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1.
R. J. Smith P. J. Woods R. Chapman J. L. Durell J. N. Mo B. R. Fulton R. A. Cunningham 《Zeitschrift für Physik A Hadrons and Nuclei》1986,324(3):283-287
The ground-state masses of35Si and34Si have been measured using the reactions64Ni(36S,35,34Si)65,66Zn at a36S beam energy of 198 MeV.34,35Si14+ ions were analysed and identified in a QMG/2 magnetic spectrometer and gas-filled focal-plane detector. The experimental mass excess of35Si was determined to be ?14.58± 0.12 0.07 MeV while that of34Si was measured as ?19.961±0.034 MeV. A comparison is made with the results of mass model predictions. 相似文献
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4.
Garcia Ruano JL Alemparte C Martin Castro AM Adams H Rodriguez Ramos JH 《The Journal of organic chemistry》2000,65(23):7938-7943
The behavior of (Z)-3-p-tolylsulfinylacrylonitrile (1) as a chiral dienophile has been evaluated from its reactions with furan and acyclic dienes. Electrostatic interactions of the cyano group with the sulfinyl one restrict the conformational mobility around the C-S bond, thus controlling the pi-facial selectivity, which is almost complete in all cases, the approach of the diene from the less-hindered face of the dienophile (that bearing the lone electron pair) in the predominant rotamer being the favored one. The regioselectivity is also completely controlled by the cyano group. Additionally, the reactivity of compound 1 as well as its endo-selectivity are both higher than those observed for the corresponding (Z)-3-sulfinylacrylates, thus proving the potential of sulfinylnitriles as chiral dienophiles. 相似文献
5.
Garcia Ruano JL Alcudia A del Prado M Barros D Maestro MC Fernandez I 《The Journal of organic chemistry》2000,65(10):2856-2862
The addition of the lithium anions derived from (R)- and (S)-methyl and -ethyl p-tolyl sulfoxides to (S)-N-benzylidene-p-toluenesulfinamide provides an easy access route to enantiomerically pure beta-(N-sulfinyl)amino sulfoxides. Stereoselectivity can be achieved when the configurations at the sulfur atoms of the two reagents are opposite (matched pair), thus resulting in only one diastereoisomer, even for the case in which two new chiral centers are created. The N-sulfinyl group primarily controls the configuration of the carbon bonded to the nitrogen, whereas the configuration of the alpha-sulfinyl carbanion seems to be responsible for the level of asymmetric induction, as well as for the configuration of the new stereogenic C-SO carbon in the reactions with ethyl p-tolyl sulfoxides. An efficient method for transforming the obtained beta-(N-sulfinyl)amino sulfoxides into optically pure beta-amino alcohols, based on the stereoselective non-oxidative Pummerer reaction, is also reported. 相似文献
6.
The reaction 40Ca(13C, 12C)41Ca leading to the ground and low-lying ? levels has been studied at bombarding energies of 18.5 and 19.0 MeV, close to the Coulomb barrier. The cross sections have been analysed using the DWBA with previously measured calibrations to obtain the rms radii of 1f and 2p orbits in the 41Ca levels. The rms radius of the 1f point neutron orbit in the ground state relative to the 40Ca core was determined to be 3.89 ± 0.12 fm. This is compared with various theoretical predictions based on Hartree-Fock theory. The 1f orbit radius gives the point neutron excess size to a good approximation for comparison with the value of 3.45 fm deduced from Coulomb energy differences. The consistency of the results with 40Ca(t, d)41Ca experiments using a (t/d), zero-range normalization of 3.26 × 104 MeV2 · fm3 is demonstrated, and trends in neutron size parameters through the Ca isotopes are discussed. 相似文献
7.
W. Urban T. Rzaca-Urban N. Schulz J.L. Durell W.R. Phillips A.G. Smith B.J. Varley I. Ahmad 《The European Physical Journal A - Hadrons and Nuclei》2003,16(3):303-307
Excited levels in 140Xe and 142Xe nuclei, populated in the spontaneous fission of 248Cm, were studied by means of prompt γ-ray spectroscopy, using EUROGAM2 array. We report the first observation of an octupole
band in 142Xe and extend the octupole band in 140Xe. Level schemes of 140Xe and 142Xe obtained in this work show patterns characteristic of ocupole-vibrational bands. Properties of octupole bands in Xe isotopes
indicate that octupole correlations in these nuclei are lower than in the corresponding Ba nuclei. The electric dipole moment
of 142Xe was found to be larger than in other Xe isotopes, contrary to theoretical predictions. This may be due to the special role
of the N = 88 neutron number.
Received: 18 November 2002 / Accepted: 15 December 2002 / Published online: 25 February 2003
RID="a"
ID="a"e-mail: urban@fuw.edu.pl
Communicated by D. Schwalm 相似文献
8.
The space group of alpha(')-NaV2O5 turns below T(c) = 34 K from Pmmn with all V sites equivalent, into Fmm2 with three independent vanadium sites per layer. This is incompatible with models of charge ordering into V4+ and V5+. Our structure determination indicates that the phase transition consists of a charge ordering with three distinct valence states, formally V4+, V4.5+, and V5+. The singlet formation is not associated with dimerization on the spin ladder, but with the formation of spin clusters. Finally, we ascribe the quadrupling of the c axis to the large polarizability of the V2O5 skeleton. 相似文献
9.
Acoustic performance in ultrasonic transmitters can be improved by means of a suitable electrical driving response and matching/tuning networks. It is important to predict this electrical response, but doing so is not easy because it departs notably from the nominal pattern with the loading probes. In practice, the analysis of HV pulser spikes in NDE applications requires fairly complex models in the transient regime and, in addition, non-linear problems could arise, especially in the case of tuned transmitters. In this paper, the most relevant influences of loading characteristics of NDT ultrasonic probes on the pulser electrical driving responses are evaluated in time and frequency domains. Conventional pulse generators and typical NDE pulsers are considered. Driving responses are analysed across commercial ultrasonic probes and, alternatively, across similar purely electrical loads. Distinct influences on pulser responses from electrical and motional sections of the probes are identified. All these aspects are studied on the basis of experimental and computer results. 相似文献
10.
P.J. Daly C.T. Zhang P. Bhattacharyya R. Broda Z.W. Grabowski D. Nisius I. Ahmad M.P. Carpenter L.R. Morss W.R. Phillips J.L. Durell M.J. Leddy A.G. Smith W. Urban B.J. Varley N. Schulz E. Lubkiewicz M. Bentaleb J. Blomqvist 《Zeitschrift für Physik A Hadrons and Nuclei》1997,358(2):203-204
Prompt γ-ray cascades in neutron-rich nuclei around doubly-magic 132Sn have been studied using a 248Cm fission source. Yrast states located in the N = 82 isotones 134Te and 135I are interpreted as valence proton and neutron particle-hole core excitations with the help of shell model calculations employing empirical nucleon-nucleon interactions from both 132Sn and 208Pb regions. 相似文献