全文获取类型
收费全文 | 271篇 |
免费 | 3篇 |
国内免费 | 4篇 |
专业分类
化学 | 190篇 |
数学 | 31篇 |
物理学 | 57篇 |
出版年
2021年 | 1篇 |
2020年 | 2篇 |
2019年 | 5篇 |
2018年 | 1篇 |
2017年 | 3篇 |
2016年 | 6篇 |
2015年 | 8篇 |
2014年 | 3篇 |
2013年 | 6篇 |
2012年 | 9篇 |
2011年 | 15篇 |
2010年 | 9篇 |
2009年 | 9篇 |
2008年 | 10篇 |
2007年 | 16篇 |
2006年 | 13篇 |
2005年 | 8篇 |
2004年 | 13篇 |
2003年 | 14篇 |
2002年 | 10篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 6篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 8篇 |
1993年 | 5篇 |
1992年 | 7篇 |
1991年 | 5篇 |
1990年 | 6篇 |
1989年 | 4篇 |
1988年 | 9篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 6篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1941年 | 2篇 |
排序方式: 共有278条查询结果,搜索用时 15 毫秒
1.
2.
Hans R. Kricheldorf Nino Lomadze Detlev Fritsch Gert Schwarz 《Journal of polymer science. Part A, Polymer chemistry》2006,44(18):5344-5352
5,5′,6,6′‐Tetrahydroxy‐3,3,3′,3′‐tetramethylspirobisindane was polycondensed with 1,4‐dicyanotetrafluorobenzene in four different solvents at 70 °C. In dimethylformamide, N‐methylpyrrolidone, and sulfolane exclusively, cyclic polymers were detectable by matrix‐assisted laser desorption/ionization time‐of‐flight (MALDI‐TOF) mass spectrometry up to masses around 13,000 Da. In dimethyl sulfoxide, linear byproducts were also found. Higher temperatures caused degradation reactions catalyzed by potassium carbonate. Polycondensations performed with the addition of 4‐tert‐butyl catechol or 2,2′‐dihydroxy binaphthyl yielded linear telechelic oligomers. Equimolar mixtures of linear and cyclic ladder polymers were examined by MALDI‐TOF mass spectra to determine how the end groups and the cyclic structure influenced the signal‐to‐noise ratio. The results suggested a preferential detection of the linear chains. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5344–5352, 2006 相似文献
3.
It is shown that any local quantum field theory admits thermodynamical equilibrium states (KMS-states) for all positive temperatures provided it satisfies a nuclearity condition, proposed by Wichmann and one of the authors, which restricts the admissible number of local degrees of freedom.Dedicated to E. H. Wichmann on the occasion of his 60th birthday 相似文献
4.
5.
6.
Water vapor can be a significant interference in the analysis of air for non-methane volatile organic compounds (NMVOCs) using solid-adsorbent sampling techniques. The adsorbent materials used in sampling cartridges have different hydrophobic characteristics, and it is therefore necessary to characterize solid-adsorbent cartridges over a wide range of humidity. Controlled humidity experiments were performed to assess the extent of water vapor interference when samples are collected onto AirToxics solid-adsorbent cartridges. It was found that elevating the temperature of the cartridge to 10 degrees C above the temperature of the air sample greatly reduced water vapor adsorption and interferences and resulted in > or = 90% recovery of NMVOCs, biogenic VOCs and chlorofluorocarbons. Similar collection efficiencies were obtained at ambient temperature by reducing the relative humidity to > or = 60% in the sample by dilution with dry, scrubbed ambient air. A procedure also was developed and optimized for dry-purging cartridges prior to analysis. However, under optimized conditions, significant losses of C3-C5 compounds still occurred under highly humid conditions. It was determined that these losses were due to reduced retention during sampling rather than loss during the dry purge procedure. The dry purge method was shown to be adequate at high humidities for sampling NMVOCs with retention indices greater than 500. 相似文献
7.
Microchip electrophoresis (MCE) is a promising new technique for the separation of enantiomers. This recently introduced technique enables chiral separations to be performed in seconds on tiny micromachined devices. This review is intended to give a brief introduction into the principles of chiral separations with MCE with regard to methodology and instrumentation. Different approaches to realize chiral separations in microfluidic devices are described and discussed. This review gives an overview of original work done in this field with emphasis on approaches to improve detection and resolution in chiral MCE. 相似文献
8.
Detlev W. Hoffmann 《Transactions of the American Mathematical Society》1996,348(8):3267-3281
Let and be anisotropic quadratic forms over a field of characteristic not . Their function fields and are said to be equivalent (over ) if and are isotropic. We consider the case where and is divisible by an -fold Pfister form. We determine those forms for which becomes isotropic over if , and provide partial results for . These results imply that if and are equivalent and , then is similar to over . This together with already known results yields that if is of height and degree or , and if , then and are equivalent iff and are isomorphic over .
9.
S. Unterricker Kim Jung Ho W. Stolz D. Degering 《Journal of Radioanalytical and Nuclear Chemistry》1988,122(2):271-278
The underground radiation conditions in the mining district of Freiberg and in a rock salt environment of the Werra district were investigated. In a salt mine a very low natural activity level can be found. For selection of proper shielding materials a low-level -spectrometer and an optimum sample geometry must be used. The photopeak differences between sample and blank are small in most cases. Considerable differences can be found in the continuous background below 0.7 MeV. 相似文献
10.
D. Degering S. Unterricker W. Stolz 《Journal of Radioanalytical and Nuclear Chemistry》1988,127(1):7-11
The excitation function of the89Y/d,2n/89Zr reaction was determined by the stacking foil technique below 13.5 MeV. The measured dependence has a threshold energy of Ethr=6.0 MeV. An estimation by the Keller, Lange and Münzel tables is in good agreement with the experiment. 相似文献