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1.
Deerenberg S Schrekker HS van Strijdonck GP Kamer PC van Leeuwen PW Fraanje J Goubitz K 《The Journal of organic chemistry》2000,65(16):4810-4817
A series of chiral phosphine-phosphite ligands 1-6 have been synthesized and used in the enantioselective palladium-catalyzed reaction of rac-1,3-diphenyl-2-propenyl acetate with dimethyl malonate as nucleophile. Ligands 1a, 2, 3, 5a, 6a, and 6b have been synthesized starting from racemic tert-butylphenylphosphinoborane. The use of dynamically resolved Li phosphide (-)-sparteine provided the optically pure ligands. Crystals of the allylpalladium (6a) complex were obtained, suitable for X-ray crystal structure determination. The X-ray crystal structure of the allylpalladium (6a) complex revealed a longer palladium-carbon bond distance trans to the phosphine moiety indicating that the attack of the nucleophile takes place at the carbon trans to the phosphine moiety. This was confirmed by the fact that the phosphine moiety did not affect the enantioselectivity directly. Under mild reaction conditions, enantioselectivities up to 83% were obtained (25 degrees C) with ligand 1e. Systematic variation of the ligand bridge and the phosphite moiety showed that the configuration of the product is controlled by the atropisomerism of the biphenyl substituent at the phosphite moiety. The conformation of the biphenyl group, in turn, is controlled by the substituent at the chiral carbon in the bridge. Ligands with large bite angles yielded higher enantioselectivities. 相似文献
2.
R. P. Hallett K. G. McKay S. P. Balm A. W. Allaf H. W. Kroto A. J. Stace 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1995,34(1):65-70
Reaction studies of carbon clustersC
n
in the rangen=8–37, produced by laser vaporisation in a supersonic nozzle, have been investigated using time-of-flight mass spectrometry. Clear differences in reaction products formed on hydrogenation are detected which show that even and odd clusters behave quite differently and furthermore thatat least two different types of even cluster appear to exist. The reactivity patterns for clusters C
n
withn=16, 18 and 22 are in a different class from those withn=20, 24, 26 ..., a behaviour consistent with the existence of closed cage fullerene structures for even clusters with 20 or more carbon atoms (other thann=22). 相似文献
3.
Petra DG Kamer PC Spek AL Schoemaker HE van Leeuwen PW 《The Journal of organic chemistry》2000,65(10):3010-3017
A new class of efficient catalysts was developed for the asymmetric transfer hydrogenation of unsymmetrical ketones. A series of chiral N,S-chelates (6-22) was synthesized to serve as ligands in the iridium(I)-catalyzed reduction of ketones. Both formic acid and 2-propanol proved to be suitable as hydrogen donors. Sulfoxidation of an (R)-cysteine-based aminosulfide provided a diastereomeric ligand family containing a chiral sulfur atom. The two chiral centers of these ligands showed a clear effect of chiral cooperativity. In addition, aminosulfides containing two asymmetric carbon atoms in the backbone were synthesized. Both the sulfoxide-containing beta-amino alcohols and the aminosulfides derived from 1,2-disubstituted amino alcohols gave rise to high reaction rates and moderate to excellent enantioselectivities in the reduction of various ketones. The enantioselective outcome of the reaction was favorably affected by selecting the most appropriate hydrogen donor. Enantioselectivities of up to 97% were reached in the reduction of aryl-alkyl ketones. 相似文献
4.
