Infrared thermography of masonry structures

The attention of the present paper was devoted to nondestructive evaluation of masonry structures with a Focal Plane Array infrared camera. Tests were carried out in laboratory on specimens, which simulated one- and two-layer structures, with defects of different geometry and nature and located at different depths. The defects detection was analysed through a cause/effect relationship between the characteristics of defects and hosting material and the observed defect thermal signature, or contrast, on the hosting material.     

To Sandwich Technetium: Highly Functionalized Bis-Arene Complexes [99mTc(η6-arene)2]+ Directly from Water and [99mTcO4]−

The labeling of (bio)molecules with metallic radionuclides such as ^99mTc demands conjugated, multidentate chelators. However, this is not always necessary since phenyl rings can directly serve as integrated, organometallic ligands. Bis-arene sandwich complexes are generally prepared by the Fischer–Hafner reaction. In extension of this, we show that [^99mTc(η⁶-C₆R₆)₂]⁺-type complexes are directly accessible from water and [^99mTcO₄]⁻, even using arenes incompatible with Fischer–Hafner conditions. To unambiguously confirm the nature of these unprecedented ^99mTc complexes, their rhenium homologous have been prepared by substituting naphthalene ligands in [Re(η⁶-C₁₀H₈)₂]⁺ with the corresponding phenyl groups. The ease with which highly stable [^99mTc(η⁶-C₆R₆)₂]⁺ complexes are formed under standard labeling conditions enables a multitude of new potential imaging agents based on commercial pharmaceuticals or lead structures.     

A survey on infrared thermography for convective heat transfer measurements

During the past several years infrared thermography has evolved into a powerful investigative means of thermo-fluid-dynamic analysis to measure convective heat fluxes as well as to investigate the surface flow field behaviour over complicated body shapes. The basic concepts that govern this innovative measurement technique together with some particular aspects linked to its use are herein reviewed. Different operating methods together with their implementations are also discussed. Finally, the capability of infrared thermography to deal with several simple, or complex, fluid flow configurations is analysed.     

Analysis of Composites with Infrared Thermography

The aim of this study was a non-destructive evaluation of composites through their behaviour under thermal stimulation. Such behaviour was monitored by infrared thermography. Several specimens were fabricated involving: glass/epoxy with inclusion of foreign materials; carbon/epoxy with backdrilled holes; carbon/epoxy with impact damage; Glare^® failed in bearing way. The obtained results prove that infrared thermography is capable of detecting the materials inhomogeneities and/or damage listed above. In particular, lock-in thermography is capable of supplying useful information about: the distribution of the adhesive thickness in composite structures; the distribution of the paint thickness; the behaviour under load of aluminium layers and glass fibres in Glare^®.     

On the critical problem of F. D. pressure treatment for laminar flows confined by permeable walls

In the present work the viscous (low Reynolds) flow in plane ducts confined by permeable walls has been studied. A simple model of the filtrating walls has been used, with the normal velocity component proportional to the pressure jump across the wall, resulting in a non-standard boundary value Navier-Stokes problem. A critical analysis of the appropriate boundary condition and pressure problem has led to the conclusions of employing a simple explicit finite volume approach, and of avoiding the use of higher order finite difference schemes. In this paper a special emphasis on the structure of the involved computational matrices has been given to illustrate the chosen algorithm. The latter yields a steady state solution that is second order accurate in space, and it has an accuracy in time of order ≤ Δt (the time step), due to the explicit treatment of the velocity boundary conditions along the membrane. The model has been tested to study the effects of the inlet/outlet conditions, Reynolds number and filtrating wall constant.     

2-Imidazolines. IV . 1-Aryl-2-alkylthio-4,5- diamino-4,5-dihydroimidazoles. Synthesis and properties

1,2-Diimmonium salts ( 1 ) react with S-substituted isothioureas ( 3 ) yielding 2-alkylthio-4,5-diamino-4,5-dihydroimidazoles ( 4 ), which under mild pyrolytic conditions afforded 2-alkylthio-5-aminoimidazoles ( 7 ). Imidazolines ( 4 ) and imidazoles ( 7 ) were easily desulfurated with Raney nickel affording 4,5-diamino-4,5-dihydroimidazole ( 9 ) and 5-aminoimidazole ( 10 ), respectively.     

Azimuthal instability in an impinging jet: adiabatic wall temperature distribution

The present work has been aimed at gaining some new insights into instability phenomena arising when an air jet impinges on a flat plate under certain conditions. At a critical Mach number, depending on the impingement distance, the jet loses its circumferential appearance with the formation of evenly equidistant azimuthal structures, whose number and location depend on the nozzle geometry and on the flow conditions. The instability is investigated in terms of pressure and adiabatic wall temperature; the latter is measured by means of an infrared scanning radiometer. Entrainment effects are found to play a key role in the priming and evolution of the instability.     

Infrared thermography to detect residual ceramic in gas turbine blades

A serious problem in the production of gas turbine blades is the detection of residual ceramic cores inside the cooling passages; in fact, the presence of even small ceramic pieces affects turbine performance and may cause difficulties in successive manufacturing. Therefore, it is important to have a non-destructive technique that must be capable of detecting tiny ceramic fragments in a fast and easy way. In this perspective, the suitability of infrared thermography was investigated within cooperation between the University of Naples and the Europea Microfusioni Aerospaziali S.p.A. (EMA). Several blades of three different types were inspected revealing that in many cases infrared thermography can discover small ceramic fragments which were missed by X-ray inspection. In addition, infrared thermography allows gaining of information about other types of anomalies (e.g., surface defects) during the same testing step (by eventually changing the test parameters) and then saving time and money. The obtained results look promising in view of introducing infrared thermography among industrial instrumentation as an alternative to, or integrated with, the most currently utilized non-destructive techniques.     

Infrared thermography as a tool for thermal surface flow visualization

Infrared (IR) thermography is a two-dimensional, non-contact technique of temperature measurement which can be usefully exploited in a vast variety of heat transfer industrial applications as well as research fields. The present work focuses attention on thermal surface flow visualizations of several types of fluid flow studied by means of the IR imaging system and in particular: the flow over a delta wing at angle of attack; the flow generated by a disk rotating in still air; air jets impinging on a flat wall; the flow inside a 180deg turn in astatic channel with, or without, turbulence promoters; the flow inside a 180deg turn in arotating square channel. Each flow visualization is illustrated through thermographic images and/or Nusselt number maps. The emphasis is on the capability of the infrared system to study: laminar-to-turbulent transition and location of primary and secondary vortices over the delta wing at angle of attack; the spiral vortical structure developing at transition over the disk; azimuthal structures arising for certain jet conditions; the influence of the channel aspect ratio (width to height ratio) on the heat transfer coefficient distribution along the 180deg turn, as well as the influence of ribs, in the case ofstatic channel; the influence of rotation for the rotating channel.     

On the relation between the entropy balance and the numerical solutions of systems of conservation laws

This work deals with the relation between the numerical solutions of hyperbolic systems of conservation laws and the associated entropy evolution. An analysis of the continuum problem by means of variational calculus clearly emphasizes the consequences of the adopted reconstruction procedure on the induced entropy balance. A methodology is proposed that allows for a posterior local and global spurious entropy production estimates on the basis of an additional equation representing a discrete approximation to the entropy inequality. The problem of defining a consistent approximation of the numerical entropy flux is also addressed in detail. Properly designed numerical experiments support the analysis and contribute to providing a more comprehensive evaluation of the numerical entropy dynamics. © 1997 John Wiley & Sons, Ltd.