2,3-吡啶二羧酸铜(Ⅰ)配合物的合成与结构

铜配合物具有多变的配位结构,可活化小分子,可用于氧转移、氧化加成、新陈代谢、均相催化等许多领域。还可以用作金属酶的化学模拟和配合物结构及反应性能研究方面[1-3]。本文以2,3 二羧酸 吡啶为辅助配体及[(PPh3)2Cu(BH4)]作为起始原料,室温下,通过取代反应合成了单核铜(Ⅰ)配合物[(PPh3)2Cu(C7H4NO4)],经元素分析、电导、光电子能谱、红外光谱及单晶XRD方法对配合物进行了表征。1　实验部分1 1　仪器和试剂意大利ERBA 1106元素分析仪,JA96 970等离子光谱仪,Nicolet170SX分析仪(CsI压片),AV 300Bruker分析仪(CDCl3溶剂,8…     

人参中总皂甙的超声波快速提取方法研究

建立了人参中总皂甙超声波半微量快速提取方法，与索氏提取法相比，此法提取时间由索氏法的1－2个工作日缩短到30min，节省大量试剂，综合提取效率提高数十倍，与索氏提取法对照分析表明，此法可完全满足人参中总皂甙的快速测定要求。     

Snyder’s quantized space-time and de Sitter special relativity

There is a one-to-one correspondence between Snyder’s model in de Sitter space of momenta and the dS-invariant special relativity as well as a minimum uncertainty-like relation. This indicates that physics at the Planck length ? _P and the scale R = (3/Λ)^1/2 should be dual to each other and there is in-between gravity of local dS-invariance characterized by a dimensionless coupling constant g = ? _P /R ～ 10^?61.     

小空位团浅能级对正电子的声子激发比捕获率

若小空位团中存在束缚能小于晶体德拜能量的正电子捕获态, 则这一能态对自由正电子的捕获具有较强的温度依赖性. 这种温度依赖性有两种类型, 且比捕获率的取值也可能相当高, 显示了与位错的很大不同. 关键词：     

On General Volume-Preserving Mechanical Systems via Cohomology

We present the general form of equations that generate a volume-preserving flow on a symplectic manifold(Μ,ω) via the highest Euler-Lagrange cohomology. It is shown that for every volume-preserving fiow there are some 2-forms that play a similar role to the Hamiltonian in the Hamilton mechanics and the ordinary canonical equations with Hamiltonian H are included as a special case with a 2-form Hω/(n - 1).     

Difference Discrete Variational Principle in Discrete Mechanics and Symplectic Algorithm

We propose the difference discrete variational principle in discrete mechanics and symplectic algorithmwith variable step-length of time in finite duration based upon a noncommutative differential calculus established inthis paper. This approach keeps both symplecticity and energy conservation discretely. We show that there exists thediscrete version of the Euler-Lagrange cohomology in these discrete systems. We also discuss the solution existencein finite time-length and its site density in continuous limit, and apply our approach to the pendulum with periodicperturbation. The numerical results are satisfactory.     

华罗庚与爱因斯坦相对论及其扩展——纪念华罗庚诞辰一百周年

华罗庚先生运用矩阵几何与投影几何,研究并简化了爱因斯坦狭义相对论的基本原理,得到惯性运动的对称性,并促进了对德西特不变的狭义相对论的研究.他的深入考察至今仍引领着我们如何面对精确宇宙学的挑战.爱因斯坦相对论作为以宇宙常数Λ>0为特征的宇观物理学的基础面临疑难.相对性原理应该扩充到具有两个不变普适常数c和l,具有24个生成元的惯性运动对称性的相对性原理.于是,存在庞加莱、德西特和反德西特不变的3种相对论,伴随着对偶庞加莱运动学,它们构成相对论三位一体.取……,德西特相对论提供宇观尺度之新运动学,亦可避开相对性的宇宙佯谬.华老不仅是大数学家,而且是大思想家和大教育家,是一位为复兴中华民族而奉献终身的伟大代表.     

Beltrami Gauge Symmetry and 2D Induced Gravity

We introduce the Beltrami gauge symmetry related to the Beltrami parametrization of the metrics and the Beltrami equations. We explore its role in 2d induced gravity and show that Polynkov's. SL(R) and KPZ's residual symmetries are subsymmetries of the Beltrami gnuge symmetry in the light-cone gauge. We also find that the 2d induced gravity with or without matter can be reformulated as Beltrami-Liouville field theories on Riemann surfaces of higher genus.     

Wave Function of Contract-Expanding Universe

It is shown that the wave functions of a contract-reexpanding universe may be constructed in two different ways corresponding to different boundary conditions in superspace and both may offer satisfactory inflationary scenario.     

ASSOCIATIVITY OF REPRESENTATIONS AND COCYCLES OF GAUGE GROUPS

It is shown that the consistency of certain representa-tions of group requires a mod Z-cocycle condition which leads to some topological quantization constants in cor-responding anomalous algebraic relations, such as anomalous commutators and anomalous Jacobi identities. It should be pointed out that the mod Z-cocycles for gauge groups could be constructed by means of the generalized secondary charac-teristic classes.