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The equilibrium and transport properties of interacting ad-particles on bivariate heterogeneous chains are studied by combining analytical and simulation approaches. Heterogeneity is introduced in the way of patches of shallow and deep adsorbing sites distributed in a deterministic alternating way. Adsorption isotherms and mean-square fluctuations of the surface coverage, as well as the jump and collective diffusion coefficients, are calculated for different values of lateral interactions between ad-particles and substrate heterogeneity. In addition, different elementary jump mechanisms are introduced and their influence in the coverage dependence of the collective diffusion coefficient is investigated.  相似文献   
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The monolayer adsorption of interacting binary mixtures on 2D square lattices has been studied through grand canonical Monte Carlo simulation in the framework of the lattice-gas model. The process has been monitored through total and partial isotherms and differential heats of adsorption corresponding to both species of the mixture. Repulsive lateral interactions between the adsorbed particles have been considered, resulting in a rich variety of structural orderings in the adlayer. At the end of this work, the phase diagram characterizing the transitions occurring in the system has been determined. A nontrivial interdependence between the partial surface coverage of both species was observed and discussed.  相似文献   
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LetA be aC*-algebra with second dualA″. Let (φ n)(n=1,...) be a sequence in the dual ofA such that limφ n(a) exists for eacha εA. In general, this does not imply that limφ n(x) exists for eachx εA″. But if limφ n(p) exists whenever p is the range projection of a positive self-adjoint element of the unit ball ofA, then it is shown that limφ n(x) does exist for eachx inA″. This is a non-commutative generalisation of a celebrated theorem of Dieudonné. A new proof of Dieudonné’s theorem, for positive measures, is given here. The proof of the main result makes use of Dieudonné’s original theorem.  相似文献   
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This article presents the realization of many self-reversible quantum logic gates using two-qubit quadrupolar spin 3/2 systems. Such operations are theoretically described using propagation matrices for the RF pulses that include the effect of the quadrupolar evolution during the pulses. Experimental demonstrations are performed using a generalized form of the recently developed method for quantum state tomography in spin 3/2 systems. By doing so, the possibility of controlling relative phases of superimposed pseudo-pure states is demonstrated. In addition, many aspects of the effect of the quadrupolar evolution, occurring during the RF pulses, on the quantum operations performance are discussed. Most of the procedures presented can be easily adapted to describe selective pulses of higher spin systems (>3/2) and for spin 1/2 under J couplings.  相似文献   
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The behaviour of the surface diffusion coefficient on an heterogeneous correlated surface is studied in the framework of the lattice-gas model. Using the multivariate adsorptive energy distribution function the statistical properties of the heterogeneous correlated surface can be appropriately described and the effect of the heterogeneity on the collective diffusion coefficient at finite coverage can be analized through a correlation length. Monte Carlo simulation is also performed to test the analytical results.  相似文献   
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The eigen frequencies of radial pulsations of neutron stars are calculated in a strong magnetic field. At low densities we use the magnetic BPS equation of state (EOS) similar to that obtained by Lai and Shapiro while at high densities the EOS obtained from the relativistic nuclear mean field theory is taken and extended to include strong magnetic field. It is found that magnetized neutron stars support higher maximum mass whereas the effect of magnetic field on radial stability for observed neutron star masses is minimal.  相似文献   
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