Abazov VM Abbott B Abdesselam A Abolins M Abramov V Acharya BS Adams DL Adams M Ahmed SN Alexeev GD Alves GA Amos N Anderson EW Arnoud Y Baarmand MM Babintsev VV Babukhadia L Bacon TC Baden A Baldin B Balm PW Banerjee S Barberis E Baringer P Barreto J Bartlett JF Bassler U Bauer D Bean A Beaudette F Begel M Belyaev A Beri SB Bernardi G Bertram I Besson A Beuselinck R Bezzubov VA Bhat PC Bhatnagar V Bhattacharjee M Blazey G Blessing S Boehnlein A Bojko NI Borcherding F Bos K Brandt A Breedon R 《Physical review letters》2002,88(17):171802
We have performed a search for scalar top quark (stop) pair production in the inclusive electron-muon-missing transverse energy final state, using a sample of pp events corresponding to 108.3 pb(-1) of data collected with the D0 detector at Fermilab. The search is done in the framework of the minimal supersymmetric standard model assuming that the sneutrino is the lightest supersymmetric particle. For the dominant decays of the lightest stop, t-->b chi+1 and t-->blnu, no evidence for signal is found. We derive cross-section limits as a function of stop ( t ), chargino ( chi+1), and sneutrino ( nu) masses. 相似文献
5.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Agelou M Agram JL Ahn SH Ahsan M Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Andeen T Anderson S Andrieu B Arnoud Y Askew A Asman B Jesus AC Atramentov O Autermann C Avila C Badaud F Baden A Baldin B Balm PW Banerjee S Barberis E Bargassa P Baringer P Barnes C Barreto J Bartlett JF Bassler U Bauer D Bean A Beauceron S Begel M Bellavance A Beri SB Bernardi G Bernhard R Bertram I Besançon M Beuselinck R Bezzubov VA 《Physical review letters》2005,95(5):051802
We present a measurement of the Zgamma production cross section and limits on anomalous ZZgamma and Zgammagamma couplings for form-factor scales of lambda = 750 and 1000 GeV. The measurement is based on 138 (152) candidates in the eegamma (mumugamma) final state using 320(290) pb(-1) of pp(-1) collisions at square root of s = 1.96 TeV. The 95% C.L. limits on real and imaginary parts of individual anomalous couplings are /h(10,30)Z/ < 0.23, /h(20,40)Z/ < 0.020, /h(10,30)gamma/ < 0.23, and /h(20,40)gamma/ < 0.019 for lambda = 1000 GeV. 相似文献
6.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Agelou M Agram JL Ahn SH Ahsan M Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Anderson S Andrieu B Arnoud Y Askew A Asman B Atramentov O Autermann C Avila C Badaud F Baden A Baldin B Balm PW Banerjee S Barberis E Bargassa P Baringer P Barnes C Barreto J Bartlett JF Bassler U Bauer D Bean A Beauceron S Begel M Bellavance A Beri SB Bernardi G Bernhard R Bertram I Besançon M Beuselinck R Bezzubov VA Bhat PC Bhatnagar V 《Physical review letters》2005,94(10):102001
We present measurements of the Lambda(0)(b) lifetime in the exclusive decay channel Lambda(0)(b)--> J/psiLambda(0), with J/psi--> mu(+)mu(-) and Lambda(0)--> ppi(-), the B0 lifetime in the decay B0-->J/psiK(0)(S) with J/psi--> mu(+)mu(-) and K(0)(S)-->pi(+)pi(-), and the ratio of these lifetimes. The analysis is based on approximately 250 pb(-1) of data recorded with the D0 detector in pp collisions at sqrt[s] = 1.96 TeV. The Lambda(0)(b) lifetime is determined to be tau(Lambda(0)(b)) = 1.22(+0.22)(-0.18)(stat) +/- 0.04(syst) ps, the B0 lifetime tau(B0) = 1.40(+0.11)(-0.10)(stat) +/- 0.03(syst) ps, and the ratio tau(Lambda(0)(b))/tau(B0) = 0.87(+0.17)(-0.14)(stat) +/- 0.03(syst). In contrast with previous measurements using semileptonic decays, this is the first determination of the Lambda(0)(b) lifetime based on a fully reconstructed decay channel. 相似文献
7.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Agelou M Agram JL Ahn SH Ahsan M Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Andeen T Anderson S Andrieu B Arnoud Y Arov M Askew A Asman B Jesus AC Atramentov O Autermann C Avila C Badaud F Baden A Bagby L Baldin B Balm PW Banerjee P Banerjee S Barberis E Bargassa P Baringer P Barnes C Barreto J Bartlett JF Bassler U Bauer D Bean A Beauceron S Begalli M Begel M Bellavance A Beri SB Bernardi G Bernhard R Bertram I 《Physical review letters》2005,95(17):171801
