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1.
Active anodes, especially those consisting of metal mixed oxides (MMOs) containing Ru and/or Ir oxides, have been applied in the treatment of wastewater, especially when chloride ions are present. Their characteristics continuously drive the study of applications of these materials, be they in the degradation of different organic molecules, the preparation of new electrode materials and in the association of various processes to increase pollutant removal. Thus, this brief review aims to present some of the recent advances in the application of active anode materials in environmental electrochemistry. Focussing on the 2018–2020 period, it is possible to note many applied studies, using commercially available materials, covering a wide range of target pollutants. Still other studies aim to modify the catalyst surfaces to increase the mineralization capacity, and the use of these anodes in the production of free chlorine species to mediate indirect organic reduction is observed. 相似文献
2.
Francesco Segatta David M. Rogers Naomi T. Dyer Ellen E. Guest Zhuo Li Hainam Do Artur Nenov Marco Garavelli Jonathan D. Hirst 《Molecules (Basel, Switzerland)》2021,26(2)
A fully quantitative theory of the relationship between protein conformation and optical spectroscopy would facilitate deeper insights into biophysical and simulation studies of protein dynamics and folding. In contrast to intense bands in the far-ultraviolet, near-UV bands are much weaker and have been challenging to compute theoretically. We report some advances in the accuracy of calculations in the near-UV, which were realised through the consideration of the vibrational structure of the electronic transitions of aromatic side chains. 相似文献
3.
Artur Erdélyi 《Monatshefte für Mathematik》1939,47(1):87-103
Ohne Zusammenfassung 相似文献
4.
Letg:U→ℝ (U open in ℝn) be an analytic and K-subanalytic (i. e. definable in ℝ
an
K
, whereK, the field of exponents, is any subfield ofℝ) function. Then the set of points, denoted Σ, whereg does not admit an analytic extension is K-subanalytic andg can be extended analytically to a neighbourhood of Ū\∑.
Partially supported by the European RTN Network RAAG (contract no. HPRN-CT-00271) 相似文献
5.
L. Sajo-Bohus M. C. Scott E. D. Greaves L. J. Somervaille S. Green T. Avila F. Loaiza L. Foglietta 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(2):251-255
Gamma-ray induced X-ray emission (GIXE) technique for elemental lead in-vivo tibial measurement using a large volume hyper
pure germanium detector is presented with the most convenient source-sample-detector geometry. The system operates advantageously
when several parameters are considered for a lower dead time operation. The detection limit (DL) is better that 3.5 μg/g of
Ca. Results of in-vivo average tibial lead concentration for some of the monitored groups are: control 7 μg of lead per g
of Ca; gasoline filling attendants 6 μg/g of Ca; custom office workers near the DL; industrial workers range from DL up to
84±3 μg/g of Ca, suggesting that lead accumulation in the bone does not represent a major health risk
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
6.
Ana I. R. N. A. Barros Artur M. S. Silva 《Monatshefte für Chemie / Chemical Monthly》2006,137(12):1505-1528
Summary. Several nitroflavone derivatives were synthesized by cyclodehydrogenation of 2′-hydroxychalcones and by the Baker-Venkataraman approach, starting from 2′-hydroxyacetophenones and benzoic acid derivatives. Nitroflavones synthesised by the first synthetic
approach were obtained in better global yields than those obtained by the later method. The structures of all new compounds
were elucidated by microanalyses, 1D and 2D NMR, IR, and mass spectroscopic measurements. 相似文献
7.
8.
Coordination of dinitrogen to Sellmann-type iron (II) complexes in a sulfur-dominated coordination sphere, which emulates
the environment of iron centers in the FeMo-cofactor of nitrogenase, is analyzed with respect to spin states, spin barriers,
and the effect of trans-ligands. Such detailed investigations became only recently feasible when the reliability of density functional methods, which
are the only quantum chemical methods capable of describing large transition metal complexes, could significantly be improved
for the calculation of energies for states of different spin. It is found that the actual binding energy of dinitrogen is
of sufficient magnitude for a reasonably strong fixation of N2 by Sellmann-type coordination compounds. However, potential fixation is determined by additional factors which reduce the
binding energy. One factor is the change in spin state of the N2-free metal fragment, which lowers the total energy and quenches the thermodynamic stabilization effect of the binding energy.
In addition, the metal fragment rearranges and gains even more stabilization energy for the un-coordinated state. Apart from
these thermodynamical effects, the existence of spin barriers, which must be overcome upon binding of dinitrogen, leads to
kinetical effects, which cannot be neglected. 相似文献
9.
Ana?C.?F.?RibeiroEmail author Victor?M.?M.?Lobo Artur?J.?M.?Valente Eduarda?F.?G.?Azevedo M.??da?G.?Miguel H.?D.?Burrows 《Colloid and polymer science》2004,283(3):277-283
Differential mutual diffusion coefficients of n-alkyltrimethylammonium bromides [CH3(CH2)n–1N(CH3)3Br, CnTAB] (n=10, 12, 14, 16) have been measured in aqueous solutions at 298.15 K using a conductimetric cell and an automatic apparatus to follow diffusion. The cell is based on an open-ended capillary, and the technique follows the diffusion process by measuring the resistance of a solution inside the capillaries at various times. The electrical conductances of those solutions have also been measured to calculate the critical micellar concentration (cmc). Thermodynamic analysis of the data suggests that the free ion concentration decreases at concentrations above the cmc, in agreement with theoretical predictions. The obtained values of the micellization parameters were used to model the mutual diffusion coefficients of CnTAB aqueous solutions. 相似文献
10.
Experimental data of excess molar enthalpy of binary mixtures of acetonitrile + diethylamine or S-butylamine mixtures as a function of composition at 288.15, 293.15, 298.15 and 303.15 K at atmospheric pressure have been used to calculate excess partial molar enthalpy and partial molar enthalpy of each component as a function of composition as well as partial molar enthalpy properties at infinite dilution. The Flory and Prigogine–Flory–Patterson (PFP) theories were applied to correlate the data. The results of the calculations as well as the influence of temperature and isomers chain on the partial molar enthalpy properties are discussed. 相似文献