排序方式: 共有35条查询结果,搜索用时 15 毫秒
1.
2.
D. A. Andersson G. Baldinozzi L. Desgranges D. R. Conradson S. D. Conradson 《ChemInform》2013,44(22):no-no
DFT calculations of UO2 oxidation indicate stable compounds U4O8.889, U3O7, and U3O7.333, which are based on ordering of split quad‐interstitial clusters. 相似文献
3.
In many generic combustion models, one finds that a combustionwave will develop with a specific wave speed. However, thereare possible initial temperature profiles which do not evolveinto such waves, but rather die out to the ambient temperature.There can exist, in some models, a clear distinction betweenthose initial conditions that do evolve into combustion wavesand those that do not; this is sometimes referred to as thewatershed initial condition. When fuel consumption is consideredto be negligible, analytical methods can be used to obtain theexact watershed. In this paper, we consider the problem of determiningpseudo-watersheds and ascertaining the relationship betweenthese pseudo-watersheds and the exact watersheds. In the processa novel weight-function approach for infinite spatial domainsis developed. 相似文献
4.
5.
6.
7.
Garcia-Adeva AJ Howell RC Conradson SD Mustre de Leon JF Espinosa-Faller FJ 《The journal of physical chemistry. B》2005,109(20):10419-10428
Local electronic and magnetic structure calculations for NiMn exchange bias alloys are reported for clusters containing NiMn in both the chemically disordered face-centered cubic and the chemically and magnetically ordered L1(0) phases. The results of these calculations are consistent with our local structure measurements that point toward the existence of nanometer-scale ordered clusters at the beginning stages of chemical ordering. The spatial dependence of both the local density of states and the magnetization is strongly influenced by the existence of magnetic order on short length scales, giving rise to an inhomogeneous profile for these quantities across the material with the greatest change at the interface that is still small enough within the domain to imply that the magnetization is still highly developed. 相似文献
8.
Conradson SD Begg BD Clark DL Den Auwer C Espinosa-Faller FJ Gordon PL Hess NJ Hess R Keogh DW Morales LA Neu MP Runde W Tait CD Veirs DK Villella PM 《Inorganic chemistry》2003,42(12):3715-3717
Pu L(3) XAFS measurements show that the excess oxygen in single phase PuO(2+)(x)() occurs as oxo groups with Pu-O distances of 1.83-1.91 A. This distance and the energy of the edge (via comparison with a large number of related compounds) are more consistent with a Pu(IV/V) than a Pu(IV/VI) mixture. Analogous to Pu(IV) colloids, although the Pu-Pu pair distribution remains single site even when it shows substantial disorder, the Pu-O distribution can display a number of additional shells at specific distances up to 3.4 A even in high fired materials when no oxo groups are present, implying intrinsic H(+)/OH(-)(/H(2)O). The number of oxo atoms increases when samples are equilibrated with humid air at ambient temperature, indicating that the Pu reactivity in this solid system differs notably from that of isolated complexes and demonstrating the importance of nanoscale cooperative phenomena and total free energy in determining its chemical properties. 相似文献
9.
Conradson SD Abney KD Begg BD Brady ED Clark DL den Auwer C Ding M Dorhout PK Espinosa-Faller FJ Gordon PL Haire RG Hess NJ Hess RF Keogh DW Lander GH Lupinetti AJ Morales LA Neu MP Palmer PD Paviet-Hartmann P Reilly SD Runde WH Tait CD Veirs DK Wastin F 《Inorganic chemistry》2004,43(1):116-131
Pu L(3) X-ray near edge absorption spectra for Pu(0-VII) are reported for more than 60 chalcogenides, chlorides, hydrates, hydroxides, nitrates, carbonates, oxy-hydroxides, and other compounds both as solids and in solution, and substituted in zirconolite, perovskite, and borosilicate glass. This large database extends the known correlations between the energy and shape of these spectra from the usual association of the XANES with valence and site symmetry to higher order chemical effects. Because of the large number of compounds of these different types, a number of novel and unexpected behaviors are observed, such as effects resulting from the medium and disorder that can be as large as those from valence. 相似文献
10.
Conradson SD Manara D Wastin F Clark DL Lander GH Morales LA Rebizant J Rondinella VV 《Inorganic chemistry》2004,43(22):6922-6935
Analysis of X-ray absorption fine structure spectra of UO(2+x) for x = 0-0.20 (UO(2)--U(4)O(9)) reveals that the adventitious O atoms are incorporated as oxo groups with U--O distances of 1.74 A, most likely associated with U(VI), that occur in clusters so that the UO(2) fraction of the material largely remains intact. In addition to the formation of some additional longer U--O bonds, the U sublattice consists of an ordered portion that displays the original U--U distance and a spectroscopically silent, glassy part. This is very different from previous models derived from neutron diffraction that maintained long U--O distances and high U--O coordination numbers. UO(2+x) also differs from PuO(2+x) in its substantially shorter An-oxo distances and no sign of stable coordination with H(2)O and its hydrolysis products. 相似文献