We present a study of the decay B0(s) --> J/psiphi. We obtain the CP-odd fraction in the final state at time zero, Rperpendicular = 0.16 +/- 0.10(stat) +/- 0.02 (syst), the average lifetime of the (B0(s), B0(s)) system, tau(B0(s)) = 1.39(+0.13)(-0.16)(stat)(+0.01)(-0.02)(syst) ps, and the relative width difference between the heavy and light mass eigenstates, DeltaGamma/Gamma tripple bond (GammaL - GammaH)/Gamma = 0.24(+0.28)(-0.38)(stat)(+0.03)(-0.04)(syst). With the additional constraint from the world average of the lifetime measurements using semileptonic decays, we find tau(B0(s)) = 1.39 +/- 0.06 ps and DeltaGamma/Gamma = 0.25(+0.14)(-0.15). For the ratio of the B0(s) and B0 lifetimes we obtain tau(B0(s))/tau(B0) = 0.91 +/- 0.09(stat) +/- 0.003(syst). 相似文献
8.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Agelou M Agram JL Ahn SH Ahsan M Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Andeen T Anderson S Andrieu B Arnoud Y Askew A Asman B Assis Jesus AC Atramentov O Autermann C Avila C Badaud F Baden A Baldin B Balm PW Banerjee S Barberis E Bargassa P Baringer P Barnes C Barreto J Bartlett JF Bassler U Bauer D Bean A Beauceron S Begel M Bellavance A Beri SB Bernardi G Bernhard R Bertram I Besançon M Beuselinck R Bezzubov VA 《Physical review letters》2005,95(15):151805
A search for associated production of charginos and neutralinos is performed using data recorded with the D0 detector at a pp center-of-mass energy of 1.96 TeV at the Fermilab Tevatron Collider. This analysis considers final states with missing transverse energy and three charged leptons, of which at least two are electrons or muons. No evidence for supersymmetry is found in a data set corresponding to an integrated luminosity of 320 pb-1. Limits on the product of the production cross section and leptonic branching fraction are set. For the minimal supergravity model, a chargino lower mass limit of 117 GeV at the 95% C.L. is derived in regions of parameter space with enhanced leptonic branching fractions. 相似文献
9.
Abazov VM Abbott B Abolins M Acharya BS Adams M Adams T Agelou M Agram JL Ahn SH Ahsan M Alexeev GD Alkhazov G Alton A Alverson G Alves GA Anastasoaie M Andeen T Anderson S Andrieu B Arnoud Y Askew A Asman B Assis Jesus AC Atramentov O Autermann C Avila C Badaud F Baden A Baldin B Balm PW Banerjee S Barberis E Bargassa P Baringer P Barnes C Barreto J Bartlett JF Bassler U Bauer D Bean A Beauceron S Begel M Bellavance A Beri SB Bernardi G Bernhard R Bertram I Besançon M Beuselinck R Bezzubov VA 《Physical review letters》2005,95(9):091801
We report the first direct search for the Kaluza-Klein (KK) modes of Randall-Sundrum gravitons using dielectron, dimuon, and diphoton events observed with the D0 detector operating at the Fermilab Tevatron pp(-) Collider at sqrt[s]=1.96 TeV. No evidence for resonant production of gravitons has been found in the data corresponding to an integrated luminosity of approximately equal to 260 pb(-1). Lower limits on the mass of the first KK mode at the 95% C.L. have been set between 250 and 785 GeV, depending on its coupling to standard model particles. 相似文献
10.
Abazov VM Abbott B Abdesselam A Abolins M Abramov V Acharya BS Adams DL Adams M Ahmed SN Alexeev GD Alves GA Amos N Anderson EW Baarmand MM Babintsev VV Babukhadia L Bacon TC Baden A Baldin B Balm PW Banerjee S Barberis E Baringer P Barreto J Bartlett JF Bassler U Bauer D Bean A Begel M Belyaev A Beri SB Bernardi G Bertram I Besson A Beuselinck R Bezzubov VA Bhat PC Bhatnagar V Bhattacharjee M Blazey G Blessing S Boehnlein A Bojko NI Borcherding F Bos K Brandt A Breedon R Briskin G Brock R 《Physical review letters》2001,87(6):061802
We present results of searches for technirho (rho(T)), techniomega (omega(T)), and Z' particles, using the decay channels rho(T),omega(T),Z'-->e(+)e(-). The search is based on 124.8 pb(-1) of data collected by the D0 detector at the Fermilab Tevatron during 1992-1996. In the absence of a signal, we set 95% C.L. upper limits on the cross sections for the processes pp-->rho(T),omega(T),Z'-->e(+)e(-) as a function of the mass of the decaying particle. For certain model parameters, we exclude the existence of degenerate rho(T) and omega(T) states with masses below about 200 GeV. We exclude a Z' with mass below 670 GeV, assuming that it has the same couplings to fermions as the Z boson. 相似文献