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排序方式: 共有186条查询结果,搜索用时 15 毫秒
1.
Helmut Endres 《无机化学与普通化学杂志》1984,513(6):78-88
Formation of Octahedral Complexes via cis-Addition to Square Planar Bis (oxamideoximato)nickel(II): Three Structure Examples In the reaction of orange square planar bis(oxamide oximato)nickel(II) with acids, blue to blue-green octahedral complexes are formed with neutral oxamide oximide ligands and two acid anions in cis-positions. Three compounds are described: cis-dichlorobis(oxamide oxime)nickel(II) ( 1 ), NiCl2(C2H6N4O2)2, Mr = 365.81, monoclinic P21/n, a = 6.641(2), b = 14.086(4), c = 13.473(3) Å, β = 96.26(2)°, V = 1 252.8 Å3, Z = 4, dc = 1.94 gcm?3, final Rw = 0.031 for 4090 reflections. In cis-di(sulfanilato)bis(oxamide oxime)nickel(II) dihydrate ( 2 ) one sulfanilic anion coordinates via the sulfonic acid group, the other one via the amino group; Ni(C6H6NO3S)2(C2H6N4O2)2 · 2 H2O, Mr = 675.30, monoclinic P21, a = 6.879(3), b = 14.305(5), c = 13.930(5) Å, β = 103.62(4)°, V = 1332 Å, Z = 2, dc = 1.68 gcm?3, R = 0.067 for 2693 reflections. In catena-μ-(phthalato)bis(oxamide oxime)nickel(II) tetrahydrate ( 3 ) bidentate bridging phthalate anions lead to chain formation; Ni(C8H4O4)(C2H6N4O2)2 · 4H2O, Mr = 531.09, monoclinic P21/c, a = 10.633(8), b = 11.324(5), c = 17.680(14) Å, β = 98.25(7)°, V = 2107 Å3, Z = 4, dc = 1.67 gcm?3. Final R = 0.110 for 3290 reflections. 相似文献
2.
R. Endres 《Monatshefte für Mathematik》1982,94(4):281-297
Let Γθ be the subgroup of Siegel modular groupSp(n, ?) consisting of all matrices \(M = \left( {\begin{array}{*{20}c} {A B} \\ {C D} \\ \end{array} } \right)\) , such that the diagonal elements ofA t C andB t D are even. A multiplier system of weightr(∈?) is a system of complex numbers ν (M)≠0,M∈Γθ, such thatJ (M, Z)=ν(M) det(CZ+D) r is an automorphy factor (that isJ (M N, Z)=J (M, N Z) J (N, Z) forM, N ∈Sp(n,?) and $$Z \in S_n = \left\{ {Z = X + i Y \in M^{(n,n)} (\mathbb{C}); X = X^t , Y = Y^t > 0} \right\})$$ . We show that in casen≥2 such a multiplier system exists if and only if 2r∈?. A corollary of this fact is the following. From the cohomology theory of Siegel modular group we derive that in casen≥8 any Γθ-invariant divisor is the exact zero divisor of a modular form for Γθ. Therefore the zero divisor of classical theta function \(\theta (Z) = \sum\limits_{g \in \mathbb{Z}^n } {e^{\pi iZ[g]} } \) , a modular form of weight 1/2 is irreducible. In the second part of this paper we calculate the commutator factor group of Γ n, θ forn≥2. 相似文献
3.
4.
A.S. Ismail S. Zein El Abedin O. Höfft F. Endres 《Electrochemistry communications》2010,12(7):909-911
In this letter we report on the decomposition of the bis (trifluoromethylsulfonyl) amide (TFSA) anion under quite mild electrochemical conditions. The results show clearly that the TFSA anion can easily be decomposed during anodic oxidation of copper in the ionic liquid 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) amide [BMP] TFSA at 70 °C leading to the formation of CuF2. At room temperature, however, no significant decomposition was obtained. Therefore, one has to be very careful in applying ionic liquids based on TFSA anions under anodic conditions at elevated temperature as the TFSA anion might decompose, depending on the anode material. 相似文献
5.
