Effects of Adsorbed Polyaniline on Redox Process on MoO3 Surface

The effects exhibited by adsorbed conducting polyaniline on the redox process on a molybdenum oxide surface were studied. Thermogravimetric results indicate a 4% polyaniline deposition. Cyclic voltammograms of the adsorbed polymer on MoO3 show that polyaniline exerts remarkable effects on the molybdenum blue oxidation-reduction process, with oxidation and reduction potentials of 0.33 and 0.18 V, respectively. This effect strongly enhances the electrode response, and can be used as an important tool in qualitative and/or quantitative determinations of molybdenum in solution as well as in any substrate. Copyright 1999 Academic Press.     

奥尔堡PBL模式对提升有机波谱分析教学效果的启示

概述了有机波谱分析课程教学中存在的主要问题，介绍了奥尔堡PBL模式的主要特点和优势，分析了将奥尔堡PBL模式用于有机波谱分析课程教学的必要性和可行性，并从课时分配、教学内容、教学方式和考核方式等4方面提出了教学改革方案，旨在提高教学效果。     

Observing High‐Pressure Chemistry in Graphene Bubbles

Using IR spectroscopy, high‐pressure reactions of molecules were observed in liquids entrapped by graphene nanobubbles formed at the graphene–diamond interface. Nanobubbles formed on graphene as a result of thermally induced bonding of its edges with diamond are highly impermeable, thus providing a good sealing of solvents within. Owing to the optical transparency of graphene and diamond, high‐pressure chemical reactions within the bubbles can be probed with vibrational spectroscopy. By monitoring the conformational changes of pressure‐sensitive molecules, the pressure within the nanobubble can be calibrated as a function of temperature and it is about 1 GPa at 600 K. The polymerization of buckministerfullerene (C₆₀), which is symmetrically forbidden under ambient conditions, is observed to proceed in well‐defined stages in the pressurized nanobubbles.     

Synthesis of heterocyclic thiosulfonates

[formula: see text] A simple synthesis of heterocyclic thiosulfonates containing indole, indoline, benzoimidazole, and quinoxaline rings is described. The synthesis of these thiosulfonates involves the preparation of the appropriately substituted thiols followed by sulfonylation to give thiosulfonates. The corresponding thiols were prepared in a simple and efficient manner by using a thiocyanation reaction either prior to heterocycle ring formation or after heterocycle ring formation. These thiosulfonates were coupled successfully to the 5,6-dihydropyran-2-one ring to give products that showed excellent HIV protease activity.     

Mechanism of Inhibition of Advanced Glycosylation by Aminoguanidine in Vitro

Abstract

A triazine and a bishydrazone were isolated from a solution of aminoguanidine incubated with an Amadori product (1-deoxy-1-propylamino-D-fructose) under physiological conditions. The new products were characterized by NMR and mass spectrometric analysis. The mechanism of the inhibition was proposed to involve the reactive intermediate 1, 4-dideoxy-1-(propylamino)-D-glycero-2, 3-hexodiulose (i.e., 1-propylamino-1, 4-dideoxyosone). The existence of this intermediate was supported by acetylation and characterization of the product. Formation of a proposed triazine and bis(amidinohydrazone) after the incubation of 1-propylamino-1, 4-dideoxyosone with aminoguanidine also supported the proposed mechanism.     

Magnetic stochasticity in gyrokinetic simulations of plasma microturbulence

Analysis of the magnetic field structure from electromagnetic simulations of tokamak ion temperature gradient turbulence demonstrates that the magnetic field can be stochastic even at very low plasma pressure. The degree of magnetic stochasticity is quantified by evaluating the magnetic diffusion coefficient. We find that the magnetic stochasticity fails to produce a dramatic increase in the electron heat conductivity because the magnetic diffusion coefficient remains small.     

A Continuous-Wave Ho：YA103 Laser with Output 8.5 W Pumped by a 1.91μm Laser at Room Temperature

A cw high efficient Ho：YAI03 laser pumped by 1.91 μm diode-pumped Tm：YLF laser at room temperature is realized. The maximum output power reaches 8.5 W when the incident pump power is 15.6 W. The slope efficiency is 63.7%, and the Tm：YLF to Ho：YAP optical conversion efficiency is 54.5%. The laser wavelength is 2118.3nm when the transmission of output coupler is 30%. The beam quality factor is M2 -1.39 measured by the traveling knife-edge method.     

Free trial or no free trial: Optimal software product design with network effects

A common business strategy to promote product adoption in software industry is to provide a free trial version with limited functionalities of the commercial product to increase the installed user base. The increase of user base will lead to higher value of the software because of positive network effects. However, offering a free trial version may cannibalize some demand of the commercial software. This paper examines the tradeoff between network effects and the cannibalization effect, and aims to uncover the conditions under which firms should introduce the free trial product. We find that when network intensity is strong, it is more profitable for a software monopoly to offer free trial than to segment the market with two versions of different qualities. In addition, this paper solves the joint decision problem of finding the optimal quality for the firm’s free trial software and the optimal price of its commercial product.