Nuclear Quadrupole Coupling Constants of Chlorine and Microwave Spectrum, Structure, and ab Initio Calculation of 1-Chloro-1,1,2-trifluoroethane

The microwave spectrum of the ³⁵Cl and ³⁷Cl isotopic species of 1-chloro-1,1,2-trifluoroethane (HCFC-133b) has been investigated in the frequency region 10 to 50 GHz using a Stark modulation microwave spectrometer. A pulsed jet Fourier transform microwave spectrometer was also used for the measurement of hyperfine splittings. A least-squares analysis of the observed b-type Q- and R-branch transition frequencies gave rotational and centrifugal distortion constants and components of the chlorine nuclear quadrupole coupling constant tensors in the principal axes system as follows: A=4625.161 (3) MHz, B=2004.127 (2) MHz, C=1875.813 (2) MHz, Δ_J=0.144 (9) kHz, Δ_JK=1.0748 (8) kHz, Δ_K=1.57 (1) kHz, δ_J=0.01376 (4) kHz, δ_K=−0.146 (4) kHz, χ_aa=−57.958 (10) MHz, χ_bb=21.231 (11) MHz, and χ_cc=36.727 (11) MHz for ³⁵ClCF₂CH₂F species, and A=4607.684 (6) MHz, B=1960.565 (2) MHz, C=1834.823 (2) MHz, Δ_J=0.106 (7) kHz, Δ_JK=1.022 (3) kHz, Δ_K=1.48 (1) kHz, δ_J=0.0142 (2) kHz, δ_K=−0.18 (2) kHz, χ_aa=−46.268 (11) MHz, χ_bb=17.319 (13) MHz, and χ_cc=28.950 (13) MHz for ³⁷ClCF₂CH₂F species. The structural parameters are calculated from the observed six rotational constants by assuming the partial structure of ab initio calculation. The electronic properties of the C-Cl bond are evaluated from the observed nuclear quadrupole constants of chlorine. These molecular properties are compared with those of other related molecules.     

第I类非自共轭锥上的Gamma函数

本文将Ｇａｍｍａ函数及Ｓｉｅｇｅｌ积分推广到一般的第Ｉ类非自共轭锥上．作为其应用，显式给出了以这些锥为底的管状域（或第一类Ｓｉｅｇｅｌ域）的Ｃａｕｃｈｙ Ｓｚｅｇ¨ｏ核和形式Ｐｏｉｓｏｎ核．     

弹性体型聚氨酯和聚碳酸酯共混物的形态结构

用ＤＳＣ、ＷＡＸＤ和ＳＡＸＳ研究了溶液共混的弹性体型聚氨酯（ＰＵ）／聚碳酸酯（ＰＣ）共混物的结构。结果表明，ＰＵ／ＰＣ为部分相容体系；共混过程中，溶剂ＤＭＦ的诱导作用使ＰＣ形成结晶，其长周期与ＰＵ硬段形成微相的长周期相近     

Ar原子电离能谱和Ar3p电子动量谱研究

电子动量谱学（ElectronMomentumSPectroscoP则是近．二十年来发展起来的一种新兴的探测原子、分子和固体结构的手段，它不仅能够获得轨道结合能的信息，而且能够能壳分辨地得到轨道电子的动量分布（即动量表象中的波函数模方）；同时它还是研究电子关联的最有效的实验手段．其     

Pt-V2O5/HM催化剂积炭机理的TPO研究

Ｐｔ┐Ｖ２Ｏ５／ＨＭ催化剂积炭机理的ＴＰＯ研究蔡炳新（湖南大学化学化工系，长沙４１００１２）周烈华郑小明（杭州大学催化研究所，杭州３１００２８）关键词铂，五氧化二钒，氢型丝光沸石，程序升温氧化酸性载体Ｐｔ系贵金属双功能催化剂表面积炭是导致其催化性能衰...     

贵金属催化剂用于抽余油加氢精制

研制了一种以铂为主的担载型芳烃抽余油加氢精制催化剂。与传统的Ni-Mo-Al型催化剂相比,上述贵金属催化剂使用温度低(160—185℃),空速高(4—6h~(-1)),寿命长。是一种较为理想的抽余油加氢催化剂。该催化剂已在工业上得到成功应用。     

Electrochemical DNA Biosensor Based on Partially Reduced Graphene Oxide Modified Carbon Ionic Liquid Electrode for the Detection of Transgenic Soybean A2704‐12 Gene Sequence

In this work a partially reduced graphene oxide (p‐RGO) modified carbon ionic liquid electrode (CILE) was prepared as the platform to fabricate an electrochemical DNA sensor, which was used for the sensitive detection of target ssDNA sequence related to transgenic soybean A2704‐12 sequence. The CILE was fabricated by using 1‐butylpyridinium hexafluorophosphate as the binder and then p‐RGO was deposited on the surface of CILE by controlling the electroreduction conditions. NH₂ modified ssDNA probe sequences were immobilized on the electrode surface via covalent bonds between the unreduced oxygen groups on the p‐RGO surface and the amine group at the 5′‐end of ssDNA, which was denoted as ssDNA/p‐RGO/CILE and further used to hybridize with the target ssDNA sequence. Methylene blue (MB) was used as electrochemical indicator to monitor the DNA hybridization. The reduction peak current of MB after hybridization was proportional to the concentration of target A2704‐12 ssDNA sequences in the range from 1.0×10^?12 to 1.0×10^?6 mol/L with a detection limit of 2.9×10^?13 mol/L (3σ). The electrochemical DNA biosensor was further used for the detection of PCR products of transgenic soybean with satisfactory results.     

The Bergman kernel functions on Hua domains

We get the Bergman kernel functions in explicit formulas on four types of Hua domain.There are two key steps: First, we give the holomorphic automorphism groups of four types of Hua domain; second, we introduce the concept of semi-Reinhardt domain and give their complete orthonormal systems. Based on these two aspects we obtain the Bergman kernel function in explicit formulas on Hua domains.     

镱掺杂的Ca_(1-x)Yb_xMnO_3(x=0～0.2)化合物的Rietveld结构精修和热电性能

采用溶胶-凝胶和无压烧结的方法制备了Yb掺杂的钙钛矿型Ca1-xYbxMnO3(x=0~0.2)系列固溶体,并结合X射线R ietveld精修、扫描电子显微镜及热电性能测试,系统研究了Yb掺杂量对产物相组成、晶体结构、显微结构和热电性能的影响。结果表明,Yb的掺杂引起了CaMnO3的晶格畸变,导致Mn-O2-Mn键角(氧八面体在水平方向的扭转)随着Yb的增加而减小;Yb的掺杂大幅度降低了样品的电阻率,并改变了电传输特性:Seebeck系数绝对值显著降低,同时随着掺杂量的增加,进一步减小。Yb的掺杂明显抑制了晶粒长大,此外,其重原子特性和少量第二相的生成显著降低了材料的热导率。其中x=0.1的样品Ca0.9Yb0.1MnO3在T=700℃时,ZT值达到0.093,较单相的CaMnO3提高了120%。     

Influence of atomic densities on propagation property for ultrashort pulses in a two-level medium

The influence of atomic densities on the propagation property for ultrashort pulses in a two-level atom (TLA) medium is investigated. With higher atomic densities, the self-induced transparency (SIT) cannot be recovered even for 2π ultrashort pulses. New features such as pulse splitting, red-shift and blue-shift of the corresponding spectra arise, and the component of central frequency gradually disappears.