submillimeter emissions of difluoromethane pumped by cw 9R(6) laser line of 12C16O2

Pumped by the 9R(6) ¹²C¹⁶O₂ laser lines, CH₂F₂ produces five SMM emissions. Levels involved in this process are identified with the help of a Fourier transform spectrum. Among these emissions we find cascade and intervibrational transitions allowed by Coriolis resonance between v₉ and v₃.     

Experiments in mixed-integer linear programming

This paper presents a branch and bound method for solving mixed integer linear programming problems. After briefly discussing the bases of the method, new concepts called pseudo-costs and estimations are introduced. Then, the heuristic rules for generating the tree, which are the main features of the method, are presented. Numerous parameters allow the user for adjusting the search strategy to a given problem.This method has been implemented in the IBM Extended Mathematical Programming System in order to solve large mixed integer L. P. problems. Numerical results making comparisons between different choices of rules are provided and discussed.This paper was presented at the 7th Mathematical Programming Symposium The Hague, The Netherlands.     

The efficient solution of large-scale linear programming problems—some algorithmic techniques and computational results

First, this paper presents the results of experiments with algorithmic techniques for efficiently solving medium and large scale linear and mixed integer programming problems. The techniques presented here are either original or recent.The solution of a great number of problems has shown that efficient problem solving requires automatic adaptation of algorithmic techniques upon problem characteristics. We show when a given technique should be used for a particular problem.The last part of this paper describes an attempt to provide a powerful mathematical programming language, allowing an easy programming of specific studies on medium-size models such as the recursive use of LP or the build-up of algorithms based on the simplex method.All these features have been implemented in the IBM Mathematical Programming System, MPSX/370, and its feature MIP/370. Extensive numerical results and comparisons on real-life problems are provided and commented upon.Presented at the IXth International Symposium on Mathematical Programming in Budapest (1976).     

Effect of a thioalkane capping layer on the first hyperpolarizabilities of gold and silver nanoparticles

We have measured the first hyperpolarizabilities of thioalkane capped silver and gold metallic nanoparticles. The values found are β(AgC 12-10 nm) = (2.10 ± 0.23) × 10(-26) esu for 10 nm diameter silver nanoparticles and β(AuC 18-18 nm) = (3.37 ± 0.08) × 10(-26) esu for 18 nm diameter gold nanoparticles at the fundamental wavelength of 784 nm. By comparison to the corresponding values reported for citrate capped silver and gold metallic nanoparticles, after size corrections, decreases by factors of 4.3 and 6.5 respectively are observed. These decreases are tentatively attributed to the bonds formed between the gold and silver surface atoms and the sulfur atoms of the capping layer.     

Second harmonic generation monitoring of nitric acid extraction by a monoamide at the water-dodecane interface

The interface dynamic properties of a monoamide extractant with potential for application to the front end of the nuclear cycle and to waste treatment are examined by second harmonic generation. The results are compared with bulk nitric ion titration and surface pressure measurements. SH static studies show the extractant reaching the interface and accurately match the IFT measurements. The main feature of the SH dynamic studies is a chaotic fluctuation period, strongly related to intense extraction. Fluctuations are a signature of the interface behaviour during the extraction process. Vertical development of the interface, often called protrusion, remains the most probable origin of the measured fluctuation. Additionally, interfacial measurements show a non-monotonic lag time during extraction, probably related to cooperative effects not observed in the bulk at the working concentration. Such mutual behaviour could be a supplementary prerequisite for the ion transfer across this liquid-liquid interface.     

Assignments of submillimeter emissions in difluoromethane pumped by12C18O2 and12C18O2 lasers

A FT spectrum of ₃, ₉ and ₇ of CH₂F₂ is recorded and assigned between 1030 and 1230 cm^–1. Coincidences with CO₂ lasers are investigated.Submillimeter emissions are unambiguously assigned by a loop procedure including only IR and SMM measurements. In some cases pseudo-loops are added using ground state computed energies. In spite of the large perturbations, an exact model for excited vibrational states is not needed to ascertain SMM assignments.