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Capillary electrophoresis with amperometric detection of curcumin in Chinese herbal medicine pretreated by solid-phase extraction 总被引:1,自引:0,他引:1
In the present study, curcumin from Chinese herbal medicine turmeric was determined by capillary electrophoresis with amperometric detection (CE-AD) pretreated by a self-designed, simple, inexpensive solid-phase extraction (SPE) cartridge based on the material of tributyl phosphate resin. An average concentration factor of 9 with the recovery of > 80% was achieved when applied to the analysis of curcumin in extracts of tumeric. Under the optimized CE-AD conditions: a running buffer composed of 15 mM phosphate buffer at a pH 9.7, separation voltage at 16 kV, injection for 6 s at 9 kV and detection at 1.20 V, CE-AD with SPE exhibited low detection limit as 3 x 10(-8) mol/l (S/N = 3), high efficiency of 1.0 x 10(5) N, linear range of 7 x 10(-4) -3 x 10(-6) mol/l (r = 0.9986) for curcumin extracted from light petroleum. The method developed resulted in enhancement of the detection sensitivity and reduction of interference from sample matrix in complicated samples and exhibited the potential application for routine analysis, especially in food, because a relatively complete process of sample treatment and analysis was described. 相似文献
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概述宁波大学地基处理中心自成立以来紧密结合宁波市工程建设中的需要,在地基处理、桩基工程质量检测等方面开展的科研开发工作,和取得的成果,这些成果在工程中的应用已取得了良好的经济和社会效益。 相似文献
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Herein, we have demonstrated that the electrospun nanofibers of TiO(2)/CdS heteroarchitectures could be fabricated through combining electrospinning technique with hydrothermal process. The configuration, crystal structure, and element composition of the as-prepared TiO(2)/CdS heteroarchitectures were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray diffraction (XRD), resonant Raman spectrometer, X-ray photoelectron spectroscopy (XPS). The results indicated that the high-density hexagonal wurtzite CdS crystalline particles of ca. 6-40 nm in diameter were uniformly and closely grown on anatase TiO(2) nanofibers. Especially, the light-absorption properties as well as photocatalytic characteristics of pure TiO(2) nanofibers and TiO(2)/CdS heteroarchitectures with different amount loading of CdS were also investigated. The absorption of TiO(2)/CdS heteroarchitectures was extended to the visible due to effective immobilization of sensitizing agent CdS on TiO(2). In contrast with the pure TiO(2) nanofibers, the TiO(2)/CdS heteroarchitectures showed excellent photocatalytic activity by using rhodamine B dye as a model organic substrate under visible-light irradiation. It was worth noting that the cooperative photocatalytic mechanism of the TiO(2)/CdS heteroarchitectures was also discussed. 相似文献
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1.引言 对线性算子的有限秩算子逼近是最经典的问题.并且它的应用极广.如数值积分公式、函数的逼近、数值原函数、方程的数值解法等.1986年,在文[1]中,首次给出了在再生核空间中函数的最佳逼近算子(恒等算子的有限秩算子逼近).之后;在文[2]中给出了数值原函数.又在文[3]、[5]、[6]等中利用有限秩算子逼近(并非是最佳逼近)给出了一些方程的数值解法.但这些讨论都是在一元函数空间上只对特殊算子进行的.1997年,虽然在文[4]中给出了完备的二元再生核空间及二元函数的最佳逼近插值算子.但是对多元… 相似文献
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本文采用相对灵敏度因子,研究了99.999%-99.9999%的Ho2O3和Lu2O3中40余种杂质元素的火花源定量分析方法,讨论了谱线干扰。做了加入回收及生理性实验,大多数元素的相对标准偏差在30%以内,检测下限为0.00xμg/g。 相似文献
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Growth and optical properties of faceted hexagonal ZnO nanotubes 总被引:5,自引:0,他引:5
Tong Y Liu Y Shao C Liu Y Xu C Zhang J Lu Y Shen D Fan X 《The journal of physical chemistry. B》2006,110(30):14714-14718
Well-faceted hexagonal ZnO nanotubes were synthesized by a simple hydrothermal method and the subsequent aging process without any catalysts or templates. The formation of the tubular structure is closely linked to the polarity of ZnO and the selective adsorption behavior of Zn2+ amino complexes. The surface-related optical properties were studied with use of Raman and photoluminescence spectra. It was found that the oxygen vacancy-related visible emission intensity decreased while surface defect-related visible emission intensity increased when the nanotubes were annealed in oxygen ambient. The anomalous enhancement of PL integrated intensity with the temperature shows fairly high surface state density existing in ZnO nanotubes. 相似文献
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静电纺丝法制备聚丙烯腈/聚苯胺复合纳米纤维及其表征 总被引:1,自引:0,他引:1
利用静电纺丝技术,以聚丙烯腈(PAN)和苯胺(ANI)为前驱物,用过硫酸胺(APS)溶液在低温下缓慢氧化聚合,制备了PAN/PANI复合纳米纤维,直径约500 nm.通过扫描电子显微镜(SEM)、红外光谱(FTIR)、X射线衍射(XRD)和激光拉曼(RAMAN)光谱仪等测试手段对材料的形貌和结构进行了表征.探讨了材料制备过程中影响纤维形貌、尺寸、均匀度的因素和PANI含量对复合纤维导电性能的影响,结果表明,PAN浓度、ANI的加入量和电压是影响纤维特性的主要因素;PANI在PAN基体中呈纳米尺寸分布,复合纳米纤维具有良好的导电性能,导电率可达10-2S/cm. 相似文献
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Through sol-gel processing and electrospinning technique, extrathin fibers of poly(vinyl alcohol) (PVA)/lithium chloride/manganese acetate composite fibers were prepared. After calcination of the above precursor fibers at 600 degrees C, the spinel lithium manganese oxide (LiMn2O4) nanofibers, with a diameter of 100-200 nm, were successfully obtained. The fibers were investigated by TG-DTA, XRD, FT-IR, and SEM, respectively. The results showed that the crystalline phase and morphology of the fibers were largely influenced by the calcination temperature. 相似文献