全文获取类型
收费全文 | 77篇 |
免费 | 0篇 |
专业分类
化学 | 31篇 |
力学 | 1篇 |
数学 | 1篇 |
物理学 | 44篇 |
出版年
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2016年 | 1篇 |
2014年 | 2篇 |
2013年 | 4篇 |
2012年 | 1篇 |
2011年 | 6篇 |
2010年 | 2篇 |
2008年 | 6篇 |
2007年 | 3篇 |
2006年 | 5篇 |
2005年 | 3篇 |
2004年 | 1篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有77条查询结果,搜索用时 0 毫秒
1.
2.
3.
4.
L. F. Brum Malta Marta Eloisa Medeiros 《Journal of Thermal Analysis and Calorimetry》2005,81(1):149-152
Summary This work reports the room-temperature stabilization of the Bi4V2-xFexIIO11-1.5x γ ‘ phase, a promising ionic conductive material that finds application in solid oxide fuel cell and oxygen sensor devices. The Fe(II) cation proved to be a better stabilizer than Fe(III), which was previously used, since a lower substitution degree of V5+ is needed for the former. Powder X-ray diffraction, Fourier-transform infrared spectroscopy and differential scanning calorimetry were used in these experiments. 相似文献
5.
An experimental study of the thermal decomposition of a β‐hydroxy alkene, 3‐methyl‐3‐buten‐1‐ol, in m‐xylene solution, has been carried out at five different temperatures in the range of 513.15–563.15 K. The temperature dependence of the rate constants for the decomposition of this compound in the corresponding Arrhenius equation is given by ln k (s?1) = (25.65 ± 1.52) ? (17,944 ± 814) (kJ·mol?1)·T?1. A computational study has been carried out at the M05–2X/6–31+G(d,p) level of theory to calculate the rate constants and the activation parameters by the classical transition state theory. There is a good agreement between the experimental and calculated rate constants and activation Gibbs energies. The bonding characteristics of reactant, transition state, and products have been investigated by the natural bond orbital analysis, which provides the natural atomic charges and the Wiberg bond indices. Based on the results obtained, the mechanism proposed is a one‐step process proceeding through a six‐membered cyclic transition state, being a concerted and slightly asynchronous process. The results have been compared with those obtained previously by us (Struct Chem 2013, 24, 1811–1816) for the thermal decomposition of 3‐buten‐1‐ol, in m‐xylene solution. We can conclude that in the compound studied in this work, 3‐methyl‐3‐buten‐1‐ol, the effect of substitution at position 3 by a weakly activating CH3 group is the stabilization of the transition state formed in the reaction and therefore a small increase in the rate of thermal decomposition. 相似文献
6.
Abstract Due to the wide use of polymers in medicine, researchers are required to solve a very important problem–to understand the interaction between materials of nonphysiological origin and the surrounding biological liquids, and tissues, particularly blood. 相似文献
7.
Thermostable heterocyclic polymers containing benzimidazole and imide rings, as well as flexible ester groups, have been synthesized by solution polycondensation of diaminobenzimidazoles with dianhydrides incorporating preformed ester linkages. The thermal stability and the electrical insulating properties of these products are discussed and compared with related heterocyclic polymers. 相似文献
8.
Aires da Conceição Silva Lucia C.S. Aguiar Andréa Luzia F. de Souza Luiz Fernando Brum Malta 《Tetrahedron letters》2010,51(30):3883-6491
In this work, we present ligand-free Suzuki cross-coupling reactions in PEG 300 under thermal conditions at 55 °C with good yields of conversion; better results were obtained with low reaction time. In 1 hour, 1-iodo-4-nitrobenzene and phenylboronic acid reached 98% of the yield and 9700 of TON. Better results were obtained with Pd(0) sources. The reaction system was recycled up to three times with good activity. 相似文献
9.
10.