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1.
In this paper, we report the conducting and electrochemical properties of a homogeneous V2O5-SiO2 xerogel composite obtained from the simultaneous polymerization in both inorganic components (Si-O and V-O based polymers) forming an interpenetrating polymer network, where a mutual “solubility” due to cross-links and entanglements was observed. The presence of V2O5 inside the silica matrix has a strong effect on electrical conductivity; measurements showed room temperature conductivity almost 1000 times higher than what is found in the literature. In addition, the electrochemical behavior is quite similar to that found in V2O5 xerogel. Moreover, the effects of thermal treatment on the conducting and electrochemical properties were investigated. It was found that both properties were improved with no significant effect on V2O5 xerogel layered structure. 相似文献
2.
The radical anion of aceneazulenedione in which a benzoquinone is fused to an azulene moiety was generated by electrolysis and by reduction with the alkali metals in ethereal solvents. The hyperfine data could not be reproduced by standard Hückel calculations which usually give reliable predictions for the spin distribution in radical ions such as azulene quinones and a variety of extended π systems. However, PPP and, preferably,ab initio geometry optimisations followed by single-point calculations of the Fermi contact interaction with density functional theory, led to a straightforward assignment of the hyperfine coupling constants. 相似文献
3.
E. M. Araújo Renata Barbosa Amanda D. Oliveira Crislene R. S. Morais T. J. A. deMélo A. G. Souza 《Journal of Thermal Analysis and Calorimetry》2007,87(3):811-814
Polyethylene/montmorillonite clay nanocomposites were obtained via direct
melt intercalation. The clay was organically modified with four different
types of quaternary ammonium salts. The objective of this work is to study
the use of montmorillonite clay in the production of nanocomposites by means
on rheological, mechanical and crystallization properties of nanocomposites
and to compare to the properties of the matrix and PE/unmodified clay nanocomposites.
In general, the tensile test showed that the yield strength and modulus of
the nanocomposites are close to the pure PE. Apparently, the mixture with
Dodigen salt seems to be more stable than the pure PE and PE/unmodified clay. 相似文献
4.
In the present work, models describing the effect of the pH on the chromatographic and electrophoretic behaviour for polyprotic peptides were compared. The proposed models can be simultaneously used for determination of dissociation constants and selection of the optimum pH for the separation of peptides, in water and acetonitrile-water mixtures widely used in liquid chromatography and in capillary electrophoresis. The models use the pH value measured in the acetonitrile-water mixture instead of the pH value in water and take into account the effect of the activity coefficients. They permit the determination of the acidity constants in the aqueous and hydro-organic mobile phase from chromatographic retention and electrophoretic migration measurements, respectively. The values obtained by both proposed techniques agree with the potentiometric values previously determined. The suitability of the proposed models for predicting chromatographic and electrophoretic behaviour of compounds studied from a limited number of experimental data was also compared. The separation between solutes by both techniques in a complex mixture can be easily predicted, making simple and rapid pH selection to achieve optimum separation. 相似文献
5.
A two-dimensional model is developed to describe the hydrodynamics, heat transfer and adsorption phenomena associated with the adsorptive storage of natural gas (NG) in cylindrical reservoirs. Intraparticle and film resistances to both heat and mass transfer are neglected. In the momentum equation, Ergun's law is considered locally valid and is extended to two dimensions. These assumptions are fully justified in the paper. Numerical results are presented concerning the pressurization and blowdown of an ultra-lightweight 50 litre cylinder, commercially available for the storage of compressed NG, if it were filled with an activated carbon having a good adsorptive storage capacity. A simple formula is also proposed to predict the filling times for fast charges. The predicted temperature changes in the packed-bed are in good agreement with those reported in the literature for an experimental charge/discharge. 相似文献
6.
Capillary electrophoresis coupled to time of flight-mass spectrometry of therapeutic peptide hormones 总被引:2,自引:0,他引:2
We have established a method for separation and characterization of a series of peptide hormones of pharmaceutical interest and wide therapeutical use by capillary electrophoresis-electrospray-mass spectrometry (CE-ES-MS) using a sheath flow interface. Several parameters were systematically investigated, such as concentration of the electrolyte, organic solvent and sheath liquid composition, gas flow rates and capillary position. Moreover, limits of detection, linearity, repeatability and day-to-day reproducibility of the proposed method were studied in order to obtain the main quality parameters. 相似文献
7.