Brunecker P Villringer A Schultze J Nolte CH Jungehülsing GJ Endres M Steinbrink J 《Magnetic resonance imaging》2007,25(9):1300-1311
To prevent systematic errors in quantitative brain perfusion studies using dynamic susceptibility contrast-enhanced magnetic resonance imaging (DSC-MRI), a reliable determination of the arterial input function (AIF) is essential. We propose a novel algorithm for correcting distortions of the AIF caused by saturation of the peak amplitude and discuss its relevance for longitudinal studies. The algorithm is based on the assumption that the AIF can be separated into a reliable part at low contrast agent concentrations and an unreliable part at high concentrations. This unreliable part is reconstructed, applying a theoretical framework based on a transport-diffusion theory and using the bolus-shape in the tissue. A validation of the correction scheme is tested by a Monte Carlo simulation. The input of the simulation was a wide range of perfusion, and the main aim was to compare this input to the determined perfusion parameters. Another input of the simulation was an AIF template derived from in vivo measurements. The distortions of this template was modeled via a Rician distribution for image intensities. As for a real DSC-MRI experiment, the simulation returned the AIF and the tracer concentration-dependent signal in the tissue. The novel correction scheme was tested by deriving perfusion parameters from the simulated data for the corrected and the uncorrected case. For this analysis, a common truncated singular value decomposition approach was applied. We find that the saturation effect caused by Rician-distributed noise leads to an overestimation of regional cerebral blood flow and regional cerebral blood volume, as compared to the input parameter. The aberration can be amplified by a decreasing signal-to-noise ratio (SNR) or an increasing tracer concentration. We also find that the overestimation can be successfully eliminated by the proposed saturation-correction scheme. In summary, the correction scheme will allow DSC-MRI to be expanded towards higher tracer concentrations and lower SNR and will help to increase the measurement to measurement reproducibility for longitudinal studies. 相似文献
6.
Dr. Florian Rauch Peter Endres Dr. Alexandra Friedrich Dr. Daniel Sieh Dr. Martin Hähnel Dr. Ivo Krummenacher Prof. Dr. Holger Braunschweig Prof. Dr. Maik Finze Prof. Dr. Lei Ji Prof. Dr. Todd B. Marder 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(57):12951-12963
Using a new divergent approach, conjugated triarylborane dendrimers were synthesized up to the 2nd generation. The synthetic strategy consists of three steps: 1) functionalization, via iridium catalyzed C−H borylation; 2) activation, via fluorination of the generated boronate ester with K[HF2] or [N(nBu4)][HF2]; and 3) expansion, via reaction of the trifluoroborate salts with aryl Grignard reagents. The concept was also shown to be viable for a convergent approach. All but one of the conjugated borane dendrimers exhibit multiple, distinct and reversible reduction potentials, making them potentially interesting materials for applications in molecular accumulators. Based on their photophysical properties, the 1st generation dendrimers exhibit good conjugation over the whole system. However, the conjugation does not increase further upon expansion to the 2nd generation, but the molar extinction coefficients increase linearly with the number of triarylborane subunits, suggesting a potential application as photonic antennas. 相似文献
7.
Antibody drug conjugates are cytotoxic pharmaceuticals, designed to destroy malignant cells. A cytotoxic molecule is attached to an antibody that binds specific to a cancer‐cell surface. Given the high toxicity of the drugs, strict safety standards have to be kept. For this reason, an antibody drug conjugates model was developed with fluorescein 5‐isothiocyanate as the nontoxic payload surrogate. Due to the similar hydrophobicity, this model is used to establish a suitable purification process and characterization method for antibody drug conjugates. Because of the pH dependent solubility of fluorescein, the hydrophobicity of conjugates can be modulated by the pH value. Based on the complex heterogeneity and hydrophobicity of the conjugates a chromatographic purification is challenging. Hydrophobic interaction chromatography is used for analytical as well as for preparative separation. Because of the increased hydrophobicity of the conjugates compared to native antibody, hydrophobic interaction chromatography often suffer from resolution and recovery problems. Conjugates were separated differing on the number of payloads attached to the antibody. For this matter, the drug–antibody ratio is determined and used as a quantitative term. The conjugates are purified at high recoveries and resolution by step gradients using suitable resins, allowing the separation of the target drug–antibody ratio. 相似文献
8.
