全文获取类型
收费全文 | 113062篇 |
免费 | 6011篇 |
国内免费 | 3994篇 |
专业分类
化学 | 48929篇 |
晶体学 | 1125篇 |
力学 | 8765篇 |
综合类 | 241篇 |
数学 | 35824篇 |
物理学 | 28183篇 |
出版年
2024年 | 111篇 |
2023年 | 759篇 |
2022年 | 1225篇 |
2021年 | 1340篇 |
2020年 | 1443篇 |
2019年 | 1330篇 |
2018年 | 11298篇 |
2017年 | 11065篇 |
2016年 | 7512篇 |
2015年 | 2446篇 |
2014年 | 2283篇 |
2013年 | 2869篇 |
2012年 | 6937篇 |
2011年 | 13423篇 |
2010年 | 7660篇 |
2009年 | 7948篇 |
2008年 | 8666篇 |
2007年 | 10567篇 |
2006年 | 2034篇 |
2005年 | 2805篇 |
2004年 | 2785篇 |
2003年 | 2918篇 |
2002年 | 1880篇 |
2001年 | 974篇 |
2000年 | 973篇 |
1999年 | 978篇 |
1998年 | 880篇 |
1997年 | 777篇 |
1996年 | 898篇 |
1995年 | 715篇 |
1994年 | 624篇 |
1993年 | 562篇 |
1992年 | 501篇 |
1991年 | 426篇 |
1990年 | 373篇 |
1989年 | 294篇 |
1988年 | 274篇 |
1987年 | 255篇 |
1986年 | 198篇 |
1985年 | 202篇 |
1984年 | 177篇 |
1983年 | 152篇 |
1982年 | 121篇 |
1981年 | 97篇 |
1980年 | 95篇 |
1979年 | 77篇 |
1978年 | 60篇 |
1976年 | 43篇 |
1975年 | 47篇 |
1914年 | 45篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Liu Jingze Fei Qingguo Wu Shaoqing Tang Zhenhuan Zhang Dahai 《Nonlinear dynamics》2021,106(3):1869-1890
Nonlinear Dynamics - Rolling bearing and squeeze film damper will introduce structural nonlinearity into the dynamic model of aeroengine. Rubbing will occur due to the clearance reduction design of... 相似文献
2.
Rongrong Li Hongjie Peng Qingping Wu Xuejun Zhou Jiang He Hangjia Shen Minghui Yang Chilin Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(29):12227-12236
Herein, we propose the construction of a sandwich-structured host filled with continuous 2D catalysis–conduction interfaces. This MoN-C-MoN trilayer architecture causes the strong conformal adsorption of S/Li2Sx and its high-efficiency conversion on the two-sided nitride polar surfaces, which are supplied with high-flux electron transfer from the buried carbon interlayer. The 3D self-assembly of these 2D sandwich structures further reinforces the interconnection of conductive and catalytic networks. The maximized exposure of adsorptive/catalytic planes endows the MoN-C@S electrode with excellent cycling stability and high rate performance even under high S loading and low host surface area. The high conductivity of this trilayer texture does not compromise the capacity retention after the S content is increased. Such a job-synergistic mode between catalytic and conductive functions guarantees the homogeneous deposition of S/Li2Sx, and avoids thick and devitalized accumulation (electrode passivation) even after high-rate and long-term cycling. 相似文献
3.
Mesoscopic modeling at the pore scale offers great promise in exploring the underlying structure transport performance of flow through porous media. The present work studies the fluid flow subjected to capillarity-induced resonance in porous media characterized by different porous structure and wettability. The effects of porosity and wettability on the displacement behavior of the fluid flow through porous media are discussed. The results are presented in the form of temporal evolution of percentage saturation and displacement of the fluid front through porous media. The present study reveals that the vibration in the form of acoustic excitation could be significant in the mobilization of fluid through the porous media. The dependence of displacement of the fluid on physicochemical parameters like wettability of the surface, frequency along with the porosity is analyzed. It was observed that the mean displacement of the fluid is more in the case of invading fluid with wetting phase where the driving force strength is not so dominant. 相似文献
4.
