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2.
A deuteron magnetic resonance and infrared study of the water molecules in lithium formate monohydrate, LiHCOO · H2O, has been made. The quadrupole coupling constants (e2qQ/h) and asymmetry parameters (η) were found to be 198.7±0.4 and 231.3±0.6 kHz, and 0.060±0.005 and 0.097±0.003, respectively, at 25 ° C.An interpretation is given of the infrared spectra in the OH-stretching region in terms of intra- and intermolecular couplings of the water molecules. It is found that the water molecules are vibrationally distorted by their environments such that the OH-stretching modes consist of independent stretchings of the two O-H bonds. 相似文献
3.
We consider classical billiards in plane, connected, but not necessarily bounded domains. The charged billiard ball is immersed in a homogeneous, stationary magnetic field perpendicular to the plane. The part of dynamics which is not trivially integrable can be described by a bouncing map. We compute a general expression for the Jacobian matrix of this map, which allows us to determine stability and bifurcation values of specific periodic orbits. In some cases, the bouncing map is a twist map and admits a generating function. We give a general form for this function which is useful to do perturbative calculations and to classify periodic orbits. We prove that billiards in convex domains with sufficiently smooth boundaries possess invariant tori corresponding to skipping trajectories. Moreover, in strong field we construct adiabatic invariants over exponentially large times. To some extent, these results remain true for a class of nonconvex billiards. On the other hand, we present evidence that the billiard in a square is ergodic for some large enough values of the magnetic field. A numerical study reveals that the scattering on two circles is essentially chaotic. 相似文献
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Ulf Berg Marcia Berglund Nina Bladh Anette Svensson Magnus Stödeman 《Journal of inclusion phenomena and macrocyclic chemistry》1996,25(1-3):73-76
The properties of inclusion complexes of 1,4-di-R-bicyclo[2.2.2]octaves (R = H (1), Me (2), Cl (3), Br (4), and OH (5)) with cyclodextrins have been studied by NMR, microcalorimetry, and force-field computations. The compounds2 and3 (but not the other compounds) give dynamically stable 1:2 guest-host complexes with -cyclodextrin. Microcalorimetry of5 in water indicates a moderately strong 1:1 complex with - but weak complexes with - or -cyclodextrin. The behaviour depends on the subtle interplay size, polarity, hydrophobicity and type of solvent. 相似文献
6.
Critical factors for high-performance physically adsorbed (dynamic) polymeric wall coatings for capillary electrophoresis of DNA 总被引:2,自引:0,他引:2
Doherty EA Berglund KD Buchholz BA Kourkine IV Przybycien TM Tilton RD Barron AE 《Electrophoresis》2002,23(16):2766-2776
Physically adsorbed (dynamic) polymeric wall coatings for microchannel electrophoresis have distinct advantages over covalently linked coatings. In order to determine the critical factors that control the formation of dynamic wall coatings, we have created a set of model polymers and copolymers based on N,N-dimethylacrylamide (DMA) and N,N-diethylacrylamide (DEA), and studied their adsorption behavior from aqueous solution as well as their performance for microchannel electrophoresis of DNA. This study is revealing in terms of the polymer properties that help create an "ideal" wall coating. Our measurements indicate that the chemical nature of the coating polymer strongly impacts its electroosmotic flow (EOF) suppression capabilities. Additionally, we find that a critical polymer chain length is required for polymers of this type to perform effectively as microchannel wall coatings. The effective mobilities of double-stranded (dsDNA) fragments within dynamically coated capillaries were determined in order to correlate polymer hydrophobicity with separation performance. Even for dsDNA, which is not expected to be a strongly adsorbing analyte, wall coating hydrophobicity has a deleterious influence on separation performance. 相似文献
7.
The electric field gradient (EFG) tensors at the deuterons in the water molecules in BeSO4 · 4D2O at 25°C are reported. The quadrupole coupling constants (e2Q/h) and asymmetry parameters (η) for the two independent deuterons are 181.1(4) and 194.8(3) kHz, and 0.226(4) and 0.123(3), respectively. The EFG tensor corresponding to the smallest e2qQ/h is considerably distorted by the beryllium ion, which causes a high η value as well as a deviation of the y-principal axis by 21.8(6)° from the normal to the water molecule plane. A redetermination of the EFG tensors at the deuterons in the water molecule in Li2SO4 · D2O at 25°C and ?110°C is also reported. The e2Q/h and η values for the two deuterons are 236.6(1.2) and 239.8(1.1) kHz, and 0.091(8) and 0.126(7), respectively, at ?110°C. The corresponding e2qQ/h and η values for the averaged EFG tensor at 25°C are 125.8(1.1) kHz and 0.813(13), respectively. The results are in good agreement with those from the pioneer work by Ketudat and Pound, 20 years ago on the same compound. 相似文献
8.
We consider a Calabi-Yau compactification paradigm with three light generations and anR-symmetry. From a special form of the Tian-Yau manifold, we also construct a new three-generation model with markedly different phenomenology. Thecomplete spectrum of all light matter fields is obtained in a universal way and moreover in a physically suitable basis, allowing a straightforward analysis of all their couplings. Here we discuss all the renormalizable Yukawa couplings. This computation can equally well be repeated for all compactification models based on Calabi-Yau complete intersections in products of homogeneous spaces. 相似文献
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10.
Nicholas J. Kuklinski E. Carina Berglund Andrew G. Ewing 《Journal of separation science》2010,33(3):388-393
The fruit fly is one of the most heavily studied model organisms for genetics research and has significantly contributed to the molecular, cellular, and evolutionary understandings of human behavior. Recent research in the analytical chemistry of the fruit fly has focused on developing methods to obtain highly sensitive chemical quantification information of Drosophila melanogaster, especially looking at the nervous system. We provide a brief overview of work in the area of CE of the fly head and brain. 相似文献