We construct stationary solutions to the barotropic, compressible Euler and Navier-Stokes equations in several space dimensions with spherical or cylindrical symmetry. For given Dirichlet data on a sphere or a cylinder we first construct smooth and radially symmetric solutions to the Euler equations in the exterior domain. On the other hand, stationary smooth solutions in the interior domain necessarily become sonic and cannot be continued beyond a critical inner radius. We then use these solutions to construct entropy-satisfying shocks for the Euler equations in the region between two concentric spheres or cylinders. Next we construct smooth Navier-Stokes solutions converging to the previously constructed Euler shocks in the small viscosity limit. In the process we introduce a new technique for constructing smooth solutions, which exhibit a fast transition in the interior, to a class of two-point boundary problems. 相似文献
9.
Yu S Pearson JC Drouin BJ Sung K Pirali O Vervloet M Martin-Drumel MA Endres CP Shiraishi T Kobayashi K Matsushima F 《The Journal of chemical physics》2010,133(17):174317
Complete and reliable knowledge of the ammonia spectrum is needed to enable the analysis and interpretation of astrophysical and planetary observations. Ammonia has been observed in the interstellar medium up to J=18 and more highly excited transitions are expected to appear in hot exoplanets and brown dwarfs. As a result, there is considerable interest in observing and assigning the high J (rovibrational) spectrum. In this work, numerous spectroscopic techniques were employed to study its high J transitions in the ground and ν(2)=1 states. Measurements were carried out using a frequency multiplied submillimeter spectrometer at Jet Propulsion Laboratory (JPL), a tunable far-infrared spectrometer at University of Toyama, and a high-resolution Bruker IFS 125 Fourier transform spectrometer (FTS) at Synchrotron SOLEIL. Highly excited ammonia was created with a radiofrequency discharge and a dc discharge, which allowed assignments of transitions with J up to 35. One hundred and seventy seven ground state and ν(2)=1 inversion transitions were observed with microwave accuracy in the 0.3-4.7 THz region. Of these, 125 were observed for the first time, including 26 ΔK=3 transitions. Over 2000 far-infrared transitions were assigned to the ground state and ν(2)=1 inversion bands as well as the ν(2) fundamental band. Of these, 1912 were assigned using the FTS data for the first time, including 222 ΔK=3 transitions. The accuracy of these measurements has been estimated to be 0.0003-0.0006?cm(-1). A reduced root mean square error of 0.9 was obtained for a global fit of the ground and ν(2)=1 states, which includes the lines assigned in this work and all previously available microwave, terahertz, far-infrared, and mid-infrared data. The new measurements and predictions reported here will support the analyses of astronomical observations by high-resolution spectroscopy telescopes such as Herschel, SOFIA, and ALMA. The comprehensive experimental rovibrational energy levels reported here will permit further refinement of the potential energy surface to improve ammonia ab initio calculations and facilitate assignment of new high-resolution spectra of hot ammonia. 相似文献
10.
W. Hanke O. Schmitt H. Endres R. Kleiner P. Müller 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,5(3):465-471
A quantitative analysis of a microscopic model for the intrinsic Josephson effect in high-temperature superconductors based
on interlayer tunneling is presented both within a mean-field BCS evaluation and a numerically essentially exact Quantum Monte-Carlo
study. The pairing correlations in the CuO2-planes are modelled by a 2D Hubbard model with attractive interaction, a model which accounts well for some of the observed
features such as the short planar coherence length. The stack of Hubbard planes is arranged on a torus, which is threaded
by a magnetic flux. The current perpendicular to the planes is calculated as a function of applied flux (i.e. the phase), and - after careful elimination of finite-size effects due to single-particle tunneling - found to display a
sinusoidal field dependence in accordance with interlayer Josephson tunneling. Studies of the temperature dependence of the
supercurrent reveal at best a mild elevation of the Josephson transition temperature compared to the planar Kosterlitz-Thouless
temperature. These and other results on the dependence of the model parameters are compared with a standard BCS evaluation.
Received: 24 February 1998 / Revised: 28 April 1998 / Accepted: 23 June 1998 相似文献