Synthesis and novel reactivity of halomethyldimethylsulfonium salts

Iodomethyl-, chloromethyl-, and fluoromethyldimethylsulfonium salts, 4b-d, have been synthesized and are observed to be highly reactive molecules that exhibit extraordinary diversity with respect to the nature of their reactivity, undergoing facile direct substitution (S(N)2) reactions, but also being highly susceptible to electron-transfer reactions. Cyclic voltametry experiments indicated that the iodomethyldimethylsulfonium compound, 4b, is a potent electron acceptor, even surpassing the reactivity of perfluoro-n-alkyl iodides in that capacity. The iodo- and chloromethyldimethylsulfonium salts, 4b,c, as well as the analogous iodomethyltrimethylammonium salt, 3a, are shown to be reactive SET acceptors.     

2.5-W, continuous-wave, 629-nm solid-state laser source

We report an efficient, high-power, cw, 629-nm laser source based on a diode-pumped Nd:YAG laser and a periodically poled lithium niobate (PPLN) frequency converter. This device integrates two separate frequency-conversion steps in a single crystal, taking advantage of the ability to fabricate PPLN with nearly arbitrary grating periods and phase-matching temperatures. This device uses a single PPLN crystal that has two grating regions in series. The first region quasi-phase matches a standard optical parametric oscillator process (1064nm?1540nm +3450nm), and the second region quasi-phase matches a sum-frequency process whereby the pump and the signal light make red light (1064nm+1540nm ?629nm). Using a four-mirror ring cavity, we were able to convert 21% of the 1064-nm pump to 629-nm output, yielding 2.5W of red output with 11.8W of input.     

The single-mode rate equations for semiconductor lasers with thermal effects

A mathematical model describing the coupling of electrical,optical and thermal effects in semiconductor lasers is introduced.Numerical and asymptotic solutions are derived, including expressionsfor key physical quantities such as the initial time delay,the frequency of spike oscillation and the temperature rise,together with its influence on the photon density, the electronconcentration and the threshold current. The consequences ofthermal effects in reducing efficiency are thus quantified.     

Continuous-wave frequency tripling and quadrupling by simultaneous three-wave mixings in periodically poled crystals: application to a two-step 1.19-10.71-microm frequency bridge

We observed cw third-harmonic generation in a periodically poled LiNbO(3) crystal by cascading optimally phase-matched second-harmonic and sum-frequency generation. Other processes, such as fourth-harmonic generation, are allowed by the flexibility of quasi-phase matching. We demonstrate a divide-by-nine (1.19- 10.71-microm) frequency chain that uses only two lasers.     

On <Emphasis Type="Italic">g</Emphasis>-functions for Laguerre function expansions of Hermite type

We examine weighted L ^p boundedness of g-functions based on semigroups related to multi-dimensional Laguerre function expansions of Hermite type. A technique of vector-valued Calderón–Zygmund operators is used.