A tungsten-rhodium treatment on the integrated platform of a transversely heated graphite atomiser was used as a permanent chemical modifier for the determination of copper in biological materials by using digested samples as well as slurry sampling in electrothermal atomic absorption spectrometry. The W-Rh permanent modifier was as efficient as Pd+Mg(NO(3))(2) conventional modifier for obtaining good Cu thermal stabilisation in the digested and slurry samples. The permanent W-Rh modifier remained stable by approximately 300 and 250 firings when 20 mul of digested sample and 20 mul of slurry were delivered into the atomiser, respectively. In addition, the permanent modifier increased the tube lifetime up to 1370 and 744 analytical measurements in the digested and slurry samples, respectively. Also, when the W-Rh permanent modifier was employed, there was less variation of the slope of the analytical curves during the total atomiser lifetime, resulting in a decreased need of re-calibration during routine analysis, increasing the sample throughput, and consequently diminishing the variable analytical costs. Detection limits obtained with W-Rh permanent modifier were 0.64 and 0.33 mug g(-1) Cu for digested (dilution factor 100 ml g(-1)) and 1.0% m/v slurries of biological materials, respectively. Results for the determination of copper in the samples were in agreement with those obtained with decomposed sample solutions by using Pd+Mg(NO(3)), since no statistical differences were found after applying the paired t-test at the 95% level. 相似文献
8.
Lupane Pentacyclic Triterpenes Isolated from Stems and Branches of Maytenus imbricata (Celastraceae)
Silvia Ribeiro deSouzaeSilva GraciaDivina deFtimaSilva LucaCludio deAlmeidaBarbosa LucienirPains Duarte SidneyAugustoVieira Filho 《Helvetica chimica acta》2005,88(5):1102-1109
Four lupane pentacyclic triterpenes were isolated from the hexane extract of stems and branches of Maytenus imbricata Mart. ex Reissek : 3‐oxolup‐20(30)‐en‐29‐al ( 1 ), 30‐hydroxylup‐20(29)‐en‐3‐one ( 2 ), (11α)‐11‐hydroxylup‐20(29)‐en‐3‐one ( 3 ), and (3β)‐lup‐20(30)‐ene‐3,29‐diol ( 4 ). The structural identification of 1 – 4 was achieved by 1H‐ and 13C‐NMR techniques, including 2D experiments (HSQC, HMBC, and NOESY). 相似文献
9.
An accurate estimation of pKa values in methanol-water binary mixtures is very important for several separation techniques such as liquid chromatography and capillary electrophoresis that use these solvent mixtures. In this study, the pKa values of 11 polyphenolic acids have been determined in methanol-water binary mixtures (10%, 20% and 30% (v/v)) by potentiometry, liquid chromatography (LC) and LC-DAD methodology.The results show a similar trend for the pKa values of all the studied compounds, as they increase with increasing concentration of organic modifier, which allows a linear relationship between pKa values and mole fraction of methanol to be obtained. The pKa values obtained in aqueous medium have been compared with those given in the literature, and also with the values predicted by the SPARC on-line pKa calculator. The data obtained have been used to test the feasibility of an estimation of dissociation constants in a methanol-water medium from the relationship between pKa values and the organic cosolvent fraction in the mixtures. 相似文献
10.
In order to separate and characterize the target peptide and the side-product peptide compounds of a synthesis mixture of the peptide hormone goserelin, liquid chromatography coupled to high-flow electrospray ionization mass spectrometry (LC-ES-MS) has been used. Goserelin is an important drug with recognized therapeutical application for palliative treatment of prostatic and breast carcinomas. Stepwise solid-phase peptide synthesis commonly results in unwanted side-products associated with incomplete peptide chains. Consequently, this procedure requires extensive purification and characterization of the final synthesis mixture. The method of linear solvation energy relationships has been applied to optimize the proportion of organic modifier of the mobile phase used in the established LC method. On the other hand, ES-MS has allowed rapid and reliable identification of the target peptide and the other impurities present in the goserelin synthesis products. 相似文献