Jie Lu Ju-Kang Wu Yao Jiang Dr. Peng Tan Lin Zhang Yu Lei Prof. Xiao-Qin Liu Prof. Lin-Bing Sun 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6490-6496
Hierarchically porous metal–organic frameworks (HP-MOFs) are promising in various applications. Most reported HP-MOFs are prepared based on the generation of mesopores in microporous frameworks, and the formed mesopores are connected by microporous channels, limiting the accessibility of mesopores for bulky molecules. A hierarchical structure is formed by constructing microporous MOFs in uninterrupted mesoporous tunnels. Using the confined space in as-prepared mesoporous silica, highly dispersed metal precursors for MOFs are coated on the internal surface of mesoporous tunnels. Ligand vapor-induced crystallization is employed to enable quantitative formation of MOFs in situ, in which sublimated ligands diffuse into mesoporous tunnels and react with metal precursors. The obtained hierarchically porous composites exhibit record-high adsorption capacity for the bulky molecule trypsin. The thermal and storage stability of trypsin is improved upon immobilization on the composites. 相似文献
5.
Su X. F. Zhang Y. L. Maximov A. L. Zhang K. Xin Q. Feng C. Q. Bai X. F. Wu W. 《Russian Journal of Applied Chemistry》2020,93(1):127-136
Russian Journal of Applied Chemistry - Nanoscale ZSM-5 (AlZ5-D) and Ga-substituted ZSM-5 zeolites ((Al,Ga)Z5-D and GaZ5-D) were synthesized by a green dry-gel conversion strategy. For comparison,... 相似文献
6.
Lijuan Shen Li Li Sheng Lu Xiaohan Zhang Jie Liu Junlin An Guojun Zhang Bo Wu Fei Wang 《中国颗粒学报》2015,(3):10-15
We conducted measurements of black carbon(BC) aerosol in Jiaxing,China during autumn from September 26 to November 30,2013.We investigated temporal and diurnal variations of BC,and its correlations with meteorological parameters and other major pollutants.Results showed that hourly mass concentrations of BC ranged from 0.2 to 22.0 μg/m3,with an average of 5.1 μg/m3.The diurnai variation of BC exhibited a bimodal distribution,with peaks at 07:00 and 18:00.The morning peak was larger than the evening peak.The mass percentages of BC in PM2.5 and PM10 were 7.1%and 4.8%,respectively.The absorption coefficient of BC was calculated to be 44.4 Mm-1,which accounted for 11.1%of the total aerosol extinction.BC was mainly emitted from local sources in southwestern Jiaxing where BC concentrations were generally greater than 11 μg/m3 during the measurement period.Correlation analysis indicated that the main sources of BC were motor vehicle exhaust,and domestic and industrial combustion. 相似文献
7.
8.
The Effect of the Spacer of Bis(biurea) Ligands on the Structure of A2L3‐type (A=anion) Phosphate Complexes
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Prof. Biao Wu Dr. Shaoguang Li Prof. Yibo Lei Prof. Huaiming Hu Dr. Nader de Sousa Amadeu Prof. Dr. Christoph Janiak Dr. Jennifer S. Mathieson Dr. De‐Liang Long Prof. Leroy Cronin Prof. Xiao‐Juan Yang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(6):2588-2593
By tuning the length and rigidity of the spacer of bis(biurea) ligands L, three structural motifs of the A2L3 complexes (A represents anion, here orthophosphate PO43?), namely helicate, mesocate, and mono‐bridged motif, have been assembled by coordination of the ligand to phosphate anion. Crystal structure analysis indicated that in the three complexes, each of the phosphate ions is coordinated by twelve hydrogen bonds from six surrounding urea groups. The anion coordination properties in solution have also been studied. The results further demonstrate the coordination behavior of phosphate ion, which shows strong tendency for coordination saturation and geometrical preference, thus allowing for the assembly of novel anion coordination‐based structures as in transition‐metal complexes. 相似文献
9.
10.