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Quan Shi Narendiran Vitchuli Joshua Nowak Zhan Lin Bingkun Guo Marian Mccord Mohamed Bourham Xiangwu Zhang 《Journal of Polymer Science.Polymer Physics》2011,49(2):115-122
The electrospinnability of polyethylene oxide (PEO) was manipulated by atmospheric plasma treatment of pre‐electrospinning solutions. Conductivity, viscosity, and surface tension of PEO solutions increased after plasma treatment, and the plasma effect remained longer when the solution concentrate increased. Both untreated and treated solutions were then electrospun, and the morphology of the resultant nanofibers was observed by SEM. Atmospheric plasma treatment improved the electrospinnability of PEO solutions and led to less beads and finer diameter distribution in the resultant nanofibers. Additionally, plasma treatment of the pre‐electrospinning solutions affected the crystal structure of resultant nanofibers. These results suggest that atmospheric plasma treatment is a feasible approach to improve the electrospinnability of polymer solutions and can used to control the structure of electrospun nanofibers. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
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Bourham M.A. Hankins O.E. Auciello O. Stock J.M. Wehring B.W. Mohanti R.B. Gilligan J.G. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1989,17(3):386-391
The experimental and theoretical verification of the vapour shield concept in an electrothermal accelerator is reported. Measurements of the ablation mass loss of the insulator material (Lexan) demonstrate that the energy transmission factor through the vapor shield is of the order of 10%. If enough vapor is produced under high heat flux, the vapor shield mechanism will help limit the surface erosion in electromechanical devices. The erosion of the barrel material (aluminum) has a strong axial dependence, and the erosion depth increases with input energy 相似文献
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Quan Shi Narendiran Vitchuli Joshua Nowak Jane M. Caldwell Frederick Breidt Mohamed Bourham Xiangwu Zhang Marian McCord 《European Polymer Journal》2011,(7):1402-1409
Durable antibacterial Ag/polyacrylonitrile (Ag/PAN) hybrid nanofibers were prepared by atmospheric plasma treatment and electrospinning. Atmospheric helium plasma treatment was first used to reduce the AgNO3 precursor in pre-electrospinning solutions into metallic silver nanoparticles, followed by electrospinning into continuous and smooth nanofibers with Ag nanoparticles embedded in the matrix. SEM, TEM, and EDX spectra were used to study the structure and surface elemental composition of the nanofibers. Silver nanoparticles, with diameters ranging between 3 and 6 nm, were found to be uniformly dispersed in the nanofiber matrix. The Ag/PAN nanofibers exhibited slow and long-lasting silver ion release, which provided robust antibacterial activity against both Gram-positive Bacillus cereus and Gram-negative Escherichia coli microorganisms. 相似文献
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Narendiran Vitchuli Quan Shi Joshua Nowak Rupesh Nawalakhe Michael Sieber Mohamed Bourham Marian McCord Xiangwu Zhang 《Plasma Chemistry and Plasma Processing》2012,32(2):275-291
Electrospun nanofiber mats are inherently weak, and hence they are often deposited on mechanically-strong substrates such
as porous woven fabrics that can provide good structural support without altering the nanofiber characteristics. One major
challenge of this approach is to ensure good adhesion of nanofiber mats onto the substrates and to achieve satisfactory durability
of nanofiber mats against flexion and abrasion during practical use. In this work, Nylon 6 nanofibers were deposited on plasma-pretreated
woven fabric substrates through a new plasma-electrospinning hybrid process with the objective of improving adhesion between
nanofibers and fabric substrates. The as-prepared Nylon 6 nanofiber-deposited woven fabrics were evaluated for adhesion strength
and durability of nanofiber mats by carrying out peel strength and flex resistance tests. The test results showed significant
improvement in the adhesion of nanofiber mats on woven fabric substrates. The nanofiber-deposited woven fabrics also exhibited
good resistance to damage under repetitive flexion. X-Ray photoelectron spectroscopy and water contact angle analyses were
conducted to study the plasma effect on the nanofibers and substrate fabric, and the results suggested that both the plasma
pretreatment and plasma-electrospinning hybrid process introduced radicals, increased oxygen contents, and led to the formation
of active chemical sites on the nanofiber and substrate surfaces. These active sites helped in creating crosslinking bonds
between substrate fabric and electrospun nanofibers, which in turn increased the adhesion properties. The work demonstrates
that the plasma-electrospinning hybrid process of nanofiber mats is a promising method to prepare durable functional materials. 相似文献
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