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We consider the problem of minimum risk point estimation for the parameter =a+b of the exponential distribution with unknown location parameter and scale parameter when the loss function is squared error plus linear cost. In this paper, we propose a sequential estimator of and show that the associated risk is asymptotically one cost less than that given by Ghosh and Mukhopadhyay (1989,South African Statist. J.,23, 251–268). 相似文献
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Dual Catalysis with Copper and Rhenium for Trifluoromethylation of Propargylic Alcohols: Efficient Synthesis of α‐Trifluoromethylated Enones 下载免费PDF全文
Dr. Hiromichi Egami Takafumi Ide Masashi Fujita Toshifumi Tojo Prof.Dr. Yoshitaka Hamashima Prof.Dr. Mikiko Sodeoka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(38):12061-12065
Trifluoromethylation of propargylic alcohols to provide (Z)‐α‐trifluoromethylated enones and β‐unsubstituted α‐trifluoromethylated enones proceeded with high yield and selectivity in the presence of CuI/Re2O7. The Z isomer was formed under kinetic control, though it is less stable than the E isomer in terms of steric repulsion. 相似文献
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Dr. Vibe B. Jakobsen Dr. Elzbieta Trzop Dr. Laurence C. Gavin Emiel Dobbelaar Dr. Shalinee Chikara Dr. Xiaxin Ding Dr. Kane Esien Dr. Helge Müller-Bunz Dr. Solveig Felton Dr. Vivien S. Zapf Prof. Eric Collet Prof. Michael A. Carpenter Prof. Grace G. Morgan 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(32):13407-13414
Domain wall motion is detected for the first time during the transition to a ferroelastic and spin state ordered phase of a spin crossover complex. Single-crystal X-ray diffraction and resonant ultrasound spectroscopy (RUS) revealed two distinct symmetry-breaking phase transitions in the mononuclear Mn3+ compound [Mn(3,5-diBr-sal2(323))]BPh4, 1. The first at 250 K, involves the space group change Cc→Pc and is thermodynamically continuous, while the second, Pc→P1 at 85 K, is discontinuous and related to spin crossover and spin state ordering. Stress-induced domain wall mobility was interpreted on the basis of a steep increase in acoustic loss immediately below the the Pc-P1 transition 相似文献
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Chikara Shito Keitaro Okamoto Yuki Sato Ryuji Watanabe Tomonori Ohashi Kazuhiro Fuchizaki 《高压研究》2013,33(3):499-508
ABSTRACTHigh pressure hydrous phases with distorted rutile-type structure have attracted much interest as potential water reservoirs in the Earth’s mantle. An in-situ X-ray diffraction study of β-CrOOH was performed at high pressures of up to 6.2?GPa and high-temperatures of up to 700?K in order to clarify the temperature effect on compression behaviors of β-CrOOH. The P-V-T data fitted to a Birch–Murnaghan equation of state yielded the following results: isothermal bulk modulus KT0?=?191(4)?GPa, temperature derivative (?KT/?T)P?=??0.04(2)?GPa?K?1, and volumetric thermal expansion coefficient α?=?3.3(2)?×?10?5?K?1. In this study, at 300?K, the a-axis became less compressible at pressures above 1–2?GPa. We found that the pressure where the slopes of a/b and a/c ratios turned positive increased with temperature. This is the first experimental study indicating the temperature dependence of the change in the axial compressibility in distorted rutile-type M3+OOH. 相似文献
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Takeshi Yabuta Kanji Tsuru Satoshi Hayakawa Chikara Ohtsuki Akiyoshi Osaka 《Journal of Sol-Gel Science and Technology》2000,19(1-3):745-748
Bioactive organic-inorganic hybrids were synthesized through sol-gel processing starting from -methacryloxypropyltrimethoxysilane. NMR-spectroscopic studies showed the presence of silanol groups (Si–OH) and Si–O–Si bonds. In vitro tests of the hybrids for bioactivity with a simulated body fluid (Kokubo solution) indicated that only calcium-containing hybrids could form apatite on their surfaces. Thus the presence of calcium ions was no less important to deposit apatite than the formation of silanol groups or Si–O–Si bonds. 相似文献
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Weber F Rosenkranz S Castellan JP Osborn R Hott R Heid R Bohnen KP Egami T Said AH Reznik D 《Physical review letters》2011,107(10):107403
We report inelastic x-ray scattering measurements of the temperature dependence of phonon dispersion in the prototypical charge-density-wave (CDW) compound 2H-NbSe2. Surprisingly, acoustic phonons soften to zero frequency and become overdamped over an extended region around the CDW wave vector. This extended phonon collapse is dramatically different from the sharp cusp in the phonon dispersion expected from Fermi surface nesting. Instead, our experiments, combined with ab initio calculations, show that it is the wave vector dependence of the electron-phonon coupling that drives the CDW formation in 2H-NbSe2 and determines its periodicity. This mechanism explains the so far enigmatic behavior of CDW in 2H-NbSe2 and may provide a new approach to other strongly correlated systems where electron-phonon coupling is important. 相似文献