Tuning the solid-state emission of the analogous GFP chromophore by varying alkyl chains in the imidazolinone ring

New analogues of green fluorescent protein (GFP) chromophore mGFP-Cn (n = 1, 3, 5, 11) with alkyl chains of different lengths in the imidazolinone rings were synthesized and their crystal structures were determined. These GFP-like chromophores are all emissive in the solid state. And the solid-state emission quantum yields of increase by extending the lengths of alkyl chains, owing to the fact that the intermolecular pi-pi interactions are significantly weakened based on their crystal structures.     

An improved evaluation of the neutron background in the PandaX-Ⅱ experiment

In dark matter direct detection experiments,neutron is a serious source of background,which can mimic the dark matter-nucleus scattering signals.In this paper,we present an improved evaluation of the neutron background in the PandaX-II dark matter experiment by a novel approach.Instead of fully relying on the Monte Carlo simulation,the overall neutron background is determined from the neutron-induced high energy signals in the data.In addition,the probability of producing a dark-matter-like background per neutron is evaluated with a complete Monte Carlo generator,where the correlated emission of neutron(s)andγ(s)in the(α,n)reactions and spontaneous fissions is taken into consideration.With this method,the neutron backgrounds in the Run 9(26-ton-day)and Run 10(28-ton-day)data sets of PandaX-II are estimated to be(0.66±0.24)and(0.47±0.25)events,respectively.     

Measurements on diproton emission from the break-up channels of ~(23)Al and ~(22)Mg

Two-proton relative momentum distributions from the break-up channels 23Al→p+p+21Na and 22Mg→p+p+20Ne at an energy of 60-70 A MeV have been measured together with two-proton opening angles at the projectile fragment separator beamline (RIPS) in the RIKEN Ring Cyclotron Facility. The results demonstrate the existence of diproton emission component from single-step 2He for highly excited 23Al and 22Mg.     

Focal plane wave-front sensing algorithm for high-contrast imaging

High-contrast imaging provided by a coronagraph is critical for the direction imaging of the Earth-like planet orbiting its bright parent star. A major limitation for such direct imaging is the speckle noise that is induced from the wave-front error of an optical system. We derive an algorithm for the wave-front measurement directly from 3 focal plane images. The 3 images are achieved through a deformable mirror to provide specific phases for the optics system. We introduce an extra amplitude modulation on one deformable mirror configuration to create an uncorrelated wave-front, which is a critical procedure for wave-front sensing. The simulation shows that the reconstructed wave-front is consistent with the original wave-front theoretically, which indicates that such an algorithm is a promising technique for the wave-front measurement for the high-contrast imaging. Supported by the National Natural Science Foundation of China (Grant No. 10873024)     

核破裂中的激发能的作用

在晶格气体模型的框架中研究了¹²⁹Xe系统在破裂过程中的热力学性质和轻粒子发射性质随核温度和系统的冻结密度的变化规律.计算发现在不同的冻结密度下,¹²⁹Xe破裂过程的物理观测量呈现了不同的温度相关性.在这种情况下,核物质液气相变发生时的临界温度强烈地依赖于系统的冻结密度.当激发能代替温度作为一个自变量时,临界激发能将不再灵敏地依赖于系统的冻结密度.除此之外,由于不同冻结密度而引起的不同粒子发射产额的温度相关性,也随着激发能的应用,出现了几乎一致的激发能依赖性.从这些结果中可以认为,激发能可以作为一个控制核破裂的基本物理量和标度量.     

Isospin and symmetry energy study in nuclear EOS

This paper summarizes the isoscaling and isospin related studies in asymmetry nuclear reactions by different dynamic and statistical models. Isospin dependent quantum molecular dynamics model (IQMD) and lattice gas model (LGM) are used to study the isoscaling properties and isoscaling parameters dependence on incident energies, impact parameters, temperature and other parameters. In the LGM model, the signal of phase transition has been found in free neutron (proton) chemical potential difference Δµ_n or Δµ_p as a function of temperature, or in free neutron and proton chemical potential difference Δµ_n−Δµ_p. Density dependence of symmetry energy coefficient C _sym(ρ/ρ ₀) is also studied in the frame of LGM, with the potential parameters which can reproduce the nuclear ground state property, soft density dependence of symmetry energy is deduced from the simulation results. Giant dipole resonance (GDR) induced by isospin asymmetry in entrance channel is also studied via IQMD model, and the dynamic dipole resonance shows isospin sensitivity on the isospin asymmetry of entrance channel and symmetry energy of the nuclear equation of state (EOS). GDR can also be regarded as a possible isospin sensitive signature.

     

Molecular dynamics simulations of the mechanisms of thermal conduction in methane hydrates

The thermal conductivity of methane hydrate is an important physical parameter affecting the processes of methane hydrate exploration,mining,gas hydrate storage and transportation as well as other applications.Equilibrium molecular dynamics simulations and the Green-Kubo method have been employed for systems from fully occupied to vacant occupied sI methane hydrate in order to estimate their thermal conductivity.The estimations were carried out at temperatures from 203.15 to 263.15 K and at pressures from 3 to 100 MPa.Potential models selected for water were TIP4P,TIP4P-Ew,TIP4P/2005,TIP4P-FQ and TIP4P/Ice.The effects of varying the ratio of the host and guest molecules and the external thermobaric conditions on the thermal conductivity of methane hydrate were studied.The results indicated that the thermal conductivity of methane hydrate is essentially determined by the cage framework which constitutes the hydrate lattice and the cage framework has only slightly higher thermal conductivity in the presence of the guest molecules.Inclusion of more guest molecules in the cage improves the thermal conductivity of methane hydrate.It is also revealed that the thermal conductivity of the sI hydrate shows a similar variation with temperature.Pressure also has an effect on the thermal conductivity,particularly at higher pressures.As the pressure increases,slightly higher thermal conductivities result.Changes in density have little impact on the thermal conductivity of methane hydrate.     

Electrochemical sensing of ATP with synthetic cyclophane as recognition element

A new electrochemical sensor for ATP with synthetic cyclophane stably attached onto single-walled carbon nanotubes (SWNTs) as the recognition elements is described. UV-vis and cyclic voltammetric results demonstrate that ATP may interact with the synthetic cyclophane recognition elements to form a stable adduct mainly through electrostatic, π-π stacking and donor-acceptor interactions. Such interactions eventually lead to a decrease in the peak currents of the cyclophane recognition elements attached onto t...     

Kinetic studies of gas hydrate formation with low-dosage hydrate inhibitors

Pipeline blockage by gas hydrates is a serious problem in the petroleum industry. Low-dosage inhibitors have been developed for its cost-effective and environmentally acceptable characteristics. In a 1.072-L reactor with methane, ethane and propane gas mixture under the pressure of about 8.5 MPa at 4 °C, hydrate formation was investigated with low-dosage hydrate inhibitors PVP and GHI1, the change of the compressibility factor and gas composition in the gas phase was analyzed, the gas contents in hydrates were compared with PVP and GHI1 added, and the inhibition mechanism of GHI1 was discussed. The results show that PVP and GHI1 could effectively inhibit the growth of gas hydrates but not nucleation. Under the experimental condition with PVP added, methane and ethane occupied the small cavities of the hydrate crystal unit and the ability of ethane entering into hydrate cavities was weaker than that of methane. GHI1 could effectively inhibit molecules which could more readily form hydrates. The ether and hydroxy group of diethylene glycol monobutyl ether have the responsibility for stronger inhibition ability of GHI1 than PVP.